(2S,3S,4R,6S)-6-[(E)-2-BROMOVINYL]-2-METHOXY-3-[(S)-OXIRAN-2-YL]-4-[DIMETHYL-(1,1,2-TRIMETHYLPROPYL)-SILOXY]-3,4,5,6-TETRAHYDRO-2H-PYRAN
Compound with spectra: 1 NMR
![(2S,3S,4R,6S)-6-[(E)-2-BROMOVINYL]-2-METHOXY-3-[(S)-OXIRAN-2-YL]-4-[DIMETHYL-(1,1,2-TRIMETHYLPROPYL)-SILOXY]-3,4,5,6-TETRAHYDRO-2H-PYRAN](/api/compound/3dcRQmgB5nM.png?ph=true&h=300&w=458 "(2S,3S,4R,6S)-6-[(E)-2-BROMOVINYL]-2-METHOXY-3-[(S)-OXIRAN-2-YL]-4-[DIMETHYL-(1,1,2-TRIMETHYLPROPYL)-SILOXY]-3,4,5,6-TETRAHYDRO-2H-PYRAN")
| SpectraBase Compound ID | 3dcRQmgB5nM |
|---|---|
| InChI | InChI=1S/C18H33BrO4Si/c1-12(2)18(3,4)24(6,7)23-14-10-13(8-9-19)22-17(20-5)16(14)15-11-21-15/h8-9,12-17H,10-11H2,1-7H3/b9-8+/t13-,14-,15-,16-,17+/m1/s1 |
| InChIKey | JZTAWIRUPYJYSE-JHPHETSHSA-N |
| Mol Weight | 421.4 g/mol |
| Molecular Formula | C18H33BrO4Si |
| Exact Mass | 420.133149 g/mol |
| Enantiomer InChIKey | JZTAWIRUPYJYSE-ZGSMWXOJSA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
(2S,3R,4R,6S)-4-[(S)-(TERT.-BUTYLDIMETHYLSILOXY)-6-ETHYNYL-2-METHOXY-3,4,5,6-TETRAHYDRO-2H-PYRAN-3-YL]-2-(4-METHOXYBENZYLOXY)-ETHANOL
#12;(+)-METHYL-(3S,4S,5S,7R,9S,10R,11R)-9-(TERT.-BUTYLDIMETHYLSILANYLOXY)-4-METHYL-5-TRIISOPROPYLSILANYLOXY-BICYCLOMETHANO-[1(10,11)]-OXA-[1(3,7)]-DODECANOATE
(3R,4S,5R)-5-[tert-butyl(dimethyl)silyl]oxy-3-ethenyl-5-[(4S,5R)-2,2,5-trimethyl-1,3-dioxolan-4-yl]pentane-1,4-diol
7-(2-(3,8-di(trimethylsiloxy)-1-octenyl)-4,6-di(trimethylsiloxy)-2,3,5,6-tetrahydro-1,4-pyran-3-yl)-5(Z)-heptenoic acid methyl ester
Thromboxane B2, methyl ester, tris(trimethylsilyl)- deriv.
2,4-Di(trimethylsiloxy)-5-(8-(methoxycarbonyl)-2(Z),5(Z)-octadienyl)-6-(3-(triemthylsiloxy)-1(E)-octenyl)-1-oxacyclohexane
(1R,2S,3S,4R,6R,7S)-1,4-DI-O-TERT.-BUTYLDIMETHYLSILYL-2,3-O-METHYLETHYLIDENE-CYCLOOCTANE-1,2,3,4,6,7-HEXOL
(1S,2S,3S,4S,6R,7S)-1,4-DI-O-TERT.-BUTYLDIMETHYLSILYL-2,3-O-METHYLETHYLIDENE-CYCLOOCTANE-1,2,3,4,6,7-HEXOL
(1R,2S,3S,5S)-3,5-Di(methoxymethjoxy)-2-methyl-1-(1,1-dimethylethyl)diphenylsiloxycyclohexane
7,9-(p-Methoxyphenylidenedioxy)-5-methoxy-1-tert-butyldimethylsilyl-2,4,6,8-tetraamethylnonan-1,3-diol
| Title | Journal or Book | Year |
|---|---|---|
| Stereocontrolled Synthesis of a Cn-Cn+7Building Block (“Eastern Moiety”) for the Unnatural Enantiomers of Important Polyol,Polyene Antibiotics Based on a Ring-Closing Metathesis and an Aldol Addition of a Lactone Enolate | European Journal of Organic Chemistry | 2013 |