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#48;(S)-1-[(2S,3S,4R,6S)-4-(TERT.-BUTYLDIMETHYLSILOXY)-2-METHOXY-6-[(E)-2-(TRIBUTYLSTANNYL)-VINYL]-3,4,5,6-TETRAHYDRO-2H-PYRAN-3-YL]-2-(4-METHOXYBENZYLOXY)-ETH

Compound with spectra: 1 NMR

#48;(S)-1-[(2S,3S,4R,6S)-4-(TERT.-BUTYLDIMETHYLSILOXY)-2-METHOXY-6-[(E)-2-(TRIBUTYLSTANNYL)-VINYL]-3,4,5,6-TETRAHYDRO-2H-PYRAN-3-YL]-2-(4-METHOXYBENZYLOXY)-ETH
SpectraBase Compound ID I9vrE8kVRh8
InChI InChI=1S/C24H39O6Si.3C4H9.Sn/c1-9-18-14-21(30-31(7,8)24(2,3)4)22(23(27-6)29-18)20(25)16-28-15-17-10-12-19(26-5)13-11-17;3*1-3-4-2;/h1,9-13,18,20-23,25H,14-16H2,2-8H3;3*1,3-4H2,2H3;/t18-,20-,21-,22+,23+;;;;/m1..../s1
InChIKey DBIGXEGHVJOVSI-FMZDSNBDSA-N
Mol Weight 741.7 g/mol
Molecular Formula C36H66O6SiSn
Exact Mass 742.365068 g/mol
Enantiomer InChIKey DBIGXEGHVJOVSI-YMVJARIVSA-N

View Spectrum of #48;(S)-1-[(2S,3S,4R,6S)-4-(TERT.-BUTYLDIMETHYLSILOXY)-2-METHOXY-6-[(E)-2-(TRIBUTYLSTANNYL)-VINYL]-3,4,5,6-TETRAHYDRO-2H-PYRAN-3-YL]-2-(4-METHOXYBENZYLOXY)-ETH

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
(R)-3-[(1S,2S,3S,6R)-6-(tert-Butyl-dimethyl-silanyloxy)-2,3-bis-(4-methoxy-benzyloxy)-cyclohexyl]-butan-1-ol
#2;(2'S,4'S,6'R,8'R,10'S)-1-(10'-(TERT.-BUTYLDIMETHYLSILANYLOXY)-4'-METHOXY-8'-(PARA-METHOXYBENZYLOXYMETHYL)-1',7'-DIOXADISPIRO-(5.5)-UNDEC-2'-YL)-BUTAN-2-ONE
(2R,4S,6R,8R,10S)-10-(TERT.-BUTYLDIMETHYLSILANYLOXY)-2-(2'-ETHYLPROP-1'-EN-3'-YL)-8-(PARA-METHOXYBENZYLOXYMETHYL)-1,7-DIOXASPIRO-(5.5)-UNDECAN-4-OL;(AE)
(2R,4R,6R,8R,10S)-10-(TERT.-BUTYLDIMETHYLSILANYLOXY)-2-(2'-ETHYLPROP-1'-EN-3'-YL)-8-(PARA-METHOXYBENZYLOXYMETHYL)-1,7-DIOXASPIRO-(5.5)-UNDECAN-4-OL;(AE)
trans-1-[2R,3aR,4R,5R,6aS)-5-{[(1,1-Dimethylethyl)dimethylsilyl]oxy}-2-ethoxyhexahydro-2H-cyclopenta[b]-furan-4-yl]-1-octene-3-one
#20;(2R,4S,6R,8R,10S)-10-(TERT.-BUTYLDIMETHYLSILANYLOXY)-2-(2'-ETHYLPROP-1'-EN-3'-YL)-4-METHOXY-8-(PARA-METHOXYBENZYLOXYMETHYL)-1,7-DIOXASPIRO-(5.5)-UNDECANE
(2R,3R,4S,5S,6S,6(2S))-3,5-Di-(tert-butyldimethylsiloxy)-2-methoxy-4-methyl-6-(2-hydroxy-2-butenyl)-3,4,5,6-tetrahydro-2H-pyran
2.beta.-[(p-Methoxy)benzyloxy]-3.alpha.-[(triisopropylsilyl)oxy]-4.beta.-methyl-8-oxabicyclo[3.2.1]oct-6-ene
(2S,4S,6S,8R,9S)-2-([5R,2E]-3,5-Dime-6-benzyloxy-hex-2-enyl)-4-(dime-T-bu-siloxy)-8,9-dime-1,7-dioxa-spiro(5.5)undecane
BENZYL-4-C-[(TERT.-BUTOXYCARBONYL)-AMINO]-METHYL-2,3-DI-O-(TERT.-BUTYLDIMETHYLSILYL)-4-DEOXY-ALPHA-D-ARABINOPYRANOSIDE
Title Journal or Book Year
Stereocontrolled Synthesis of a Cn-Cn+7Building Block (“Eastern Moiety”) for the Unnatural Enantiomers of Important Polyol,Polyene Antibiotics Based on a Ring-Closing Metathesis and an Aldol Addition of a Lactone Enolate European Journal of Organic Chemistry 2013
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