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#10A;(+)-METHYL-(3S,4S,5S,7R,9S,10E)-[7-[2-(TERT.-BUTYLDIMETHYLSILANYLOXY)-PENT-3-ENYL]-4-METHYL-5-(TRIISOPROPYLSILANYLOXY)-TETRAHYDROPYRAN-2-YL]-ACETATE

Compound with spectra: 1 NMR

#10A;(+)-METHYL-(3S,4S,5S,7R,9S,10E)-[7-[2-(TERT.-BUTYLDIMETHYLSILANYLOXY)-PENT-3-ENYL]-4-METHYL-5-(TRIISOPROPYLSILANYLOXY)-TETRAHYDROPYRAN-2-YL]-ACETATE
SpectraBase Compound ID JyXDLEPUOUE
InChI InChI=1S/C29H58O5Si2/c1-15-16-24(33-35(13,14)29(9,10)11)17-25-18-27(23(8)26(32-25)19-28(30)31-12)34-36(20(2)3,21(4)5)22(6)7/h15-16,20-27H,17-19H2,1-14H3/b16-15+/t23-,24-,25+,26-,27-/m0/s1
InChIKey NYXBJSHMXIACOI-QANMCMPSSA-N
Mol Weight 542.9 g/mol
Molecular Formula C29H58O5Si2
Exact Mass 542.382278 g/mol
Enantiomer InChIKey NYXBJSHMXIACOI-ZULWCTMOSA-N

View Spectrum of #10A;(+)-METHYL-(3S,4S,5S,7R,9S,10E)-[7-[2-(TERT.-BUTYLDIMETHYLSILANYLOXY)-PENT-3-ENYL]-4-METHYL-5-(TRIISOPROPYLSILANYLOXY)-TETRAHYDROPYRAN-2-YL]-ACETATE

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
(2R,3S)-3-(tert-butyldimethylsilyloxy)-4-(2-[(2S,3R,6S)-6-[2-(tert-butyldimethylsilyloxy)pent-3-enyl]-3-methyltetrahydropyran-2-yl}acetylamino)-2-methylbutyric acid
(2S,4R,6R)-4-tert-Butyldimethylsiloxy-6-[(S)-2,3-dimethylpropyl]-tetrahydro-5,5-dimethyl-2H-pyran-2-carbonitrile
Ethyl 2-((2S,3R,5R)-5-((1S,2S)-2-((tert-butyldimethylsilyl)oxy)-1-hydroxy-3-oxobutyl)-3-methyltetrahydrofuran-2-yl)acetate
(S)-3-((2R,4R,6S)-6-Allyl-4-((tert-butyldimethylsilyl)oxy)tetrahydro-2H-pyran-2-yl)-N-((1R,2R)-1-hydroxy-1-phenylpropan-2-yl)-N,2-dimethylpropanamide
(R)-3-((2R,4R,6S)-6-Allyl-4-((tert-butyldimethylsilyl)oxy)tetrahydro-2H-pyran-2-yl)-N-((1S,2S)-1-Hydroxy-1-phenylpropan-2-yl)-N,2-dimethylpropanamide
Cyclopentaneacetic acid, 2-(dimethoxymethyl)-3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-5-hydroxy-, methyl ester, (1.alpha.,2.beta.,3.beta.,5.beta.)-(.+-.)-
(3aR*,8aR*)-2(R*)-[1(S*)-[[Dimethyl(1,1-dimetrhylethyl)silyl]oxy]-3(E)-hexenyl]-5(S*)-(carbomethoxymethyl)tetrahydrofuro[3,2-b]tetrahydrofuran-5(S*)-acetic Acid
(2E,8E)-(4S,5R,6S,7R,10S,11S)-7-{[tert-butyl(dimethyl)silyl]oxy}-5-hydroxy-11-[(4-methoxybenzyl)oxy]-4,6,8,10-(etramethyl)dodeca-2,8-dienoic acid methyl ester
[DIMETHYL-(1,1,2-TRIMETHYLPROPYL)]-[(2S,3S,4R,6S)-6-ETHYNYL-2-METHOXY-3-[(S)-OXIRAN-2-YL]-3,4,5,6-TETRAHYDRO-2H-PYRAN-4-YL-OXY]-DIMETHYLSILANE
(E,4R,5R,7R,9S)-9-[tert-butyl(dimethyl)silyl]oxy-10-[4-[[tert-butyl(dimethyl)silyl]oxymethyl]-2-oxazolyl]-4,5-dihydroxy-7-methoxy-2-methyl-2-decenoic acid ethyl ester
Title Journal or Book Year
Total Synthesis of the Marine Natural Product (−)-Clavosolide A Organic Letters 2006
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