Spectra for:
Hans-Joachim Gais, Leleti R. Reddy, Gadamsetti S. Babu, Gerhard Raabe
Compound 4A (-)-(4R,5R)-TRIETHYL-(4-ISOPROPYL-3-METHYL-5-PHENYL-4,5-DIHYDRO-FURAN-2-YL)-SILANE
Compound 4B (-)-(4R,5R)-TRIETHYL-[4-ISOPROPYL-3-METHYL-5-(4-METHOXYPHENYL)-4,5-DIHYDRO-FURAN-2-YL]-SILANE
![(-)-(4R,5R)-TRIETHYL-[4-ISOPROPYL-3-METHYL-5-(4-METHOXYPHENYL)-4,5-DIHYDRO-FURAN-2-YL]-SILANE](/api/compound/Arw0LhgEfki.png?h=300&w=458 "(-)-(4R,5R)-TRIETHYL-[4-ISOPROPYL-3-METHYL-5-(4-METHOXYPHENYL)-4,5-DIHYDRO-FURAN-2-YL]-SILANE")
Compound 4C (-)-(4R,5R)-TRIETHYL-[4-ISOPROPYL-3-METHYL-5-(4-BROMOPHENYL)-4,5-DIHYDRO-FURAN-2-YL]-SILANE
![(-)-(4R,5R)-TRIETHYL-[4-ISOPROPYL-3-METHYL-5-(4-BROMOPHENYL)-4,5-DIHYDRO-FURAN-2-YL]-SILANE](/api/compound/Ct55K8qQTRf.png?h=300&w=458 "(-)-(4R,5R)-TRIETHYL-[4-ISOPROPYL-3-METHYL-5-(4-BROMOPHENYL)-4,5-DIHYDRO-FURAN-2-YL]-SILANE")
Compound 4D (-)-(4R,5S)-TRIETHYL-(5-CYCLOHEXYL-4-ISOPROPYL-3-METHYL-4,5-DIHYDROFURAN-2-YL)-SILANE
Compound 4E (-)-(4R,5R)-TRIETHYL-(3-METHYL-4,5-DIPHENYL-4,5-DIHYDRO-FURAN-2-YL)-SILANE
Compound 4F (-)-(4R,5R)-TRIETHYL-[3-METHYL-4-PHENYL-5-(4-METHOXYPHENYL)-4,5-DIHYDRO-FURAN-2-YL]-SILANE
![(-)-(4R,5R)-TRIETHYL-[3-METHYL-4-PHENYL-5-(4-METHOXYPHENYL)-4,5-DIHYDRO-FURAN-2-YL]-SILANE](/api/compound/Lqwitz0rG6W.png?h=300&w=458 "(-)-(4R,5R)-TRIETHYL-[3-METHYL-4-PHENYL-5-(4-METHOXYPHENYL)-4,5-DIHYDRO-FURAN-2-YL]-SILANE")
Compound 4G (-)-(4R,5R)-TRIETHYL-[3-METHYL-4-PHENYL-5-(4-BROMOPHENYL)-4,5-DIHYDRO-FURAN-2-YL]-SILANE
![(-)-(4R,5R)-TRIETHYL-[3-METHYL-4-PHENYL-5-(4-BROMOPHENYL)-4,5-DIHYDRO-FURAN-2-YL]-SILANE](/api/compound/2RBvewJbMA0.png?h=300&w=458 "(-)-(4R,5R)-TRIETHYL-[3-METHYL-4-PHENYL-5-(4-BROMOPHENYL)-4,5-DIHYDRO-FURAN-2-YL]-SILANE")
Compound 4H (-)-(4R,5S)-TRIETHYL-(4-CYCLOHEXYL-3-METHYL-4-PHENYL-4,5-DIHYDRO-FURAN-2-YL)-SILANE
Compound 5F (-)-S-N,N-DIMETHYLAMINO-S-[(Z)-(3R,4R)-2-METHYL-3-PHENYL-(4-METHOXYPHENYL)-4-(TRIETHYLSILYL)-OXY]-BUT-ENYL-PHENYL-SULFOXINIUM-TETRAFLUOROBORATE
![(-)-S-N,N-DIMETHYLAMINO-S-[(Z)-(3R,4R)-2-METHYL-3-PHENYL-(4-METHOXYPHENYL)-4-(TRIETHYLSILYL)-OXY]-BUT-ENYL-PHENYL-SULFOXINIUM-TETRAFLUOROBORATE](/api/compound/FVYMHIPjdBO.png?h=300&w=458 "(-)-S-N,N-DIMETHYLAMINO-S-[(Z)-(3R,4R)-2-METHYL-3-PHENYL-(4-METHOXYPHENYL)-4-(TRIETHYLSILYL)-OXY]-BUT-ENYL-PHENYL-SULFOXINIUM-TETRAFLUOROBORATE")
Compound 6A (-)-(4R,5R)-TRIETHYL-[3-(4-METHOXY-PHENYL)-3,3A,4,5,6,7-HEXAHYDROISOBENZOFURAN-1-YL]-SILANE
![(-)-(4R,5R)-TRIETHYL-[3-(4-METHOXY-PHENYL)-3,3A,4,5,6,7-HEXAHYDROISOBENZOFURAN-1-YL]-SILANE](/api/compound/EbZ73dCMlEy.png?h=300&w=458 "(-)-(4R,5R)-TRIETHYL-[3-(4-METHOXY-PHENYL)-3,3A,4,5,6,7-HEXAHYDROISOBENZOFURAN-1-YL]-SILANE")
Compound 6B (-)-(4R,5R)-TRIETHYL-[3-(4-METHOXY-PHENYL)-3A,4,5,6,7,8-HEPTAHYDRO-3H-CYCLOHEPTA-[C]-FURAN-1-YL]-SILANE
![(-)-(4R,5R)-TRIETHYL-[3-(4-METHOXY-PHENYL)-3A,4,5,6,7,8-HEPTAHYDRO-3H-CYCLOHEPTA-[C]-FURAN-1-YL]-SILANE](/api/compound/D7xQqiyVAxV.png?h=300&w=458 "(-)-(4R,5R)-TRIETHYL-[3-(4-METHOXY-PHENYL)-3A,4,5,6,7,8-HEPTAHYDRO-3H-CYCLOHEPTA-[C]-FURAN-1-YL]-SILANE")
Compound 6C ENT-(+)-(4S,5S)-TRIETHYL-[3-(4-METHOXY-PHENYL)-3,3A,4,5,6,7,8,9-OCTAHYDROCYCLOOCTA-[C]-FURAN-1-YL]-SILANE
![ENT-(+)-(4S,5S)-TRIETHYL-[3-(4-METHOXY-PHENYL)-3,3A,4,5,6,7,8,9-OCTAHYDROCYCLOOCTA-[C]-FURAN-1-YL]-SILANE](/api/compound/A2T7jbYqtbD.png?h=300&w=458 "ENT-(+)-(4S,5S)-TRIETHYL-[3-(4-METHOXY-PHENYL)-3,3A,4,5,6,7,8,9-OCTAHYDROCYCLOOCTA-[C]-FURAN-1-YL]-SILANE")
Compound 8C VGPAGGXDOUIQFG-BFRSPIHOSA-N
Compound 9A (-)-(3R,3AR)-3-(4-METHOXYPHENYL)-1,3,3A,4,5,6-HEXAHYDRO-ISOBENZOFURAN
Compound 9B (-)-(3R,3AR)-3-(4-METHOXYPHENYL)-3,3A,4,5,6,7-HEXAHYDRO-1H-CYCLOHEPTA-[C]-FURAN
![(-)-(3R,3AR)-3-(4-METHOXYPHENYL)-3,3A,4,5,6,7-HEXAHYDRO-1H-CYCLOHEPTA-[C]-FURAN](/api/compound/JuwpTYbfRg0.png?h=300&w=458 "(-)-(3R,3AR)-3-(4-METHOXYPHENYL)-3,3A,4,5,6,7-HEXAHYDRO-1H-CYCLOHEPTA-[C]-FURAN")
Compound 9C ENT-(+)-(3R,3AR)-3-(4-METHOXYPHENYL)-1,3,3A,4,5,6,7,8-OCTAHYDRO-1H-CYCLOOCTA-[C]-FURAN
![ENT-(+)-(3R,3AR)-3-(4-METHOXYPHENYL)-1,3,3A,4,5,6,7,8-OCTAHYDRO-1H-CYCLOOCTA-[C]-FURAN](/api/compound/Coonj25vuY7.png?h=300&w=458 "ENT-(+)-(3R,3AR)-3-(4-METHOXYPHENYL)-1,3,3A,4,5,6,7,8-OCTAHYDRO-1H-CYCLOOCTA-[C]-FURAN")
Compound 13A (E)-Isomer
Compound 13A Z-ISOMER
Compound 15A (-)-TRIETHYL-[(Z)-(1R,2R)-2-ISOPROPYL-3-METHYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-1-PHENYL-BUT-3-ENYLOXY]-SILANE
![(-)-TRIETHYL-[(Z)-(1R,2R)-2-ISOPROPYL-3-METHYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-1-PHENYL-BUT-3-ENYLOXY]-SILANE](/api/compound/IGNORExzT11.png?h=300&w=458 "(-)-TRIETHYL-[(Z)-(1R,2R)-2-ISOPROPYL-3-METHYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-1-PHENYL-BUT-3-ENYLOXY]-SILANE")
Compound 15B (-)-TRIETHYL-[(Z)-(1R,2R)-2-ISOPROPYL-3-METHYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-1-(4-METHOXYPHENYL)-BUT-3-ENYLOXY]-SILANE
![(-)-TRIETHYL-[(Z)-(1R,2R)-2-ISOPROPYL-3-METHYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-1-(4-METHOXYPHENYL)-BUT-3-ENYLOXY]-SILANE](/api/compound/ERpWoYrWaB3.png?h=300&w=458 "(-)-TRIETHYL-[(Z)-(1R,2R)-2-ISOPROPYL-3-METHYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-1-(4-METHOXYPHENYL)-BUT-3-ENYLOXY]-SILANE")
Compound 15C (-)-TRIETHYL-[(Z)-(1R,2R)-2-ISOPROPYL-3-METHYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-1-(4-BROMOPHENYL)-BUT-3-ENYLOXY]-SILANE
![(-)-TRIETHYL-[(Z)-(1R,2R)-2-ISOPROPYL-3-METHYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-1-(4-BROMOPHENYL)-BUT-3-ENYLOXY]-SILANE](/api/compound/asuAXkTAXQ.png?h=300&w=458 "(-)-TRIETHYL-[(Z)-(1R,2R)-2-ISOPROPYL-3-METHYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-1-(4-BROMOPHENYL)-BUT-3-ENYLOXY]-SILANE")
Compound 15D (-)-TRIETHYL-[(Z)-(1R,2R)-2-ISOPROPYL-3-METHYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-1-CYCLOHEXYL-BUT-3-ENYLOXY]-SILANE
![(-)-TRIETHYL-[(Z)-(1R,2R)-2-ISOPROPYL-3-METHYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-1-CYCLOHEXYL-BUT-3-ENYLOXY]-SILANE](/api/compound/Cffg8XrrLn0.png?h=300&w=458 "(-)-TRIETHYL-[(Z)-(1R,2R)-2-ISOPROPYL-3-METHYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-1-CYCLOHEXYL-BUT-3-ENYLOXY]-SILANE")
Compound 15E (+)-TRIETHYL-[(Z)-(1R,2R)-1,2-DIPHENYL-3-METHYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-BUT-3-ENYLOXY]-SILANE
![(+)-TRIETHYL-[(Z)-(1R,2R)-1,2-DIPHENYL-3-METHYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-BUT-3-ENYLOXY]-SILANE](/api/compound/11sZoAjUmA1.png?h=300&w=458 "(+)-TRIETHYL-[(Z)-(1R,2R)-1,2-DIPHENYL-3-METHYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-BUT-3-ENYLOXY]-SILANE")
Compound 15F (+)-TRIETHYL-[(Z)-(1R,2R)-2-PHENYL-3-METHYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-1-(4-METHOXYPHENYL)-BUT-3-ENYLOXY]-SILANE
![(+)-TRIETHYL-[(Z)-(1R,2R)-2-PHENYL-3-METHYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-1-(4-METHOXYPHENYL)-BUT-3-ENYLOXY]-SILANE](/api/compound/LRLW8yw2cny.png?h=300&w=458 "(+)-TRIETHYL-[(Z)-(1R,2R)-2-PHENYL-3-METHYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-1-(4-METHOXYPHENYL)-BUT-3-ENYLOXY]-SILANE")
Compound 15G (+)-TRIETHYL-[(Z)-(1R,2R)-2-PHENYL-3-METHYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-1-(4-BROMOPHENYL)-BUT-3-ENYLOXY]-SILANE
![(+)-TRIETHYL-[(Z)-(1R,2R)-2-PHENYL-3-METHYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-1-(4-BROMOPHENYL)-BUT-3-ENYLOXY]-SILANE](/api/compound/4YcYNGM2ghw.png?h=300&w=458 "(+)-TRIETHYL-[(Z)-(1R,2R)-2-PHENYL-3-METHYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-1-(4-BROMOPHENYL)-BUT-3-ENYLOXY]-SILANE")
Compound 15H (+)-TRIETHYL-[(Z)-(1S,2R)-2-PHENYL-3-METHYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-1-CYCLOHEXYL-BUT-3-ENYLOXY]-SILANE
![(+)-TRIETHYL-[(Z)-(1S,2R)-2-PHENYL-3-METHYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-1-CYCLOHEXYL-BUT-3-ENYLOXY]-SILANE](/api/compound/HEaPC3gG1cz.png?h=300&w=458 "(+)-TRIETHYL-[(Z)-(1S,2R)-2-PHENYL-3-METHYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-1-CYCLOHEXYL-BUT-3-ENYLOXY]-SILANE")
Compound 16 N,N-Dimethylbenzenesulfinamide
Compound 17C ENT-(-)-(R)-S-(1-CYCLOOCTEN-1-YL-METHYL)-N-METHYL-S-PHENYLSULFOXIMINE
Compound 18A (-)-TRIETHYL-[(Z)-(ALPHA-R,1R)-ALPHA-(4-METHOXYPHENYL)-2-[[(S)-N-METHYL-S-PHENYLSULFONIMIDOYL]-METHENE]-CYCLOHEXANE-METHANE-ALPHA-ENYLOXY]-SILANE
![(-)-TRIETHYL-[(Z)-(ALPHA-R,1R)-ALPHA-(4-METHOXYPHENYL)-2-[[(S)-N-METHYL-S-PHENYLSULFONIMIDOYL]-METHENE]-CYCLOHEXANE-METHANE-ALPHA-ENYLOXY]-SILANE](/api/compound/LqRlSLSNIfy.png?h=300&w=458 "(-)-TRIETHYL-[(Z)-(ALPHA-R,1R)-ALPHA-(4-METHOXYPHENYL)-2-[[(S)-N-METHYL-S-PHENYLSULFONIMIDOYL]-METHENE]-CYCLOHEXANE-METHANE-ALPHA-ENYLOXY]-SILANE")
Compound 28 Methyl phenyl sulfoxide
#18B;(-)-TRIETHYL-[(Z)-(ALPHA-R,1R)-ALPHA-(4-METHOXYPHENYL)-2-[[(S)-N-METHYL-S-PHENYLSULFONIMIDOYL]-METHENE]-CYCLOHEPTANE-METHANE-ALPHA-ENYLOXY]-SILANE
![#18B;(-)-TRIETHYL-[(Z)-(ALPHA-R,1R)-ALPHA-(4-METHOXYPHENYL)-2-[[(S)-N-METHYL-S-PHENYLSULFONIMIDOYL]-METHENE]-CYCLOHEPTANE-METHANE-ALPHA-ENYLOXY]-SILANE](/api/compound/36sGSOALtZW.png?h=300&w=458 "#18B;(-)-TRIETHYL-[(Z)-(ALPHA-R,1R)-ALPHA-(4-METHOXYPHENYL)-2-[[(S)-N-METHYL-S-PHENYLSULFONIMIDOYL]-METHENE]-CYCLOHEPTANE-METHANE-ALPHA-ENYLOXY]-SILANE")
#18C;ENT-(+)-TRIETHYL-[(Z)-(ALPHA-S,1S)-ALPHA-(4-METHOXYPHENYL)-2-[[(R)-N-METHYL-S-PHENYLSULFONIMIDOYL]-METHENE]-CYCLOOCTANE-METHANE-ALPHA-ENYLOXY]-SILANE
![#18C;ENT-(+)-TRIETHYL-[(Z)-(ALPHA-S,1S)-ALPHA-(4-METHOXYPHENYL)-2-[[(R)-N-METHYL-S-PHENYLSULFONIMIDOYL]-METHENE]-CYCLOOCTANE-METHANE-ALPHA-ENYLOXY]-SILANE](/api/compound/ItAJtMmZgtc.png?h=300&w=458 "#18C;ENT-(+)-TRIETHYL-[(Z)-(ALPHA-S,1S)-ALPHA-(4-METHOXYPHENYL)-2-[[(R)-N-METHYL-S-PHENYLSULFONIMIDOYL]-METHENE]-CYCLOOCTANE-METHANE-ALPHA-ENYLOXY]-SILANE")
Citation
| Citation | J.AM.CHEM.SOC.,126,4859(2004) |
|---|---|
| Journal | Journal of the American Chemical Society |
| Issue | 15 |
| Volume | 126 |
| Page(s) | 4859-4864 |
| Year | 2004 |
| Author(s) | Hans-Joachim Gais, Leleti R. Reddy, Gadamsetti S. Babu, Gerhard Raabe |
| Publisher | American Chemical Society (ACS) |
| DOI | 10.1021/ja030501v |