(-)-S-N,N-DIMETHYLAMINO-S-[(Z)-(3R,4R)-2-METHYL-3-PHENYL-(4-METHOXYPHENYL)-4-(TRIETHYLSILYL)-OXY]-BUT-ENYL-PHENYL-SULFOXINIUM-TETRAFLUOROBORATE
Compound with spectra: 1 NMR
![(-)-S-N,N-DIMETHYLAMINO-S-[(Z)-(3R,4R)-2-METHYL-3-PHENYL-(4-METHOXYPHENYL)-4-(TRIETHYLSILYL)-OXY]-BUT-ENYL-PHENYL-SULFOXINIUM-TETRAFLUOROBORATE](/api/compound/FVYMHIPjdBO.png?ph=true&h=300&w=458 "(-)-S-N,N-DIMETHYLAMINO-S-[(Z)-(3R,4R)-2-METHYL-3-PHENYL-(4-METHOXYPHENYL)-4-(TRIETHYLSILYL)-OXY]-BUT-ENYL-PHENYL-SULFOXINIUM-TETRAFLUOROBORATE")
| SpectraBase Compound ID | FVYMHIPjdBO |
|---|---|
| InChI | InChI=1S/C32H44NO3SSi.BF4/c1-8-38(9-2,10-3)36-32(28-21-23-29(35-7)24-22-28)31(27-17-13-11-14-18-27)26(4)25-37(34,33(5)6)30-19-15-12-16-20-30;2-1(3,4)5/h11-25,31-32H,8-10H2,1-7H3;/q+1;-1/b26-25-;/t31-,32-,37?;/m0./s1 |
| InChIKey | BGMGQRSVGHHFAC-PZMFACDNSA-N |
| Mol Weight | 637.7 g/mol |
| Molecular Formula | C32H44BF4NO3SSi |
| Exact Mass | 637.284035 g/mol |
| Parent InChIKey | XCRVJQJHBBESOM-OJHMKRPRSA-N |
| Enantiomer InChIKey | BGMGQRSVGHHFAC-QQQJSEPLSA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
(+)-TRIETHYL-[(Z)-(1R,2R)-2-PHENYL-3-METHYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-1-(4-METHOXYPHENYL)-BUT-3-ENYLOXY]-SILANE
(1S,2R)/(1R,2S)-2-[4-(tert-Butyl)phenyl]-3-(4-chlorophenyl)-3-oxo-1-(3,4,5-trimethoxyphenyl)propyl Acetate
(3S,4S)-3-methyl-3,4-diphenyl-4-(trifluoromethyl)oxetan-2-one
(1S,2R)/(1R,2S)-3-(4-Chlorophenyl)-3-oxo-2-phenyl-1-(3,4,5-trimethoxyphenyl)propyl Propionate
5H-Dibenzo[a,d]cycloheptene-10-carboxylic acid, 10,11-dihydro-11-(methoxymethyl)-, (10R-trans)-
endo-8-(Ethoxycarbonyl)-8-phenyl-7-oxabicyclo[4.2.0]oct-2-ene
2-amino-6-(ethylthio)-3,4-diphenyl-3,4-dihydropyridine-5-carbonitrile
1-[4,5-Dihydro-2-methyl-4-phenyl-5-(2-thienyl)furan-3-yl]ethanone
Methyl 5-(tert-butylimino)-2-(dichloromethyl)-2-phenyl-2,5-dihydrofuran-3-carboxylate
(9R,10S,E)-9-Isopropyl-11-methyl-7-[(S)-N-methyl-S-phenyl-sulfonimidoyl)]-10-(triethylsilyloxy)dodeca-1,7-dien-6-one
| Title | Journal or Book | Year |
|---|---|---|
| Asymmetric Synthesis of 2,3-Dihydrofurans and of Unsaturated Bicyclic Tetrahydrofurans through α-Elimination and Migratory Cyclization of Silyloxy Alkenyl Aminosulfoxonium Salts. Generation and Intramolecular O,Si-Bond Insertion of Chiral Disubstituted β-Silyloxy Alkylidene Carbenes | Journal of the American Chemical Society | 2004 |