(1S,4R,5S)-4-[(1S)-1-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-HYDROXYETHYL]-7,7-DIMETHYL-1-VINYL-2-OXABICYCLO-[3.2.0]-HEPTAN-3-ONE
Compound with spectra: 1 NMR
![(1S,4R,5S)-4-[(1S)-1-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-HYDROXYETHYL]-7,7-DIMETHYL-1-VINYL-2-OXABICYCLO-[3.2.0]-HEPTAN-3-ONE](/api/compound/Vj58sg31aS.png?ph=true&h=300&w=458 "(1S,4R,5S)-4-[(1S)-1-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-HYDROXYETHYL]-7,7-DIMETHYL-1-VINYL-2-OXABICYCLO-[3.2.0]-HEPTAN-3-ONE")
| SpectraBase Compound ID | Vj58sg31aS |
|---|---|
| InChI | InChI=1S/C18H32O4Si/c1-9-18-12(10-17(18,5)6)14(15(20)21-18)13(11-19)22-23(7,8)16(2,3)4/h9,12-14,19H,1,10-11H2,2-8H3/t12-,13-,14+,18+/m1/s1 |
| InChIKey | ILAPHFJIKOOOFP-ZXTQRBJTSA-N |
| Mol Weight | 340.5 g/mol |
| Molecular Formula | C18H32O4Si |
| Exact Mass | 340.206986 g/mol |
| Enantiomer InChIKey | ILAPHFJIKOOOFP-UYAYXHRUSA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
#26;(1S,3R,4S,5R)-4-[(1S)-1-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-(TRIETHYLSILYLOXY)-ETHYL]-7,7-DIMETHYL-1-VINYL-2-OXABICYCLO-[3.2.0]-HEPTAN-3-OL;MAJOR-ISOMER
No Name
11-B-H-ELEMA-1,3-DIEN-12,6-A-OLIDE,8-A,15-DIHYDROXY
ZAKDJVVJTNQRTN-OOQIBZCKSA-N
11,12-Dehydrolanuginolide
1BETA-HYDROXY-8BETA-ACETOXY-ISOCOSTIC_ACID_METHYLESTER
(4aS,4bR,7aS,7bR)-2,2-Dimethyl-4-oxooctahydrocyclopenta[3,4]cyclobuta[1,2-b]pyran-7b(2H)-carboxylic acid
rel-(1R,3aS,7R,7aS)-1-[2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-1-(S)-methylethyl]-1,2,3,6,7,7a-hexahydro-7-3a-(epoxymethano)3aH-inden-9-one
(1R*,3aR*,4R*,7aS*)-1-[(tert-Butyldimethylsilyl)oxy]-3a,4-epoxy-7a-methylperhydroinden-5-one
| Title | Journal or Book | Year |
|---|---|---|
| The Remarkable Effect of Cosolvent on a Samarium(II)-Mediated 4-exo-trig Cyclization: Further Synthetic Studies on Pestalotiopsin A | The Journal of Organic Chemistry | 2003 |