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#26;(1S,3R,4S,5R)-4-[(1S)-1-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-(TRIETHYLSILYLOXY)-ETHYL]-7,7-DIMETHYL-1-VINYL-2-OXABICYCLO-[3.2.0]-HEPTAN-3-OL;MAJOR-ISOMER

Compound with spectra: 2 NMR

#26;(1S,3R,4S,5R)-4-[(1S)-1-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-(TRIETHYLSILYLOXY)-ETHYL]-7,7-DIMETHYL-1-VINYL-2-OXABICYCLO-[3.2.0]-HEPTAN-3-OL;MAJOR-ISOMER
SpectraBase Compound ID JNfTdZEN8nX
InChI InChI=1S/C24H48O4Si2/c1-12-24-18(16-23(24,8)9)20(21(25)27-24)19(28-29(10,11)22(5,6)7)17-26-30(13-2,14-3)15-4/h12,18-21,25H,1,13-17H2,2-11H3/t18-,19+,20+,21-,24+/m1/s1
InChIKey RUDVRYGWQBTASX-ZTGMJEERSA-N
Mol Weight 456.8 g/mol
Molecular Formula C24H48O4Si2
Exact Mass 456.309113 g/mol
Enantiomer InChIKey RUDVRYGWQBTASX-QYUWHHMLSA-N

View Spectrum of #26;(1S,3R,4S,5R)-4-[(1S)-1-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-(TRIETHYLSILYLOXY)-ETHYL]-7,7-DIMETHYL-1-VINYL-2-OXABICYCLO-[3.2.0]-HEPTAN-3-OL;MAJOR-ISOMER

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3

View Spectrum of #26;(1S,3R,4S,5R)-4-[(1S)-1-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-(TRIETHYLSILYLOXY)-ETHYL]-7,7-DIMETHYL-1-VINYL-2-OXABICYCLO-[3.2.0]-HEPTAN-3-OL;MAJOR-ISOMER

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
  • #26;(1S,3R,4S,5R)-4-[(1S)-1-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-(TRIETHYLSILYLOXY)-ETHYL]-7,7-DIMETHYL-1-VINYL-2-OXABICYCLO-[3.2.0]-HEPTAN-3-OL;MINOR-ISOMER
(1S,4R,5S)-4-[(1S)-1-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-HYDROXYETHYL]-7,7-DIMETHYL-1-VINYL-2-OXABICYCLO-[3.2.0]-HEPTAN-3-ONE
(1S,4S,5R)-4-[(1S)-1-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-HYDROXYETHYL]-7,7-DIMETHYL-1-VINYL-2-OXABICYCLO-[3.2.0]-HEPTAN-3-ONE
1,6-ANHYDRO-2,4-BIS-O-(TERT.-BUTYLDIMETHYLSILYL)-3-DEOXY-3-N-((3'R,4'R)-3',4'-BIS-O-HYDROXY)-TATARIMIDO-BETA-D-GLUCOPYRANOSE
10-DEANGELOYLPALLININ
(2S*)-3-[2'-(1''-Hydroxy-3"-phenylpropyl)phenoxy]-2-(octahydro-7"',8"',8''-trimethyl-4'',7''-methano-2"'-benzofuranyl)oxy]-1-propylamine
8-ALPHA,12S,15,16-BIS-EPOXY-LABDA-13(16),14-DIENE
(12Z)-LABDA-12,14-DIENE-18-OIC-ACID-METHYLESTER
#3C;[2-R-(2-ALPHA-(S*),3A-ALPHA,4-ALPHA,7-ALPHA,7A-ALPHA)]-N-(CYClOHEXYL)-3-(1-NAPHTHOXY)-2-[(OCTAHYDRO-7,8,8-TRIMETHYL-4,7-METHANOBENZOFURAN-2-YL)-OXY]-1-PROP
(4-ALPHA,5-ALPHA,8-BETA,10-ALPHA)-4,10-DIHYDROXY-1,11(13)-GUAIDIEN-12,8-OLIDE
2-AMINO-4-(4'-BENZYLOXYPHENYL)-3-CYANO-5,6,7,8-TETRAHYDRO-7,7-DIMETHYL-5-OXO-4H-BENZOPYRAN
Title Journal or Book Year
The Remarkable Effect of Cosolvent on a Samarium(II)-Mediated 4-exo-trig Cyclization:  Further Synthetic Studies on Pestalotiopsin A The Journal of Organic Chemistry 2003
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