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(2S,8R,9S)-8-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-ETHYL-9-[2-(4-METHOXYBENZYLOXY)-ETHYL]-1-OXA-3Z,5Z-CYCLONONADIENE

Compound with spectra: 2 NMR

(2S,8R,9S)-8-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-ETHYL-9-[2-(4-METHOXYBENZYLOXY)-ETHYL]-1-OXA-3Z,5Z-CYCLONONADIENE
SpectraBase Compound ID Da56uhhrk15
InChI InChI=1S/C26H42O4Si/c1-8-22-12-10-9-11-13-25(30-31(6,7)26(2,3)4)24(29-22)18-19-28-20-21-14-16-23(27-5)17-15-21/h9-12,14-17,22,24-25H,8,13,18-20H2,1-7H3/b11-9-,12-10-/t22-,24-,25+/m0/s1
InChIKey AVTAIPPXAQLMAH-PPAXUBRQSA-N
Mol Weight 446.7 g/mol
Molecular Formula C26H42O4Si
Exact Mass 446.285236 g/mol
Enantiomer InChIKey AVTAIPPXAQLMAH-HCYGEEARSA-N

View Spectrum of (2S,8R,9S)-8-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-ETHYL-9-[2-(4-METHOXYBENZYLOXY)-ETHYL]-1-OXA-3Z,5Z-CYCLONONADIENE

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3

View Spectrum of (2S,8R,9S)-8-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-ETHYL-9-[2-(4-METHOXYBENZYLOXY)-ETHYL]-1-OXA-3Z,5Z-CYCLONONADIENE

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
(1R)-1-[(2R,4S,5S)-4-[tert-butyl(dimethyl)silyl]oxy-5-pentyl-2-oxolanyl]-9-decen-1-ol
(1S)-1-[(2R,4S,5S)-4-[tert-butyl(dimethyl)silyl]oxy-5-pentyl-2-oxolanyl]-9-decen-1-ol
(1R,4S,5R.6E)-2-(4-Methoxybenzyloxy)-1-methylethyl 7-iodo-4,5-bis(tert-butyldimethylsiloxy)-6-heptenoate
Benzoic acid (1S,2R)-1-{2-[(2R,3S)-3-(tert-Butyldimethylsilyloxy)tetrahydropyran-2-yl]ethyl}-2,3-dihydroxypropyl ester
tert-Butyl(dimethyl)({4-methylene-2,6-di[(E)-prop-1-enyl]tetrahydro-2H-pyran-3-yl}oxy)silane
Methyl 3-O-benzoyl-2-O-[(t-butyl)dimethylsilyl]-4-deoxy-.beta.-D-threo-pentopyranoside
(phenylmethyl) 2-[[(2R,3R)-3-[2-[[(2R,3R)-3-[tert-butyl(dimethyl)silyl]oxyoxan-2-yl]methoxy]ethanoyloxy]oxan-2-yl]methoxy]ethanoate
2.beta.-[(t-Butyldimethylsilyl)oxy]-8-oxabicyclo[3.2.1]oct-6-en-3-one
(1R,4R,5R)-4-[tert-butyl(dimethyl)silyl]oxy-8-oxabicyclo[3.2.1]oct-6-en-3-one
(1RS,2E,6R,7S)-6-Benzyloxy-7-tert-butyldimethylsilyloxy-6-ethyl-1-(4-methoxyphenyl)oct-2-en-1-ol
Title Journal or Book Year
Total Synthesis of (+)-Brasilenyne. Application of an Intramolecular Silicon-Assisted Cross-Coupling Reaction Journal of the American Chemical Society 2004
Intramolecular Silicon-Assisted Cross-Coupling:  Total Synthesis of (+)-Brasilenyne Journal of the American Chemical Society 2002
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