[[(1AR,1BS,3R,4R,4AS,5AS)-4-ALLYL-OCTAHYDROPENTALENO-[1,2-B]-OXIREN-3-YL]-OXY]-(TERT.-BUTYL)-DIPHENYLSILANE
Compound with spectra: 1 NMR
![[[(1AR,1BS,3R,4R,4AS,5AS)-4-ALLYL-OCTAHYDROPENTALENO-[1,2-B]-OXIREN-3-YL]-OXY]-(TERT.-BUTYL)-DIPHENYLSILANE](/api/compound/4f8bf8SAYer.png?ph=true&h=300&w=458 "[[(1AR,1BS,3R,4R,4AS,5AS)-4-ALLYL-OCTAHYDROPENTALENO-[1,2-B]-OXIREN-3-YL]-OXY]-(TERT.-BUTYL)-DIPHENYLSILANE")
| SpectraBase Compound ID | 4f8bf8SAYer |
|---|---|
| InChI | InChI=1S/C27H34O2Si/c1-5-12-21-22-17-25-26(28-25)23(22)18-24(21)29-30(27(2,3)4,19-13-8-6-9-14-19)20-15-10-7-11-16-20/h5-11,13-16,21-26H,1,12,17-18H2,2-4H3/t21-,22-,23+,24-,25+,26-/m1/s1 |
| InChIKey | NOQKONSWFJWUKV-OPOYRNPBSA-N |
| Mol Weight | 418.7 g/mol |
| Molecular Formula | C27H34O2Si |
| Exact Mass | 418.232807 g/mol |
| Enantiomer InChIKey | NOQKONSWFJWUKV-ZCGSOJCWSA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
(1R,3AS,4R,5R,6AS)-4-ALLYL-5-[(TERT.-BUTYL-(DIPHENYL)-SILYL]-OXY]-1-METHYLHEXAHYDROPENTALEN-2(1H)-ONE
(1R,2R,3aS,4aS)-2-t-Butyldiphenylsilyloxy-3a-carbomethoxy-1-ethylbicyclo[3.1.0]hexane
(1S,2R,3aS,4aS)-2-t-Butyldiphenylsilyloxy-1-ethyl-3a-carbomethoxybicyclo[3.1.0]hexane
(2R)-2-[(4S,5S,2R)-4-(tert-Butyldiphenylsiloxy)-5-pentyl-tetrahydrofuran-2-yl]-2-methylsulfonyloxyethyl benzoate
(2S)-2-[(4S,5S,2R)-4-(tert-Butyldiphenylsiloxy)-5-pentyl-tetrahydrofuran-2-yl]-2-methanesulfonyloxyethyl benzoate
(2.alpha.)-5-[(1',1'-Dimethylethyl)diphenylsilyloxy]octahydro-1-(1"-acetyloxy-2"-octenyl)-2-pentalenol
(2.beta.)-5-[(1',1'-Dimethylethyl)diphenylsilyloxy]octahydro-1-(1"-acetyloxy-2"-octenyl)-2-pentalenol
4-Nitro-benzoicacid(1R,2R,3R,5R)-3-(tert-butyl-diphenyl-silanyloxy)-5-methoxycarbonyl-2-methyl-cyclohexyl ester
(6R,8R)-8-((2R,4R,5R)-5-(2-Hydroxyethyl)-4-methyltetrahydrofuran-2-yl)-2,2,11,11-tetramethyl-3,3,10,10-tetraphenyl-4,9-dioxa-3,10-disiladodecan-6-yl isobutyrate
(6R,8R)-2,2,11,11-Tetramethyl-8-((2R,4R,5R)-4-methyl-5-(2-oxoethyl)tetrahydrofuran-2-yl)-3,3,10,10-tetraphenyl-4,9-dioxa-3,10-disiladodecan-6-yl isobutyrate
| Title | Journal or Book | Year |
|---|---|---|
| Doing it Twice: Asymmetric Deprotonation/Alkylation of Weiss Diketone Derivatives as Key Steps in the Functionalization of Bicyclo[3.3.0]octanes | European Journal of Organic Chemistry | 2012 |