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(2S,3R,4R,6S)-3-[(S)-1-(TERT.-BUTYLDIMETHYLSILOXY)-2-[(4-METHOXYBENZYLOXY)-ETHYL]-6-ETHYNYL-2-METHOXY-3,4,5,6-TETRAHYDO-2H-PYRAN-4-OL

Compound with spectra: 2 NMR

(2S,3R,4R,6S)-3-[(S)-1-(TERT.-BUTYLDIMETHYLSILOXY)-2-[(4-METHOXYBENZYLOXY)-ETHYL]-6-ETHYNYL-2-METHOXY-3,4,5,6-TETRAHYDO-2H-PYRAN-4-OL
SpectraBase Compound ID FBm9PG0P9gX
InChI InChI=1S/C24H38O6Si/c1-9-18-14-20(25)22(23(27-6)29-18)21(30-31(7,8)24(2,3)4)16-28-15-17-10-12-19(26-5)13-11-17/h1,10-13,18,20-23,25H,14-16H2,2-8H3/t18-,20-,21-,22-,23+/m1/s1
InChIKey RWXRNZVACMWMRV-KNQBKSORSA-N
Mol Weight 450.6 g/mol
Molecular Formula C24H38O6Si
Exact Mass 450.243765 g/mol
Enantiomer InChIKey RWXRNZVACMWMRV-VPSDZCSPSA-N

View Spectrum of (2S,3R,4R,6S)-3-[(S)-1-(TERT.-BUTYLDIMETHYLSILOXY)-2-[(4-METHOXYBENZYLOXY)-ETHYL]-6-ETHYNYL-2-METHOXY-3,4,5,6-TETRAHYDO-2H-PYRAN-4-OL

29Si NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3

View Spectrum of (2S,3R,4R,6S)-3-[(S)-1-(TERT.-BUTYLDIMETHYLSILOXY)-2-[(4-METHOXYBENZYLOXY)-ETHYL]-6-ETHYNYL-2-METHOXY-3,4,5,6-TETRAHYDO-2H-PYRAN-4-OL

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
(S)-1-[(2S,3S,4R,6S)-4-[DIMETHYL-(1,1,2-TRIMETHYLPROPYL)-SILOXY]-6-ETHYNYL-2-METHOXY-3,4,5,6-TETRAHYDRO-2H-PYRAN-3-YL]-ETHANE-1,2-DIOL
[DIMETHYL-(1,1,2-TRIMETHYLPROPYL)]-[(2S,3S,4R,6S)-6-ETHYNYL-2-METHOXY-3-[(S)-OXIRAN-2-YL]-3,4,5,6-TETRAHYDRO-2H-PYRAN-4-YL-OXY]-DIMETHYLSILANE
(1S,2S,4S,5S,6R)-2-Methoxy-6-(methoxymethyl)oxy-4-{[(4'-methoxyphenyl)methyl]oxy}methyl-3-oxabicyclo[3.3.0]octane
.beta.-D-Allopyranoside, tetradecyl 6-deoxy-4-O-[(1,1-dimethylethyl)dimethylsilyl]-2,3-di-O-methyl-
(6R,10R,11R,12S,13S)-6-hydroxy-10-[(4-methoxyphenyl)methoxy]-11-methyl-12,13-bis(triethylsilyloxy)hexadec-2-en-14-yn-4-one
Cyclopentanol, 2-butyl-5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3-(1-methyl-1-pheny lethoxy)-, (1.alpha.,2.beta.,3.alpha.,5.beta.)-
(2R,4R,5S,6S,7R)-5,7-Isopropylidenedioxy-6-methoxy4-[2-(4-methoxybenzyloxy)ethyl]-2-methyl-9-decenol
tert-Butyl-[(1R)-1-[(4S,5R)-2,2-dimethyl-5-(phenylmethoxymethyl)-1,3-dioxolan-4-yl]non-3-ynoxy]-dimethyl-silane
(2S,5S,6S)-6-[2-Benzyloxy-1(S)-methoxyethyl]-5,6-dihydro-2-isopropyloxy-5-[2-(4-methoxybenzyloxy)ethyl]-3-methylpyran
#33;(2R*,3S*,5R*)-(+/-)-5-[[(1,1-DIMETHYLETHYL)-DIMETHYLSILYL]-OXY]-2-[(4-FLOUROPHENOXY)-THIOCARBONYLOXY]-3-(METHOXYMETHOXY)-6-OCTYN-1-YL-2,2-DIMETHYLPROPIONAT
Title Journal or Book Year
Stereocontrolled Synthesis of a Cn-Cn+7Building Block (“Eastern Moiety”) for the Unnatural Enantiomers of Important Polyol,Polyene Antibiotics Based on a Ring-Closing Metathesis and an Aldol Addition of a Lactone Enolate European Journal of Organic Chemistry 2013
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