#18C;ENT-(+)-TRIETHYL-[(Z)-(ALPHA-S,1S)-ALPHA-(4-METHOXYPHENYL)-2-[[(R)-N-METHYL-S-PHENYLSULFONIMIDOYL]-METHENE]-CYCLOOCTANE-METHANE-ALPHA-ENYLOXY]-SILANE
Compound with spectra: 1 NMR
![#18C;ENT-(+)-TRIETHYL-[(Z)-(ALPHA-S,1S)-ALPHA-(4-METHOXYPHENYL)-2-[[(R)-N-METHYL-S-PHENYLSULFONIMIDOYL]-METHENE]-CYCLOOCTANE-METHANE-ALPHA-ENYLOXY]-SILANE](/api/compound/ItAJtMmZgtc.png?ph=true&h=300&w=458 "#18C;ENT-(+)-TRIETHYL-[(Z)-(ALPHA-S,1S)-ALPHA-(4-METHOXYPHENYL)-2-[[(R)-N-METHYL-S-PHENYLSULFONIMIDOYL]-METHENE]-CYCLOOCTANE-METHANE-ALPHA-ENYLOXY]-SILANE")
| SpectraBase Compound ID | ItAJtMmZgtc |
|---|---|
| InChI | InChI=1S/C30H45NO3SSi/c1-6-36(7-2,8-3)34-30(25-20-22-27(33-5)23-21-25)29-19-15-10-9-12-16-26(29)24-35(32,31-4)28-17-13-11-14-18-28/h11,13-14,17-18,20-24,29-30H,6-10,12,15-16,19H2,1-5H3/b26-24-/t29-,30+,35?/m1/s1 |
| InChIKey | WENJUSZBGDAWLP-FFTWYZLASA-N |
| Mol Weight | 527.8 g/mol |
| Molecular Formula | C30H45NO3SSi |
| Exact Mass | 527.288942 g/mol |
| Enantiomer InChIKey | WENJUSZBGDAWLP-XROKGGQJSA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
#18B;(-)-TRIETHYL-[(Z)-(ALPHA-R,1R)-ALPHA-(4-METHOXYPHENYL)-2-[[(S)-N-METHYL-S-PHENYLSULFONIMIDOYL]-METHENE]-CYCLOHEPTANE-METHANE-ALPHA-ENYLOXY]-SILANE
(-)-TRIETHYL-[(Z)-(ALPHA-R,1R)-ALPHA-(4-METHOXYPHENYL)-2-[[(S)-N-METHYL-S-PHENYLSULFONIMIDOYL]-METHENE]-CYCLOHEXANE-METHANE-ALPHA-ENYLOXY]-SILANE
(+)-TRIETHYL-[(Z)-(1R,2R)-2-PHENYL-3-METHYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-1-(4-BROMOPHENYL)-BUT-3-ENYLOXY]-SILANE
(8R,9S,E)-8-Isopropyl-10-methyl-6-(N-methylphenylsulfonimidoyl)-9-(triethylsilyloxy)-undeca-1,6-dien-5-one
(3aS,4S,5R,6aR)-5-(tert-Butyl-dimethyl-silanyloxy)-4-{4-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-hexyl]-phenyl}-hexahydro-pentalen-2-one
acetamide, N-(3-hydroxyphenyl)-2-[[3-(4-methoxyphenoxy)-2-methyl-4-oxo-4H-1-benzopyran-7-yl]oxy]-
N-{(3'aS,4'R,6'aR)-4'-[4-((S)-1'-(t-butyldimethylsilyl-oxyhexyl)phenyl]-1',6'a',6',3'a-tetrahydro-5,5-dimethylspiro[1,3-dioxane-2,2'-pentalen])-5'-ol
exo-5-(syn-(2,3)-3-dimethyltertbutylsiloxy-2-methyl-3-phenyl-1-propanon-1-yl)-endo-5-methylbicyclo[2.2.1]hept-2-ene
(1E,5E)-1,3-Diphenyl-6-(N-t-Butyldiphenylsilyl-S-phenylsulfonimidoyl)-1,5-hexadien-3-ol
(2R,3R,3aS,4R,6S,6aS)-3-butyl-4,6-dimethylol-2-phenyl-3,3a,4,5,6,6a-hexahydro-2H-pentalen-1-one
| Title | Journal or Book | Year |
|---|---|---|
| Asymmetric Synthesis of 2,3-Dihydrofurans and of Unsaturated Bicyclic Tetrahydrofurans through α-Elimination and Migratory Cyclization of Silyloxy Alkenyl Aminosulfoxonium Salts. Generation and Intramolecular O,Si-Bond Insertion of Chiral Disubstituted β-Silyloxy Alkylidene Carbenes | Journal of the American Chemical Society | 2004 |