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(S)-1-[(2S,3R,4R,6S)-6-(2,2-DIBROMOVINYL)-4-(DIMETHYLPHENYLSILYL)-2-METHOXY-3,4,5,6-TETRAHYDRO-2H-PYRAN-3-YL]-ETHANE-1,2-DIOL

Compound with spectra: 1 NMR

(S)-1-[(2S,3R,4R,6S)-6-(2,2-DIBROMOVINYL)-4-(DIMETHYLPHENYLSILYL)-2-METHOXY-3,4,5,6-TETRAHYDRO-2H-PYRAN-3-YL]-ETHANE-1,2-DIOL
SpectraBase Compound ID Fw3peBiRMhi
InChI InChI=1S/C18H26Br2O4Si/c1-23-18-17(14(22)11-21)15(9-12(24-18)10-16(19)20)25(2,3)13-7-5-4-6-8-13/h4-8,10,12,14-15,17-18,21-22H,9,11H2,1-3H3/t12-,14+,15+,17-,18-/m0/s1
InChIKey SPJPWKDLHQGPJB-OZNHZTKRSA-N
Mol Weight 494.3 g/mol
Molecular Formula C18H26Br2O4Si
Exact Mass 491.996712 g/mol
Enantiomer InChIKey SPJPWKDLHQGPJB-QLKQHDGRSA-N

View Spectrum of (S)-1-[(2S,3R,4R,6S)-6-(2,2-DIBROMOVINYL)-4-(DIMETHYLPHENYLSILYL)-2-METHOXY-3,4,5,6-TETRAHYDRO-2H-PYRAN-3-YL]-ETHANE-1,2-DIOL

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
[(2S,3R,4R,6S)-6-(2,2-DIBROMOVINYL)-2-METHOXY-[(S)-OXIRAN-2-YL]-3,4,5,6-TETRAHYDRO-2H-PYRAN-4-YL]-DIMETHYL-PHENYLSILANE
(2R,3S)-3-(Dimethyl-phenyl-silanyl)-2-((R)-hydroxy-phenyl-methyl)-3-phenyl-propionic acid methyl ester
Methyl (2R,3R)-3-dimethyl(phenyl)silyl-2-[(S)-.alpha.-hydroxybenzyl]-3-phenylpropanoate
#48;(S)-1-[(2S,3S,4R,6S)-4-(TERT.-BUTYLDIMETHYLSILOXY)-2-METHOXY-6-[(E)-2-(TRIBUTYLSTANNYL)-VINYL]-3,4,5,6-TETRAHYDRO-2H-PYRAN-3-YL]-2-(4-METHOXYBENZYLOXY)-ETH
(1R*,4S*,5R*)-7-AZA-2,2-DIPHENYL-4-HYDROXY-7-METHYL-2-SILABICYCLO-[3.3.0]-OCTANE
RAC-(1S,2R)-2-[(R)-1-[DIMETHYL-(PHENYL)-SILYL]-2-HYDROXYETHYL]-2-(HYDROXYMETHYL)-1-(PENT-4-EN-1-YL)-CYCLOPENTANOL
Methyl (2RS,3RS)-2-allyl-3-dimethyl(phenyl)silyl-2-methyl-3-phenylpropanoate
1,7-Dioxaspiro[5.5]undecane-2-butanol, 4-(acetyloxy)-8-[2-(acetyloxy)propyl]-.beta.-ethyl-3,9-dimethyl-, acetate, [2R-[2.alpha.(R*),3.alpha.,4.alpha.,6.beta.[8R*(S*),9R*]]]-
CALYCULAGLYCOSIDE-A;3',6'-DI-O-ACETYL-BETA-D-GALACTOSE
HOMALOSIDE-C;1-FUROYLOXYMETHYL-5-HYDROXYPHENYL-BETA-D-GLUCOPYRANOSIDE
Title Journal or Book Year
Stereocontrolled Synthesis of a Cn-Cn+7Building Block (“Eastern Moiety”) for the Unnatural Enantiomers of Important Polyol,Polyene Antibiotics Based on a Ring-Closing Metathesis and an Aldol Addition of a Lactone Enolate European Journal of Organic Chemistry 2013
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