Spectra for:
Scott E. Denmark, Shyh-Ming Yang
Compound 1 (2S,8S,9S)-8-CHLORO-2-ETHYL-9-[(2Z)-PENT-2-EN-4-YNYL]-1-OXA-3Z,5Z-CYCLONONADIENE;(+)-SYNTHETIC-BRASILENYNE
![(2S,8S,9S)-8-CHLORO-2-ETHYL-9-[(2Z)-PENT-2-EN-4-YNYL]-1-OXA-3Z,5Z-CYCLONONADIENE;(+)-SYNTHETIC-BRASILENYNE](/api/compound/8QLbeGLue8z.png?h=300&w=458 "(2S,8S,9S)-8-CHLORO-2-ETHYL-9-[(2Z)-PENT-2-EN-4-YNYL]-1-OXA-3Z,5Z-CYCLONONADIENE;(+)-SYNTHETIC-BRASILENYNE")
Compound 2 (2S,8R,9S)-2-ETHYL-8-HYDROXY-9-[2-(4-METHOXYBENZYLOXY)-ETHYL]-1-OXA-3Z,5Z-CYCLONONADIENE
![(2S,8R,9S)-2-ETHYL-8-HYDROXY-9-[2-(4-METHOXYBENZYLOXY)-ETHYL]-1-OXA-3Z,5Z-CYCLONONADIENE](/api/compound/9MYFlrcvfg9.png?h=300&w=458 "(2S,8R,9S)-2-ETHYL-8-HYDROXY-9-[2-(4-METHOXYBENZYLOXY)-ETHYL]-1-OXA-3Z,5Z-CYCLONONADIENE")
Compound 3 (6R)-2,2-DIMETHYL-6-[(1S)-1-[[(1S,2Z)-1-ETHYL-3-IODO-2-PROPENYL]-OXY]-3-(4-METHOXYBENZYLOXY)-PROPAN-1-YL]-1-OXA-2-SILACYCLOHEX-3-ENE
![(6R)-2,2-DIMETHYL-6-[(1S)-1-[[(1S,2Z)-1-ETHYL-3-IODO-2-PROPENYL]-OXY]-3-(4-METHOXYBENZYLOXY)-PROPAN-1-YL]-1-OXA-2-SILACYCLOHEX-3-ENE](/api/compound/3jZ1yiMMCSV.png?h=300&w=458 "(6R)-2,2-DIMETHYL-6-[(1S)-1-[[(1S,2Z)-1-ETHYL-3-IODO-2-PROPENYL]-OXY]-3-(4-METHOXYBENZYLOXY)-PROPAN-1-YL]-1-OXA-2-SILACYCLOHEX-3-ENE")
Compound 4 (2S)-2-[[(1S,2Z)-1-ETHYL-3-IODO-2-PROPENYL]-OXY]-4-(4-METHOXYBENZYLOXY)-BUTANAL
![(2S)-2-[[(1S,2Z)-1-ETHYL-3-IODO-2-PROPENYL]-OXY]-4-(4-METHOXYBENZYLOXY)-BUTANAL](/api/compound/GhmUswBTAHp.png?h=300&w=458 "(2S)-2-[[(1S,2Z)-1-ETHYL-3-IODO-2-PROPENYL]-OXY]-4-(4-METHOXYBENZYLOXY)-BUTANAL")
Compound 5 (3S)-[[(1S)-1-ETHYL-3-TRIMETHYLSILYLPROPYNYL]-OXY]-TETRAHYDROFURAN-2-ONE
![(3S)-[[(1S)-1-ETHYL-3-TRIMETHYLSILYLPROPYNYL]-OXY]-TETRAHYDROFURAN-2-ONE](/api/compound/AlkesKi7CuP.png?h=300&w=458 "(3S)-[[(1S)-1-ETHYL-3-TRIMETHYLSILYLPROPYNYL]-OXY]-TETRAHYDROFURAN-2-ONE")
Compound 6 TERT.-BUTYLDIMETHYL-[2-[(4S)-2-ETHYL-5-OXO-1,3-DIOXOLAN-4-YL]-ETHOXY]-DIMETHYLSILANE;TRANS-ISOMER
![TERT.-BUTYLDIMETHYL-[2-[(4S)-2-ETHYL-5-OXO-1,3-DIOXOLAN-4-YL]-ETHOXY]-DIMETHYLSILANE;TRANS-ISOMER](/api/compound/st7negalSo.png?h=300&w=458 "TERT.-BUTYLDIMETHYL-[2-[(4S)-2-ETHYL-5-OXO-1,3-DIOXOLAN-4-YL]-ETHOXY]-DIMETHYLSILANE;TRANS-ISOMER")
Compound 6 TERT.-BUTYLDIMETHYL-[2-[(4S)-2-ETHYL-5-OXO-1,3-DIOXOLAN-4-YL]-ETHOXY]-DIMETHYLSILANE;CIS-ISOMER
![TERT.-BUTYLDIMETHYL-[2-[(4S)-2-ETHYL-5-OXO-1,3-DIOXOLAN-4-YL]-ETHOXY]-DIMETHYLSILANE;CIS-ISOMER](/api/compound/8zxA67bG2aA.png?h=300&w=458 "TERT.-BUTYLDIMETHYL-[2-[(4S)-2-ETHYL-5-OXO-1,3-DIOXOLAN-4-YL]-ETHOXY]-DIMETHYLSILANE;CIS-ISOMER")
Compound 7 (3S)-[[(1S)-1-ETHYL-2-IODOPROPYNYL]-OXY]-TETRAHYDROFURAN-2-ONE
![(3S)-[[(1S)-1-ETHYL-2-IODOPROPYNYL]-OXY]-TETRAHYDROFURAN-2-ONE](/api/compound/HySCXzZEB4A.png?h=300&w=458 "(3S)-[[(1S)-1-ETHYL-2-IODOPROPYNYL]-OXY]-TETRAHYDROFURAN-2-ONE")
Compound 8 (3S)-[[(1S,2Z)-1-ETHYL-3-IODO-PROPENYL]-OXY]-TETRAHYDROFURAN-2-ONE
![(3S)-[[(1S,2Z)-1-ETHYL-3-IODO-PROPENYL]-OXY]-TETRAHYDROFURAN-2-ONE](/api/compound/4bNRqVTi4oN.png?h=300&w=458 "(3S)-[[(1S,2Z)-1-ETHYL-3-IODO-PROPENYL]-OXY]-TETRAHYDROFURAN-2-ONE")
Compound 9 (2S)-N-METHOXY-N-METHYL-2-[[(1S,2Z)-1-ETHYL-3-IODO-2-PROPENYL]-OXY]-4-(4-METHOXYBENZYLOXY)-BUTANAMIDE
![(2S)-N-METHOXY-N-METHYL-2-[[(1S,2Z)-1-ETHYL-3-IODO-2-PROPENYL]-OXY]-4-(4-METHOXYBENZYLOXY)-BUTANAMIDE](/api/compound/39s4tDrVGkh.png?h=300&w=458 "(2S)-N-METHOXY-N-METHYL-2-[[(1S,2Z)-1-ETHYL-3-IODO-2-PROPENYL]-OXY]-4-(4-METHOXYBENZYLOXY)-BUTANAMIDE")
Compound 10 (4R,5S)-5-[[(1S,2Z)-1-ETHYL-3-IODO-2-PROPENYL]-OXY]-7-(4-METHOXYBENZYLOXY)-1-HEPTEN-4-OL
![(4R,5S)-5-[[(1S,2Z)-1-ETHYL-3-IODO-2-PROPENYL]-OXY]-7-(4-METHOXYBENZYLOXY)-1-HEPTEN-4-OL](/api/compound/aZlSIJSOz4.png?h=300&w=458 "(4R,5S)-5-[[(1S,2Z)-1-ETHYL-3-IODO-2-PROPENYL]-OXY]-7-(4-METHOXYBENZYLOXY)-1-HEPTEN-4-OL")
Compound 11 (2S,8R,9S)-8-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-ETHYL-9-(2-OXOETHYL)-1-OXA-3Z,5Z-CYCLONONADIENE
Compound 12 (2S,8R,9S)-2-ETHYL-8-HYDROXY-9-[(2Z)-PENT-2-EN-4-YNYL]-1-OXA-3Z,5Z-CYCLONONADIENE
![(2S,8R,9S)-2-ETHYL-8-HYDROXY-9-[(2Z)-PENT-2-EN-4-YNYL]-1-OXA-3Z,5Z-CYCLONONADIENE](/api/compound/1YKVb3UbvF2.png?h=300&w=458 "(2S,8R,9S)-2-ETHYL-8-HYDROXY-9-[(2Z)-PENT-2-EN-4-YNYL]-1-OXA-3Z,5Z-CYCLONONADIENE")
Compound 13 2-[(4S)-2-ETHYL-5-OXO-1,3-DIOXOLAN-4-YL]-ACETIC-ACID;CIS-ISOMER
![2-[(4S)-2-ETHYL-5-OXO-1,3-DIOXOLAN-4-YL]-ACETIC-ACID;CIS-ISOMER](/api/compound/Fnywj8AkwxB.png?h=300&w=458 "2-[(4S)-2-ETHYL-5-OXO-1,3-DIOXOLAN-4-YL]-ACETIC-ACID;CIS-ISOMER")
Compound 13 2-[(4S)-2-ETHYL-5-OXO-1,3-DIOXOLAN-4-YL]-ACETIC-ACID;TRANS-ISOMER
![2-[(4S)-2-ETHYL-5-OXO-1,3-DIOXOLAN-4-YL]-ACETIC-ACID;TRANS-ISOMER](/api/compound/Bz3ae70jyY2.png?h=300&w=458 "2-[(4S)-2-ETHYL-5-OXO-1,3-DIOXOLAN-4-YL]-ACETIC-ACID;TRANS-ISOMER")
Compound 14 2-[(4S)-2-ETHYL-5-OXO-1,3-DIOXOLAN-4-YL]-ETHANOL;CIS-ISOMER
![2-[(4S)-2-ETHYL-5-OXO-1,3-DIOXOLAN-4-YL]-ETHANOL;CIS-ISOMER](/api/compound/80AA6DA9IJo.png?h=300&w=458 "2-[(4S)-2-ETHYL-5-OXO-1,3-DIOXOLAN-4-YL]-ETHANOL;CIS-ISOMER")
Compound 14 2-[(4S)-2-ETHYL-5-OXO-1,3-DIOXOLAN-4-YL]-ETHANOL;TRANS-ISOMER
![2-[(4S)-2-ETHYL-5-OXO-1,3-DIOXOLAN-4-YL]-ETHANOL;TRANS-ISOMER](/api/compound/FRbDQQij4YW.png?h=300&w=458 "2-[(4S)-2-ETHYL-5-OXO-1,3-DIOXOLAN-4-YL]-ETHANOL;TRANS-ISOMER")
Compound 15 (2S)-N-METHOXY-N-METHYL-2-[[(1S,2Z)-1-ETHYL-3-IODO-PROPENYL]-OXY]-4-HYDROXYBUTANAMIDE
![(2S)-N-METHOXY-N-METHYL-2-[[(1S,2Z)-1-ETHYL-3-IODO-PROPENYL]-OXY]-4-HYDROXYBUTANAMIDE](/api/compound/uAhdkkSThg.png?h=300&w=458 "(2S)-N-METHOXY-N-METHYL-2-[[(1S,2Z)-1-ETHYL-3-IODO-PROPENYL]-OXY]-4-HYDROXYBUTANAMIDE")
Compound 16 DIMETHYL-[(4R,5S)-5-[[(1S,2Z)-1-ETHYL-3-IODO-2-PROPENYL]-OXY]-7-(4-METHOXYBENZYLOXY)-1-HEPTEN-4-OXY]-VINYLSILANE
![DIMETHYL-[(4R,5S)-5-[[(1S,2Z)-1-ETHYL-3-IODO-2-PROPENYL]-OXY]-7-(4-METHOXYBENZYLOXY)-1-HEPTEN-4-OXY]-VINYLSILANE](/api/compound/ByYsKnzb7KX.png?h=300&w=458 "DIMETHYL-[(4R,5S)-5-[[(1S,2Z)-1-ETHYL-3-IODO-2-PROPENYL]-OXY]-7-(4-METHOXYBENZYLOXY)-1-HEPTEN-4-OXY]-VINYLSILANE")
Compound 17 (2S,8R,9S)-8-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-ETHYL-9-[2-(4-METHOXYBENZYLOXY)-ETHYL]-1-OXA-3Z,5Z-CYCLONONADIENE
![(2S,8R,9S)-8-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-ETHYL-9-[2-(4-METHOXYBENZYLOXY)-ETHYL]-1-OXA-3Z,5Z-CYCLONONADIENE](/api/compound/Da56uhhrk15.png?h=300&w=458 "(2S,8R,9S)-8-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-ETHYL-9-[2-(4-METHOXYBENZYLOXY)-ETHYL]-1-OXA-3Z,5Z-CYCLONONADIENE")
Compound 18 (2S,8R,9S)-8-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-ETHYL-9-(2-HYDROXYETHYL)-1-OXA-3Z,5Z-CYCLONONADIENE
Compound 19 (2S,8R,9S)-8-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-ETHYL-9-[(2Z)-5-(TRIISOPROPYLSILYL)-PENT-2-EN-4-YNYL]-1-OXA-3Z,5Z-CYCLONONADIENE
![(2S,8R,9S)-8-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-ETHYL-9-[(2Z)-5-(TRIISOPROPYLSILYL)-PENT-2-EN-4-YNYL]-1-OXA-3Z,5Z-CYCLONONADIENE](/api/compound/L2GHrQx8X71.png?h=300&w=458 "(2S,8R,9S)-8-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-ETHYL-9-[(2Z)-5-(TRIISOPROPYLSILYL)-PENT-2-EN-4-YNYL]-1-OXA-3Z,5Z-CYCLONONADIENE")
Compound 20 LBGHAIOEEONSFJ-MPYGGPBHSA-N
Citation
| Citation | J.AM.CHEM.SOC.,124,15196(2002) |
|---|---|
| Journal | Journal of the American Chemical Society |
| Issue | 51 |
| Volume | 124 |
| Page(s) | 15196-15197 |
| Year | 2002 |
| Author(s) | Scott E. Denmark, Shyh-Ming Yang |
| Publisher | American Chemical Society (ACS) |
| DOI | 10.1021/ja028936q |