[DIMETHYL-(1,1,2-TRIMETHYLPROPYL)]-[(2S,3S,4R,6S)-6-ETHYNYL-2-METHOXY-3-[(S)-OXIRAN-2-YL]-3,4,5,6-TETRAHYDRO-2H-PYRAN-4-YL-OXY]-DIMETHYLSILANE
Compound with spectra: 1 NMR
![[DIMETHYL-(1,1,2-TRIMETHYLPROPYL)]-[(2S,3S,4R,6S)-6-ETHYNYL-2-METHOXY-3-[(S)-OXIRAN-2-YL]-3,4,5,6-TETRAHYDRO-2H-PYRAN-4-YL-OXY]-DIMETHYLSILANE](/api/compound/EqzEGtlK7hO.png?ph=true&h=300&w=458 "[DIMETHYL-(1,1,2-TRIMETHYLPROPYL)]-[(2S,3S,4R,6S)-6-ETHYNYL-2-METHOXY-3-[(S)-OXIRAN-2-YL]-3,4,5,6-TETRAHYDRO-2H-PYRAN-4-YL-OXY]-DIMETHYLSILANE")
| SpectraBase Compound ID | EqzEGtlK7hO |
|---|---|
| InChI | InChI=1S/C18H32O4Si/c1-9-13-10-14(16(15-11-20-15)17(19-6)21-13)22-23(7,8)18(4,5)12(2)3/h1,12-17H,10-11H2,2-8H3/t13-,14-,15-,16-,17+/m1/s1 |
| InChIKey | BPBNTMMDBYONKM-HHARLNAUSA-N |
| Mol Weight | 340.5 g/mol |
| Molecular Formula | C18H32O4Si |
| Exact Mass | 340.206986 g/mol |
| Enantiomer InChIKey | BPBNTMMDBYONKM-QUSNUVHPSA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
(S)-1-[(2S,3S,4R,6S)-4-[DIMETHYL-(1,1,2-TRIMETHYLPROPYL)-SILOXY]-6-ETHYNYL-2-METHOXY-3,4,5,6-TETRAHYDRO-2H-PYRAN-3-YL]-ETHANE-1,2-DIOL
(2S,3R,4R,6S)-3-[(S)-1-(TERT.-BUTYLDIMETHYLSILOXY)-2-[(4-METHOXYBENZYLOXY)-ETHYL]-6-ETHYNYL-2-METHOXY-3,4,5,6-TETRAHYDO-2H-PYRAN-4-OL
Cyclopentanol, 2-butyl-5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3-(1-methyl-1-pheny lethoxy)-, (1.alpha.,2.beta.,3.alpha.,5.beta.)-
.beta.-D-Allopyranoside, tetradecyl 6-deoxy-4-O-[(1,1-dimethylethyl)dimethylsilyl]-2,3-di-O-methyl-
3,4,6-Tri(tert-butyldimethylsilyloxy)-1,2-Dioxy-.alpha.,D-gluco-pyranose isomer
(1R,2S,3S,5S)-3,5-Di(methoxymethjoxy)-2-methyl-1-(1,1-dimethylethyl)diphenylsiloxycyclohexane
#10A;(+)-METHYL-(3S,4S,5S,7R,9S,10E)-[7-[2-(TERT.-BUTYLDIMETHYLSILANYLOXY)-PENT-3-ENYL]-4-METHYL-5-(TRIISOPROPYLSILANYLOXY)-TETRAHYDROPYRAN-2-YL]-ACETATE
Methyl 2-O-methyl-per(trimethylsilyl)-.alpha.-D-glucopyranoside
8-(tert-Butyldimethylsiloxy)-8,9-di(hydroxymethyl)bicyclo[4.3.0]nonane
(2R,4S,6R,8R,9S)-2-Allyl-8,9-dimethyl-4-(dimethyl-tert-butyl-silyloxy)-1,7-dioxa-spiro(5.5)undecane
| Title | Journal or Book | Year |
|---|---|---|
| Stereocontrolled Synthesis of a Cn-Cn+7Building Block (“Eastern Moiety”) for the Unnatural Enantiomers of Important Polyol,Polyene Antibiotics Based on a Ring-Closing Metathesis and an Aldol Addition of a Lactone Enolate | European Journal of Organic Chemistry | 2013 |