Spectra for:
Scott E. Denmark, Shyh-Ming Yang
Compound 1 (+)-BRASILENYNE;(2S,8S,9S)-8-CHLORO-2-ETHYL-9-[(2Z)-PENT-2-EN-4-YNYL]-1-OXA-3Z,5Z-CYCLONONADIENE
![(+)-BRASILENYNE;(2S,8S,9S)-8-CHLORO-2-ETHYL-9-[(2Z)-PENT-2-EN-4-YNYL]-1-OXA-3Z,5Z-CYCLONONADIENE](/api/compound/HsBxiJv1Wkk.png?h=300&w=458 "(+)-BRASILENYNE;(2S,8S,9S)-8-CHLORO-2-ETHYL-9-[(2Z)-PENT-2-EN-4-YNYL]-1-OXA-3Z,5Z-CYCLONONADIENE")
Compound 2 (2S,8R,9S)-2-ETHYL-8-HYDROXY-9-[2-(4-METHOXYBENZYLOXY)-ETHYL]-1-OXA-3Z,5Z-CYCLONONADIENE
![(2S,8R,9S)-2-ETHYL-8-HYDROXY-9-[2-(4-METHOXYBENZYLOXY)-ETHYL]-1-OXA-3Z,5Z-CYCLONONADIENE](/api/compound/9MYFlrcvfg9.png?h=300&w=458 "(2S,8R,9S)-2-ETHYL-8-HYDROXY-9-[2-(4-METHOXYBENZYLOXY)-ETHYL]-1-OXA-3Z,5Z-CYCLONONADIENE")
Compound 3 (6R)-2,2-DIMETHYL-6-[(1S)-1-[[(1S,2Z)-1-ETHYL-3-IODO-2-PROPENYL]-OXY]-3-(4-METHOXYBENZYLOXY)-PROPAN-1-YL]-1-OXA-2-SILACYCLOHEX-3-ENE
![(6R)-2,2-DIMETHYL-6-[(1S)-1-[[(1S,2Z)-1-ETHYL-3-IODO-2-PROPENYL]-OXY]-3-(4-METHOXYBENZYLOXY)-PROPAN-1-YL]-1-OXA-2-SILACYCLOHEX-3-ENE](/api/compound/3jZ1yiMMCSV.png?h=300&w=458 "(6R)-2,2-DIMETHYL-6-[(1S)-1-[[(1S,2Z)-1-ETHYL-3-IODO-2-PROPENYL]-OXY]-3-(4-METHOXYBENZYLOXY)-PROPAN-1-YL]-1-OXA-2-SILACYCLOHEX-3-ENE")
Compound 4 (2S)-2-[[(1S,2Z)-1-ETHYL-3-IODO-2-PROPENYL]-OXY]-4-(4-METHOXYBENZYLOXY)-BUTANAL
![(2S)-2-[[(1S,2Z)-1-ETHYL-3-IODO-2-PROPENYL]-OXY]-4-(4-METHOXYBENZYLOXY)-BUTANAL](/api/compound/66bzIFXFPtN.png?h=300&w=458 "(2S)-2-[[(1S,2Z)-1-ETHYL-3-IODO-2-PROPENYL]-OXY]-4-(4-METHOXYBENZYLOXY)-BUTANAL")
Compound 5 (3S)-[[(1S)-1-ETHYL-3-TRIMETHYLSILYLPROPYNYL]-OXY]-TETRAHYDROFURAN-2-ONE
![(3S)-[[(1S)-1-ETHYL-3-TRIMETHYLSILYLPROPYNYL]-OXY]-TETRAHYDROFURAN-2-ONE](/api/compound/AlkesKi7CuP.png?h=300&w=458 "(3S)-[[(1S)-1-ETHYL-3-TRIMETHYLSILYLPROPYNYL]-OXY]-TETRAHYDROFURAN-2-ONE")
Compound 6 (S)-3-HYDROXYTETRAHYDROFURAN-2-ONE;(S)-ISOMER
Compound 7 (+/-)-1-TRIMETHYLSILYL-1-PENTYN-3-OL
Compound 7 (R)-1-TRIMETHYLSILYL-1-PENTYN-3-OL;(R)-ISOMER
Compound 8 TERT.-BUTYLDIMETHYL-[2-[(4S)-2-ETHYL-5-OXO-1,3-DIOXOLAN-4-YL]-ETHOXY]-DIMETHYLSILANE;TRANS-ISOMER
![TERT.-BUTYLDIMETHYL-[2-[(4S)-2-ETHYL-5-OXO-1,3-DIOXOLAN-4-YL]-ETHOXY]-DIMETHYLSILANE;TRANS-ISOMER](/api/compound/st7negalSo.png?h=300&w=458 "TERT.-BUTYLDIMETHYL-[2-[(4S)-2-ETHYL-5-OXO-1,3-DIOXOLAN-4-YL]-ETHOXY]-DIMETHYLSILANE;TRANS-ISOMER")
Compound 8 TERT.-BUTYLDIMETHYL-[2-[(4S)-2-ETHYL-5-OXO-1,3-DIOXOLAN-4-YL]-ETHOXY]-DIMETHYLSILANE;CIS-ISOMER
![TERT.-BUTYLDIMETHYL-[2-[(4S)-2-ETHYL-5-OXO-1,3-DIOXOLAN-4-YL]-ETHOXY]-DIMETHYLSILANE;CIS-ISOMER](/api/compound/8zxA67bG2aA.png?h=300&w=458 "TERT.-BUTYLDIMETHYL-[2-[(4S)-2-ETHYL-5-OXO-1,3-DIOXOLAN-4-YL]-ETHOXY]-DIMETHYLSILANE;CIS-ISOMER")
Compound 9 2-[(4S)-2,2-DIMETHYL-5-OXO-1,3-DIOXOLAN-4-YL]-ACETIC-ACID;(S)-ISOMER
![2-[(4S)-2,2-DIMETHYL-5-OXO-1,3-DIOXOLAN-4-YL]-ACETIC-ACID;(S)-ISOMER](/api/compound/FDwDIhl3LVb.png?h=300&w=458 "2-[(4S)-2,2-DIMETHYL-5-OXO-1,3-DIOXOLAN-4-YL]-ACETIC-ACID;(S)-ISOMER")
Compound 10 1-Trimethylsilyl-1-pentyn-3-one
Compound 11 1-ETHYL-3-TRIMETHYLSILYLPROPYNYL-METHANESULFONATE
Compound 14A (S)-2-OXO-TETRAHYDROFURAN-YL-3-METHANESULFONATE;(S)-ISOMER
Compound 14B (S)-2-OXO-TETRAHYDROFURAN-YL-3-TOLUENESULFONATE;(S)-ISOMER
Compound 15 3-IODOTETRAHYDROFURAN-2-ONE
Compound 18 2-[(4S)-2-ETHYL-5-OXO-1,3-DIOXOLAN-4-YL]-ACETIC-ACID;CIS-ISOMER
![2-[(4S)-2-ETHYL-5-OXO-1,3-DIOXOLAN-4-YL]-ACETIC-ACID;CIS-ISOMER](/api/compound/Fnywj8AkwxB.png?h=300&w=458 "2-[(4S)-2-ETHYL-5-OXO-1,3-DIOXOLAN-4-YL]-ACETIC-ACID;CIS-ISOMER")
Compound 18 2-[(4S)-2-ETHYL-5-OXO-1,3-DIOXOLAN-4-YL]-ACETIC-ACID;TRANS-ISOMER
![2-[(4S)-2-ETHYL-5-OXO-1,3-DIOXOLAN-4-YL]-ACETIC-ACID;TRANS-ISOMER](/api/compound/Bz3ae70jyY2.png?h=300&w=458 "2-[(4S)-2-ETHYL-5-OXO-1,3-DIOXOLAN-4-YL]-ACETIC-ACID;TRANS-ISOMER")
Compound 19 2-[(4S)-2-ETHYL-5-OXO-1,3-DIOXOLAN-4-YL]-ETHANOL;CIS-ISOMER
![2-[(4S)-2-ETHYL-5-OXO-1,3-DIOXOLAN-4-YL]-ETHANOL;CIS-ISOMER](/api/compound/80AA6DA9IJo.png?h=300&w=458 "2-[(4S)-2-ETHYL-5-OXO-1,3-DIOXOLAN-4-YL]-ETHANOL;CIS-ISOMER")
Compound 19 2-[(4S)-2-ETHYL-5-OXO-1,3-DIOXOLAN-4-YL]-ETHANOL;TRANS-ISOMER
![2-[(4S)-2-ETHYL-5-OXO-1,3-DIOXOLAN-4-YL]-ETHANOL;TRANS-ISOMER](/api/compound/FRbDQQij4YW.png?h=300&w=458 "2-[(4S)-2-ETHYL-5-OXO-1,3-DIOXOLAN-4-YL]-ETHANOL;TRANS-ISOMER")
Compound 21 LBGHAIOEEONSFJ-MPYGGPBHSA-N
Compound 22 (3S)-[[(1S)-1-ETHYL-2-IODOPROPYNYL]-OXY]-TETRAHYDROFURAN-2-ONE
![(3S)-[[(1S)-1-ETHYL-2-IODOPROPYNYL]-OXY]-TETRAHYDROFURAN-2-ONE](/api/compound/HySCXzZEB4A.png?h=300&w=458 "(3S)-[[(1S)-1-ETHYL-2-IODOPROPYNYL]-OXY]-TETRAHYDROFURAN-2-ONE")
Compound 23 (3S)-[[(1S,2Z)-1-ETHYL-3-IODO-PROPENYL]-OXY]-TETRAHYDROFURAN-2-ONE
![(3S)-[[(1S,2Z)-1-ETHYL-3-IODO-PROPENYL]-OXY]-TETRAHYDROFURAN-2-ONE](/api/compound/4bNRqVTi4oN.png?h=300&w=458 "(3S)-[[(1S,2Z)-1-ETHYL-3-IODO-PROPENYL]-OXY]-TETRAHYDROFURAN-2-ONE")
Compound 27 (2S)-N-METHOXY-N-METHYL-2-[[(1S,2Z)-1-ETHYL-3-IODO-PROPENYL]-OXY]-4-HYDROXYBUTANAMIDE
![(2S)-N-METHOXY-N-METHYL-2-[[(1S,2Z)-1-ETHYL-3-IODO-PROPENYL]-OXY]-4-HYDROXYBUTANAMIDE](/api/compound/uAhdkkSThg.png?h=300&w=458 "(2S)-N-METHOXY-N-METHYL-2-[[(1S,2Z)-1-ETHYL-3-IODO-PROPENYL]-OXY]-4-HYDROXYBUTANAMIDE")
Compound 28 (2S)-N-METHOXY-N-METHYL-2-[[(1S,2Z)-1-ETHYL-3-IODO-PROPENYL]-OXY]-4-(4-METHOXYBENZYLOXY)-BUTANAMIDE
![(2S)-N-METHOXY-N-METHYL-2-[[(1S,2Z)-1-ETHYL-3-IODO-PROPENYL]-OXY]-4-(4-METHOXYBENZYLOXY)-BUTANAMIDE](/api/compound/Kvf6RTU0i9C.png?h=300&w=458 "(2S)-N-METHOXY-N-METHYL-2-[[(1S,2Z)-1-ETHYL-3-IODO-PROPENYL]-OXY]-4-(4-METHOXYBENZYLOXY)-BUTANAMIDE")
Compound 29 (5S)-5-[[(1S,2Z)-1-ETHYL-3-IODO-2-PROPENYL]-OXY]-7-(4-METHOXYBENZYLOXY)-1-HEPTEN-4-ONE
![(5S)-5-[[(1S,2Z)-1-ETHYL-3-IODO-2-PROPENYL]-OXY]-7-(4-METHOXYBENZYLOXY)-1-HEPTEN-4-ONE](/api/compound/Bqu7oPrEVf8.png?h=300&w=458 "(5S)-5-[[(1S,2Z)-1-ETHYL-3-IODO-2-PROPENYL]-OXY]-7-(4-METHOXYBENZYLOXY)-1-HEPTEN-4-ONE")
Compound 30 (4R,5S)-5-[[(1S,2Z)-1-ETHYL-3-IODO-2-PROPENYL]-OXY]-7-(4-METHOXYBENZYLOXY)-1-HEPTEN-4-OL
![(4R,5S)-5-[[(1S,2Z)-1-ETHYL-3-IODO-2-PROPENYL]-OXY]-7-(4-METHOXYBENZYLOXY)-1-HEPTEN-4-OL](/api/compound/AdTb40BEPwG.png?h=300&w=458 "(4R,5S)-5-[[(1S,2Z)-1-ETHYL-3-IODO-2-PROPENYL]-OXY]-7-(4-METHOXYBENZYLOXY)-1-HEPTEN-4-OL")
Compound 31 DIMETHYL-[(4R,5S)-5-[[(1S,2Z)-1-ETHYL-3-IODO-2-PROPENYL]-OXY]-7-(4-METHOXYBENZYLOXY)-1-HEPTEN-4-OXY]-VINYLSILANE
![DIMETHYL-[(4R,5S)-5-[[(1S,2Z)-1-ETHYL-3-IODO-2-PROPENYL]-OXY]-7-(4-METHOXYBENZYLOXY)-1-HEPTEN-4-OXY]-VINYLSILANE](/api/compound/Dfsnm4vfqBi.png?h=300&w=458 "DIMETHYL-[(4R,5S)-5-[[(1S,2Z)-1-ETHYL-3-IODO-2-PROPENYL]-OXY]-7-(4-METHOXYBENZYLOXY)-1-HEPTEN-4-OXY]-VINYLSILANE")
Compound 32 (2S,8R,9S)-8-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-ETHYL-9-[2-(4-METHOXYBENZYLOXY)-ETHYL]-1-OXA-3Z,5Z-CYCLONONADIENE
![(2S,8R,9S)-8-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-ETHYL-9-[2-(4-METHOXYBENZYLOXY)-ETHYL]-1-OXA-3Z,5Z-CYCLONONADIENE](/api/compound/Da56uhhrk15.png?h=300&w=458 "(2S,8R,9S)-8-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-ETHYL-9-[2-(4-METHOXYBENZYLOXY)-ETHYL]-1-OXA-3Z,5Z-CYCLONONADIENE")
Compound 33 (2S,8R,9S)-8-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-ETHYL-9-(2-HYDROXYETHYL)-1-OXA-3Z,5Z-CYCLONONADIENE
Compound 34 (2S,8R,9S)-8-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-ETHYL-9-(2-OXOETHYL)-1-OXA-3Z,5Z-CYCLONONADIENE
Compound 35 (2S,8R,9S)-8-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-ETHYL-9-[(2Z)-5-(TRIISOPROPYLSILYL)-PENT-2-EN-4-YNYL]-1-OXA-3Z,5Z-CYCLONONADIENE
![(2S,8R,9S)-8-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-ETHYL-9-[(2Z)-5-(TRIISOPROPYLSILYL)-PENT-2-EN-4-YNYL]-1-OXA-3Z,5Z-CYCLONONADIENE](/api/compound/ECkVlNE5cgb.png?h=300&w=458 "(2S,8R,9S)-8-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-ETHYL-9-[(2Z)-5-(TRIISOPROPYLSILYL)-PENT-2-EN-4-YNYL]-1-OXA-3Z,5Z-CYCLONONADIENE")
Compound 36 (2S,8R,9S)-2-ETHYL-8-HYDROXY-9-[(2Z)-PENT-2-EN-4-YNYL]-1-OXA-3Z,5Z-CYCLONONADIENE
![(2S,8R,9S)-2-ETHYL-8-HYDROXY-9-[(2Z)-PENT-2-EN-4-YNYL]-1-OXA-3Z,5Z-CYCLONONADIENE](/api/compound/DxRdRRDoh3O.png?h=300&w=458 "(2S,8R,9S)-2-ETHYL-8-HYDROXY-9-[(2Z)-PENT-2-EN-4-YNYL]-1-OXA-3Z,5Z-CYCLONONADIENE")
Compound 38 (3S,4R)-3-[[(1S,2Z)-1-ETHYL-3-IODO-2-PROPENYL]-OXY]-6-HEPTENE-1,4-DIOL
![(3S,4R)-3-[[(1S,2Z)-1-ETHYL-3-IODO-2-PROPENYL]-OXY]-6-HEPTENE-1,4-DIOL](/api/compound/CyrbEFGyutw.png?h=300&w=458 "(3S,4R)-3-[[(1S,2Z)-1-ETHYL-3-IODO-2-PROPENYL]-OXY]-6-HEPTENE-1,4-DIOL")
Compound 39 (3S,4R)-4-ALLYL-3-[[(1S,2Z)-1-ETHYL-3-IODO-2-PROPENYL]-OXY]-TETRAHYDROFURAN-2-ONE
![(3S,4R)-4-ALLYL-3-[[(1S,2Z)-1-ETHYL-3-IODO-2-PROPENYL]-OXY]-TETRAHYDROFURAN-2-ONE](/api/compound/J6GgCr80MDD.png?h=300&w=458 "(3S,4R)-4-ALLYL-3-[[(1S,2Z)-1-ETHYL-3-IODO-2-PROPENYL]-OXY]-TETRAHYDROFURAN-2-ONE")
Compound 42 [(S)-1-ETHYL-3-TRIMETHYLSILYLPROPYNYL]-3,5-DINITROBENZOATE
![[(S)-1-ETHYL-3-TRIMETHYLSILYLPROPYNYL]-3,5-DINITROBENZOATE](/api/compound/K9s3DAxFRYz.png?h=300&w=458 "[(S)-1-ETHYL-3-TRIMETHYLSILYLPROPYNYL]-3,5-DINITROBENZOATE")
Citation
| Citation | J.AM.CHEM.SOC.,126,12432(2004) |
|---|---|
| Journal | Journal of the American Chemical Society |
| Issue | 39 |
| Volume | 126 |
| Page(s) | 12432-12440 |
| Year | 2004 |
| Author(s) | Scott E. Denmark, Shyh-Ming Yang |
| Publisher | American Chemical Society (ACS) |
| DOI | 10.1021/ja0466863 |