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[(2S,3R,4R,6S)-6-(2,2-DIBROMOVINYL)-2-METHOXY-[(S)-OXIRAN-2-YL]-3,4,5,6-TETRAHYDRO-2H-PYRAN-4-YL]-DIMETHYL-PHENYLSILANE

Compound with spectra: 1 NMR

[(2S,3R,4R,6S)-6-(2,2-DIBROMOVINYL)-2-METHOXY-[(S)-OXIRAN-2-YL]-3,4,5,6-TETRAHYDRO-2H-PYRAN-4-YL]-DIMETHYL-PHENYLSILANE
SpectraBase Compound ID BeBWTXk7QLe
InChI InChI=1S/C18H24Br2O3Si/c1-21-18-17(14-11-22-14)15(9-12(23-18)10-16(19)20)24(2,3)13-7-5-4-6-8-13/h4-8,10,12,14-15,17-18H,9,11H2,1-3H3/t12-,14+,15+,17-,18-/m0/s1
InChIKey YCUTYJVRYOXRJZ-OZNHZTKRSA-N
Mol Weight 476.28 g/mol
Molecular Formula C18H24Br2O3Si
Exact Mass 473.986147 g/mol
Enantiomer InChIKey YCUTYJVRYOXRJZ-QLKQHDGRSA-N

View Spectrum of [(2S,3R,4R,6S)-6-(2,2-DIBROMOVINYL)-2-METHOXY-[(S)-OXIRAN-2-YL]-3,4,5,6-TETRAHYDRO-2H-PYRAN-4-YL]-DIMETHYL-PHENYLSILANE

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
(S)-1-[(2S,3R,4R,6S)-6-(2,2-DIBROMOVINYL)-4-(DIMETHYLPHENYLSILYL)-2-METHOXY-3,4,5,6-TETRAHYDRO-2H-PYRAN-3-YL]-ETHANE-1,2-DIOL
(2R,3S)-3-(Dimethyl-phenyl-silanyl)-2-((R)-hydroxy-phenyl-methyl)-3-phenyl-propionic acid methyl ester
Methyl (2R,3R)-3-dimethyl(phenyl)silyl-2-[(S)-.alpha.-hydroxybenzyl]-3-phenylpropanoate
#48;(S)-1-[(2S,3S,4R,6S)-4-(TERT.-BUTYLDIMETHYLSILOXY)-2-METHOXY-6-[(E)-2-(TRIBUTYLSTANNYL)-VINYL]-3,4,5,6-TETRAHYDRO-2H-PYRAN-3-YL]-2-(4-METHOXYBENZYLOXY)-ETH
1,7-Dioxaspiro[5.5]undecane-2-butanol, 4-(acetyloxy)-8-[2-(acetyloxy)propyl]-.beta.-ethyl-3,9-dimethyl-, acetate, [2R-[2.alpha.(R*),3.alpha.,4.alpha.,6.beta.[8R*(S*),9R*]]]-
(1R*,4S*,5R*)-7-AZA-2,2-DIPHENYL-4-HYDROXY-7-METHYL-2-SILABICYCLO-[3.3.0]-OCTANE
(1R*,4R*,5R*)-7-AZA-2,2-DIPHENYL-4-HYDROXY-7-METHYL-2-SILABICYCLO-[3.3.0]-OCTANE
Dimethyl (3R,5R,6S,7S,8R)-6,8-Isopropylidenedioxy-7-methoxy-5-[2-(4-methoxybenzyloxy)ethyl]-3-methyl-2-oxo-10-undecenylphosphonate
HOMALOSIDE-C;1-FUROYLOXYMETHYL-5-HYDROXYPHENYL-BETA-D-GLUCOPYRANOSIDE
P,P-DIPHENYL-N-(1-DIMETHYLPHENYLSILYL-2-NAPHTHYLMETHYLENE)-PHOSPHINIC-AMIDE
Title Journal or Book Year
Stereocontrolled Synthesis of a Cn-Cn+7Building Block (“Eastern Moiety”) for the Unnatural Enantiomers of Important Polyol,Polyene Antibiotics Based on a Ring-Closing Metathesis and an Aldol Addition of a Lactone Enolate European Journal of Organic Chemistry 2013
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