(+)-TRIETHYL-[(Z)-(1R,2R)-2-PHENYL-3-METHYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-1-(4-BROMOPHENYL)-BUT-3-ENYLOXY]-SILANE
Compound with spectra: 1 NMR
![(+)-TRIETHYL-[(Z)-(1R,2R)-2-PHENYL-3-METHYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-1-(4-BROMOPHENYL)-BUT-3-ENYLOXY]-SILANE](/api/compound/4YcYNGM2ghw.png?ph=true&h=300&w=458 "(+)-TRIETHYL-[(Z)-(1R,2R)-2-PHENYL-3-METHYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-1-(4-BROMOPHENYL)-BUT-3-ENYLOXY]-SILANE")
| SpectraBase Compound ID | 4YcYNGM2ghw |
|---|---|
| InChI | InChI=1S/C30H38BrNO2SSi/c1-6-36(7-2,8-3)34-30(26-19-21-27(31)22-20-26)29(25-15-11-9-12-16-25)24(4)23-35(33,32-5)28-17-13-10-14-18-28/h9-23,29-30H,6-8H2,1-5H3/b24-23-/t29-,30-,35?/m0/s1 |
| InChIKey | IHOHEZTWQVEOIU-HQMRDWSTSA-N |
| Mol Weight | 584.7 g/mol |
| Molecular Formula | C30H38BrNO2SSi |
| Exact Mass | 583.15759 g/mol |
| Enantiomer InChIKey | IHOHEZTWQVEOIU-JCFVGWAWSA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
(+)-TRIETHYL-[(Z)-(1R,2R)-2-PHENYL-3-METHYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-1-(4-METHOXYPHENYL)-BUT-3-ENYLOXY]-SILANE
(-)-TRIETHYL-[(Z)-(ALPHA-R,1R)-ALPHA-(4-METHOXYPHENYL)-2-[[(S)-N-METHYL-S-PHENYLSULFONIMIDOYL]-METHENE]-CYCLOHEXANE-METHANE-ALPHA-ENYLOXY]-SILANE
#18C;ENT-(+)-TRIETHYL-[(Z)-(ALPHA-S,1S)-ALPHA-(4-METHOXYPHENYL)-2-[[(R)-N-METHYL-S-PHENYLSULFONIMIDOYL]-METHENE]-CYCLOOCTANE-METHANE-ALPHA-ENYLOXY]-SILANE
#18B;(-)-TRIETHYL-[(Z)-(ALPHA-R,1R)-ALPHA-(4-METHOXYPHENYL)-2-[[(S)-N-METHYL-S-PHENYLSULFONIMIDOYL]-METHENE]-CYCLOHEPTANE-METHANE-ALPHA-ENYLOXY]-SILANE
(2S,3R)-4,4,4-Trifluoro-3-hydroxy-2,3-dimethyl-butyric acid (R)-1,2,2-triphenyl-2-trimethylsilanyloxy-ethyl ester
3-Cyano-2,4,5-triphenyl-4,5-dihydrofuran
cis-2-((E)-1-(Ethoxycarbonyl)butylidene)-4-(4-cyanophenyl)-3-phenyloxetane
(3aS,4S,5R,6aR)-5-(tert-Butyl-dimethyl-silanyloxy)-4-{4-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-hexyl]-phenyl}-hexahydro-pentalen-2-one
6,11[1',2']-Benzeno-1,4-epoxynaphthacene, 1,4,6,11-tetrahydro-
trans-4-styryl-1,3,4-triphenylcyclohexene
| Title | Journal or Book | Year |
|---|---|---|
| Asymmetric Synthesis of 2,3-Dihydrofurans and of Unsaturated Bicyclic Tetrahydrofurans through α-Elimination and Migratory Cyclization of Silyloxy Alkenyl Aminosulfoxonium Salts. Generation and Intramolecular O,Si-Bond Insertion of Chiral Disubstituted β-Silyloxy Alkylidene Carbenes | Journal of the American Chemical Society | 2004 |