(-)-TRIETHYL-[(Z)-(ALPHA-R,1R)-ALPHA-(4-METHOXYPHENYL)-2-[[(S)-N-METHYL-S-PHENYLSULFONIMIDOYL]-METHENE]-CYCLOHEXANE-METHANE-ALPHA-ENYLOXY]-SILANE
Compound with spectra: 1 NMR
![(-)-TRIETHYL-[(Z)-(ALPHA-R,1R)-ALPHA-(4-METHOXYPHENYL)-2-[[(S)-N-METHYL-S-PHENYLSULFONIMIDOYL]-METHENE]-CYCLOHEXANE-METHANE-ALPHA-ENYLOXY]-SILANE](/api/compound/LqRlSLSNIfy.png?ph=true&h=300&w=458 "(-)-TRIETHYL-[(Z)-(ALPHA-R,1R)-ALPHA-(4-METHOXYPHENYL)-2-[[(S)-N-METHYL-S-PHENYLSULFONIMIDOYL]-METHENE]-CYCLOHEXANE-METHANE-ALPHA-ENYLOXY]-SILANE")
| SpectraBase Compound ID | LqRlSLSNIfy |
|---|---|
| InChI | InChI=1S/C28H41NO3SSi/c1-6-34(7-2,8-3)32-28(23-18-20-25(31-5)21-19-23)27-17-13-12-14-24(27)22-33(30,29-4)26-15-10-9-11-16-26/h9-11,15-16,18-22,27-28H,6-8,12-14,17H2,1-5H3/b24-22-/t27-,28+,33?/m1/s1 |
| InChIKey | AEPCRURJHHEKOU-UQWHFJPHSA-N |
| Mol Weight | 499.8 g/mol |
| Molecular Formula | C28H41NO3SSi |
| Exact Mass | 499.257642 g/mol |
| Enantiomer InChIKey | AEPCRURJHHEKOU-MTGFHXRYSA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
(+)-TRIETHYL-[(Z)-(1R,2R)-1,2-DIPHENYL-3-METHYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-BUT-3-ENYLOXY]-SILANE
(+)-TRIETHYL-[(Z)-(1S,2R)-2-PHENYL-3-METHYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-1-CYCLOHEXYL-BUT-3-ENYLOXY]-SILANE
(3aS,4S,5R,6aR)-5-(tert-Butyl-dimethyl-silanyloxy)-4-{4-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-hexyl]-phenyl}-hexahydro-pentalen-2-one
exo-5-(syn-(2,3)-3-dimethyltertbutylsiloxy-2-methyl-3-phenyl-1-propanon-1-yl)-endo-5-methylbicyclo[2.2.1]hept-2-ene
(1E,5E)-1,3-Diphenyl-6-(N-t-Butyldiphenylsilyl-S-phenylsulfonimidoyl)-1,5-hexadien-3-ol
N-{(3'aS,4'R,6'aR)-4'-[4-((S)-1'-(t-butyldimethylsilyl-oxyhexyl)phenyl]-1',6'a',6',3'a-tetrahydro-5,5-dimethylspiro[1,3-dioxane-2,2'-pentalen])-5'-ol
(2S,3R)-2-(3,4-Methylenedioxybenzyl)-3-[(S)-(3,4-methylidenedioxyphenyl)(triethylsiloxy)methyl]-4-butane-1,4-diol
(22-E)-DE-A,B-8-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-24-NORCHOL-22-ENE-23-PHENYLSULFONE
3-but-3-en-2-yl-4,6-dimethoxy-3H-2-benzofuran-1-one
2-(3-fluorobenzyl)-1-(4-methoxyphenyl)octahydro-4a(2H)-isoquinolinol
| Title | Journal or Book | Year |
|---|---|---|
| Asymmetric Synthesis of 2,3-Dihydrofurans and of Unsaturated Bicyclic Tetrahydrofurans through α-Elimination and Migratory Cyclization of Silyloxy Alkenyl Aminosulfoxonium Salts. Generation and Intramolecular O,Si-Bond Insertion of Chiral Disubstituted β-Silyloxy Alkylidene Carbenes | Journal of the American Chemical Society | 2004 |