(1R,3AS,4R,5R,6AS)-1-ALLYL-5-[[TERT.-BUTYL-(DIPHENYL)-SILYL]-OXY]-4-METHYLHEXAHYDROPENTALEN-2(1H)-ONE
Compound with spectra: 1 NMR
![(1R,3AS,4R,5R,6AS)-1-ALLYL-5-[[TERT.-BUTYL-(DIPHENYL)-SILYL]-OXY]-4-METHYLHEXAHYDROPENTALEN-2(1H)-ONE](/api/compound/EoX9XcwKf5X.png?ph=true&h=300&w=458 "(1R,3AS,4R,5R,6AS)-1-ALLYL-5-[[TERT.-BUTYL-(DIPHENYL)-SILYL]-OXY]-4-METHYLHEXAHYDROPENTALEN-2(1H)-ONE")
| SpectraBase Compound ID | EoX9XcwKf5X |
|---|---|
| InChI | InChI=1S/C28H36O2Si/c1-6-13-23-25-19-27(20(2)24(25)18-26(23)29)30-31(28(3,4)5,21-14-9-7-10-15-21)22-16-11-8-12-17-22/h6-12,14-17,20,23-25,27H,1,13,18-19H2,2-5H3/t20-,23-,24-,25-,27-/m1/s1 |
| InChIKey | RLMRFLUHIRDOPF-MYTFBLFYSA-N |
| Mol Weight | 432.7 g/mol |
| Molecular Formula | C28H36O2Si |
| Exact Mass | 432.248457 g/mol |
| Enantiomer InChIKey | RLMRFLUHIRDOPF-HNRCJHGASA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
(1S,3AR,5R,6R,6AS)-1-ALLYL-5-[[TERT.-BUTYL-(DIPHENYL)-SILYL]-OXY]-6-METHYLHEXAHYDROPENTALEN-2(1H)-ONE
(3AR,5R,6R,6AS)-6-ALLYL-5-[[TERT.-BUTYL-(DIPHENYL)-SILYL]-OXY]-4,5,6,6A-TETRAHYDROPENTALEN-1(3AH)-ONE
(3AR,4R,5R,6AS)-4-ALLYL-5-[[TERT.-BUTYL-(DIPHENYL)-SILYL]-OXY]-4,5,6,6A-TETRAHYDROPENTALEN-1(3AH)-ONE
(2.alpha.)-5-[(1',1'-Dimethylethyl)diphenylsilyloxy]octahydro-1-(1"-acetyloxy-2"-octenyl)-2-pentalenol
(2.beta.)-5-[(1',1'-Dimethylethyl)diphenylsilyloxy]octahydro-1-(1"-acetyloxy-2"-octenyl)-2-pentalenol
(2S,4S,5S,7E,9E,11E)-4-((tert-Butyldiphenylsilyl)oxy)-1,2-(isopropylidenedioxy)-5,7,11-trimethyl-12-(2'-methyloxazol-4'-yl)-7,9,11-dodecatrien-6-one
Ethyl (1S,3R)-3-[(t-butyldiphenylsilyl)oxy]-4-methylbicyclo[3.1.0]hexane-1-carboxylate
(1S,3R,4S,5S)-3-(tert-Butyl-diphenyl-silanyloxy)-4-methyl-bicyclo[3.1.0]hexane-1-carboxylic acid ethyl ester
(S)-1-[(2R,3aS,5S,6aS)-5-(tert-Butyl-diphenyl-silanyloxy)-2-triethylsilanyloxy-octahydro-pentalen-1-yl]-4-methyl-nona-1,6-diyn-3-one
(4S)-4-[(2R,4R,5R)-4-(tert-Butyldiphenylsilyloxy)-5-(5-trimethylsilylpent-2(E)-en-4-ynyl)tetrahydrofuran-2-yl]-2,2-dimethyl[[1,3]dioxolane
| Title | Journal or Book | Year |
|---|---|---|
| Doing it Twice: Asymmetric Deprotonation/Alkylation of Weiss Diketone Derivatives as Key Steps in the Functionalization of Bicyclo[3.3.0]octanes | European Journal of Organic Chemistry | 2012 |