For citations & permissions, please see: Citations & Permissions - Wiley Science Solutions*

*Links on SpectraBase are not permalinks.

(2S,8R,9S)-8-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-ETHYL-9-[2-(4-METHOXYBENZYLOXY)-ETHYL]-1-OXA-3Z,5Z-CYCLONONADIENE

Compound with spectra: 2 NMR

(2S,8R,9S)-8-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-ETHYL-9-[2-(4-METHOXYBENZYLOXY)-ETHYL]-1-OXA-3Z,5Z-CYCLONONADIENE
SpectraBase Compound ID Da56uhhrk15
InChI InChI=1S/C26H42O4Si/c1-8-22-12-10-9-11-13-25(30-31(6,7)26(2,3)4)24(29-22)18-19-28-20-21-14-16-23(27-5)17-15-21/h9-12,14-17,22,24-25H,8,13,18-20H2,1-7H3/b11-9-,12-10-/t22-,24-,25+/m0/s1
InChIKey AVTAIPPXAQLMAH-PPAXUBRQSA-N
Mol Weight 446.7 g/mol
Molecular Formula C26H42O4Si
Exact Mass 446.285236 g/mol
Enantiomer InChIKey AVTAIPPXAQLMAH-HCYGEEARSA-N

View Spectrum of (2S,8R,9S)-8-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-ETHYL-9-[2-(4-METHOXYBENZYLOXY)-ETHYL]-1-OXA-3Z,5Z-CYCLONONADIENE

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3

View Spectrum of (2S,8R,9S)-8-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-ETHYL-9-[2-(4-METHOXYBENZYLOXY)-ETHYL]-1-OXA-3Z,5Z-CYCLONONADIENE

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
(1R)-1-[(2R,4S,5S)-4-[tert-butyl(dimethyl)silyl]oxy-5-pentyl-2-oxolanyl]-9-decen-1-ol
(1S)-1-[(2R,4S,5S)-4-[tert-butyl(dimethyl)silyl]oxy-5-pentyl-2-oxolanyl]-9-decen-1-ol
(1R,4S,5R.6E)-2-(4-Methoxybenzyloxy)-1-methylethyl 7-iodo-4,5-bis(tert-butyldimethylsiloxy)-6-heptenoate
Benzoic acid (1S,2R)-1-{2-[(2R,3S)-3-(tert-Butyldimethylsilyloxy)tetrahydropyran-2-yl]ethyl}-2,3-dihydroxypropyl ester
tert-Butyl(dimethyl)({4-methylene-2,6-di[(E)-prop-1-enyl]tetrahydro-2H-pyran-3-yl}oxy)silane
Methyl 3-O-benzoyl-2-O-[(t-butyl)dimethylsilyl]-4-deoxy-.beta.-D-threo-pentopyranoside
(phenylmethyl) 2-[[(2R,3R)-3-[2-[[(2R,3R)-3-[tert-butyl(dimethyl)silyl]oxyoxan-2-yl]methoxy]ethanoyloxy]oxan-2-yl]methoxy]ethanoate
(2E,6R,7S)-6-Benzyloxy-7-tert-butyldimethylsilyloxy-6-ethyl-1-(4-methoxyphenyl)oct-2-en-1-one
2.beta.-[(t-Butyldimethylsilyl)oxy]-8-oxabicyclo[3.2.1]oct-6-en-3-one
(1R,4R,5R)-4-[tert-butyl(dimethyl)silyl]oxy-8-oxabicyclo[3.2.1]oct-6-en-3-one
Title Journal or Book Year
Total Synthesis of (+)-Brasilenyne. Application of an Intramolecular Silicon-Assisted Cross-Coupling Reaction Journal of the American Chemical Society 2004
Intramolecular Silicon-Assisted Cross-Coupling:  Total Synthesis of (+)-Brasilenyne Journal of the American Chemical Society 2002
Other Resources
Unknown Identification

Search your unknown spectrum against the world's largest collection of reference spectra

KnowItAll Campus Solutions

KnowItAll offers faculty and students at your school access to all the tools you need for spectral analysis and structure drawing & publishing! Plus, access the world's largest spectral library.