John Wiley & Sons, Inc. SpectraBase; SpectraBase Compound ID=LqRlSLSNIfy

(accessed ).
(-)-TRIETHYL-[(Z)-(ALPHA-R,1R)-ALPHA-(4-METHOXYPHENYL)-2-[[(S)-N-METHYL-S-PHENYLSULFONIMIDOYL]-METHENE]-CYCLOHEXANE-METHANE-ALPHA-ENYLOXY]-SILANE
SpectraBase Compound ID LqRlSLSNIfy
InChI InChI=1S/C28H41NO3SSi/c1-6-34(7-2,8-3)32-28(23-18-20-25(31-5)21-19-23)27-17-13-12-14-24(27)22-33(30,29-4)26-15-10-9-11-16-26/h9-11,15-16,18-22,27-28H,6-8,12-14,17H2,1-5H3/b24-22-/t27-,28+,33?/m1/s1
InChIKey AEPCRURJHHEKOU-UQWHFJPHSA-N
Mol Weight 499.8 g/mol
Molecular Formula C28H41NO3SSi
Exact Mass 499.257645 g/mol
Enantiomer InChIKey AEPCRURJHHEKOU-MTGFHXRYSA-N
Copyright Copyright © 2016-2020 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
Title Journal or Book Year
Asymmetric Synthesis of 2,3-Dihydrofurans and of Unsaturated Bicyclic Tetrahydrofurans through α-Elimination and Migratory Cyclization of Silyloxy Alkenyl Aminosulfoxonium Salts. Generation and Intramolecular O,Si-Bond Insertion of Chiral Disubstituted β-Silyloxy Alkylidene Carbenes Journal of the American Chemical Society 2004
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