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(2S,3R,4R,6S)-4-[(S)-(TERT.-BUTYLDIMETHYLSILOXY)-6-ETHYNYL-2-METHOXY-3,4,5,6-TETRAHYDRO-2H-PYRAN-3-YL]-2-(4-METHOXYBENZYLOXY)-ETHANOL

Compound with spectra: 2 NMR

(2S,3R,4R,6S)-4-[(S)-(TERT.-BUTYLDIMETHYLSILOXY)-6-ETHYNYL-2-METHOXY-3,4,5,6-TETRAHYDRO-2H-PYRAN-3-YL]-2-(4-METHOXYBENZYLOXY)-ETHANOL
SpectraBase Compound ID CuHiJJAZTNF
InChI InChI=1S/C24H38O6Si/c1-9-18-14-21(30-31(7,8)24(2,3)4)22(23(27-6)29-18)20(25)16-28-15-17-10-12-19(26-5)13-11-17/h1,10-13,18,20-23,25H,14-16H2,2-8H3/t18-,20-,21-,22+,23+/m1/s1
InChIKey FTQMHUNTNJKHCR-FXILAVBZSA-N
Mol Weight 450.6 g/mol
Molecular Formula C24H38O6Si
Exact Mass 450.243765 g/mol
Enantiomer InChIKey FTQMHUNTNJKHCR-YRFMLNNJSA-N

View Spectrum of (2S,3R,4R,6S)-4-[(S)-(TERT.-BUTYLDIMETHYLSILOXY)-6-ETHYNYL-2-METHOXY-3,4,5,6-TETRAHYDRO-2H-PYRAN-3-YL]-2-(4-METHOXYBENZYLOXY)-ETHANOL

29Si NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3

View Spectrum of (2S,3R,4R,6S)-4-[(S)-(TERT.-BUTYLDIMETHYLSILOXY)-6-ETHYNYL-2-METHOXY-3,4,5,6-TETRAHYDRO-2H-PYRAN-3-YL]-2-(4-METHOXYBENZYLOXY)-ETHANOL

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
(S)-1-[(2S,3S,4R,6S)-4-[DIMETHYL-(1,1,2-TRIMETHYLPROPYL)-SILOXY]-6-ETHYNYL-2-METHOXY-3,4,5,6-TETRAHYDRO-2H-PYRAN-3-YL]-ETHANE-1,2-DIOL
(2S,3R,4R,6S)-3-[(S)-1-(TERT.-BUTYLDIMETHYLSILOXY)-2-[(4-METHOXYBENZYLOXY)-ETHYL]-6-ETHYNYL-2-METHOXY-3,4,5,6-TETRAHYDO-2H-PYRAN-4-OL
[DIMETHYL-(1,1,2-TRIMETHYLPROPYL)]-[(2S,3S,4R,6S)-6-ETHYNYL-2-METHOXY-3-[(S)-OXIRAN-2-YL]-3,4,5,6-TETRAHYDRO-2H-PYRAN-4-YL-OXY]-DIMETHYLSILANE
(2S,3S,4R,6S)-6-[(E)-2-BROMOVINYL]-2-METHOXY-3-[(S)-OXIRAN-2-YL]-4-[DIMETHYL-(1,1,2-TRIMETHYLPROPYL)-SILOXY]-3,4,5,6-TETRAHYDRO-2H-PYRAN
tert-Butyl-[(1R)-1-[(4S,5R)-2,2-dimethyl-5-(phenylmethoxymethyl)-1,3-dioxolan-4-yl]non-3-ynoxy]-dimethyl-silane
.beta.-D-Allopyranoside, tetradecyl 6-deoxy-4-O-[(1,1-dimethylethyl)dimethylsilyl]-2,3-di-O-methyl-
Cyclopentanol, 2-butyl-5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3-(1-methyl-1-pheny lethoxy)-, (1.alpha.,2.beta.,3.alpha.,5.beta.)-
(6R,10R,11R,12S,13S)-6-hydroxy-10-[(4-methoxyphenyl)methoxy]-11-methyl-12,13-bis(triethylsilyloxy)hexadec-2-en-14-yn-4-one
(2R,4R,5S,6S,7R)-5,7-Isopropylidenedioxy-6-methoxy4-[2-(4-methoxybenzyloxy)ethyl]-2-methyl-9-decenol
2-[(t-Butyldimethylsilyl)oxy]pentanoyl [3'-[2",2"-dimethyl-5"-[5"'-(4-methoxybenzyloxy)-3"'-methylpent-3''-enyl]-[1",3"]-dioxolan-4"-yl}-2'-[(methoxy)methoxypropyl)-amide
Title Journal or Book Year
Stereocontrolled Synthesis of a Cn-Cn+7Building Block (“Eastern Moiety”) for the Unnatural Enantiomers of Important Polyol,Polyene Antibiotics Based on a Ring-Closing Metathesis and an Aldol Addition of a Lactone Enolate European Journal of Organic Chemistry 2013
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