(1R,3AS,4R,5R,6AS)-4-ALLYL-5-[(TERT.-BUTYL-(DIPHENYL)-SILYL]-OXY]-1-METHYLHEXAHYDROPENTALEN-2(1H)-ONE
Compound with spectra: 1 NMR
![(1R,3AS,4R,5R,6AS)-4-ALLYL-5-[(TERT.-BUTYL-(DIPHENYL)-SILYL]-OXY]-1-METHYLHEXAHYDROPENTALEN-2(1H)-ONE](/api/compound/AGdNPzvd3wC.png?ph=true&h=300&w=458 "(1R,3AS,4R,5R,6AS)-4-ALLYL-5-[(TERT.-BUTYL-(DIPHENYL)-SILYL]-OXY]-1-METHYLHEXAHYDROPENTALEN-2(1H)-ONE")
| SpectraBase Compound ID | AGdNPzvd3wC |
|---|---|
| InChI | InChI=1S/C28H36O2Si/c1-6-13-23-25-18-26(29)20(2)24(25)19-27(23)30-31(28(3,4)5,21-14-9-7-10-15-21)22-16-11-8-12-17-22/h6-12,14-17,20,23-25,27H,1,13,18-19H2,2-5H3/t20-,23-,24-,25-,27-/m1/s1 |
| InChIKey | VOFHNPRSHWXEII-MYTFBLFYSA-N |
| Mol Weight | 432.7 g/mol |
| Molecular Formula | C28H36O2Si |
| Exact Mass | 432.248457 g/mol |
| Enantiomer InChIKey | VOFHNPRSHWXEII-HNRCJHGASA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
(1R,3AS,4R,5R,6AS)-1-ALLYL-5-[[TERT.-BUTYL-(DIPHENYL)-SILYL]-OXY]-4-METHYLHEXAHYDROPENTALEN-2(1H)-ONE
[[(1AR,1BS,3R,4R,4AS,5AS)-4-ALLYL-OCTAHYDROPENTALENO-[1,2-B]-OXIREN-3-YL]-OXY]-(TERT.-BUTYL)-DIPHENYLSILANE
(1R,2R,3aS,4aS)-2-t-Butyldiphenylsilyloxy-3a-carbomethoxy-1-ethylbicyclo[3.1.0]hexane
(1S,2R,3aS,4aS)-2-t-Butyldiphenylsilyloxy-1-ethyl-3a-carbomethoxybicyclo[3.1.0]hexane
4-Nitro-benzoicacid(1R,2R,3R,5R)-3-(tert-butyl-diphenyl-silanyloxy)-5-methoxycarbonyl-2-methyl-cyclohexyl ester
(2.beta.)-5-[(1',1'-Dimethylethyl)diphenylsilyloxy]octahydro-1-(1"-acetyloxy-2"-octenyl)-2-pentalenol
(2.alpha.)-5-[(1',1'-Dimethylethyl)diphenylsilyloxy]octahydro-1-(1"-acetyloxy-2"-octenyl)-2-pentalenol
(4S)-4-[(2R,4R,5R)-4-(tert-Butyldiphenylsilyloxy)-5-(5-trimethylsilylpent-2(E)-en-4-ynyl)tetrahydrofuran-2-yl]-2,2-dimethyl[[1,3]dioxolane
(2S)-2-[(4S,5S,2R)-4-(tert-Butyldiphenylsiloxy)-5-pentyl-tetrahydrofuran-2-yl]-2-methanesulfonyloxyethyl benzoate
(2R)-2-[(4S,5S,2R)-4-(tert-Butyldiphenylsiloxy)-5-pentyl-tetrahydrofuran-2-yl]-2-methylsulfonyloxyethyl benzoate
| Title | Journal or Book | Year |
|---|---|---|
| Doing it Twice: Asymmetric Deprotonation/Alkylation of Weiss Diketone Derivatives as Key Steps in the Functionalization of Bicyclo[3.3.0]octanes | European Journal of Organic Chemistry | 2012 |