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1,3:4,6-DI-O-BENZYLIDENE-2-O-ISOPROPYL-3-O-[(R)-2,2'-O,O-(1,1'-BINAPHTHYL)-DIOXOPHOSPHITE]-D-MANNITOL

Compound with spectra: 2 NMR

1,3:4,6-DI-O-BENZYLIDENE-2-O-ISOPROPYL-3-O-[(R)-2,2'-O,O-(1,1'-BINAPHTHYL)-DIOXOPHOSPHITE]-D-MANNITOL
SpectraBase Compound ID 7jIwWjvnuJx
InChI InChI=1S/2C43H39O8P/c2*1-27(2)46-36-25-44-42(30-15-5-3-6-16-30)47-40(36)41-37(26-45-43(48-41)31-17-7-4-8-18-31)51-52-49-34-23-21-28-13-9-11-19-32(28)38(34)39-33-20-12-10-14-29(33)22-24-35(39)50-52/h2*3-24,27,36-37,40-43H,25-26H2,1-2H3/t2*36-,37-,40-,41-,42?,43?/m11/s1
InChIKey IKQDRBPBTQWORQ-PTIXSQPYSA-N
Mol Weight 1429.5 g/mol
Molecular Formula C86H78O16P2
Exact Mass 1428.47651 g/mol
Enantiomer InChIKey IKQDRBPBTQWORQ-GNHATRLKSA-N

View Spectrum of 1,3:4,6-DI-O-BENZYLIDENE-2-O-ISOPROPYL-3-O-[(R)-2,2'-O,O-(1,1'-BINAPHTHYL)-DIOXOPHOSPHITE]-D-MANNITOL

31P NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent DMSO-D6

View Spectrum of 1,3:4,6-DI-O-BENZYLIDENE-2-O-ISOPROPYL-3-O-[(R)-2,2'-O,O-(1,1'-BINAPHTHYL)-DIOXOPHOSPHITE]-D-MANNITOL

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent DMSO-D6
1,3:4,6-DI-O-BENZYLIDENE-2-O-METHYL-3-O-[(R)-2,2'-O,O-(1,1'-BINAPHTHYL)-DIOXOPHOSPHITE]-D-MANNITOL
1,3:4,6-DI-O-BENZYLIDENE-2-O-PROPYL-3-O-[(R)-2,2'-O,O-(1,1'-BINAPHTHYL)-DIOXOPHOSPHITE]-D-MANNITOL
1,3:4,6-DI-O-BENZYLIDENE-2-O-BENZYL-3-O-[(S)-2,2'-O,O-(1,1'-BINAPHTHYL)-DIOXOPHOSPHITE]-D-MANNITOL
1,3:4,6-DI-O-BENZYLIDENE-2-O-BENZYL-3-O-[(R)-2,2'-O,O-(1,1'-BINAPHTHYL)-DIOXOPHOSPHITE]-D-MANNITOL
1,3:4,6-DI-O-BENZYLIDENE-2-O-ISOBUTYL-3-O-[(R)-2,2'-O,O-(1,1'-BINAPHTHYL)-DIOXOPHOSPHITE]-D-MANNITOL
3,5-BIS-[[(R)-1,1'-BINAPHTHYL-2,2'-DIYL]-PHOSPHITE]-6-DEOXY-1,2-O-ISOPROPYLIDENE-ALPHA-D-ALLOFURANOSE
JWTQHPHWEOPEHV-UHFFFAOYSA-N
1,3:4,6-DI-O-BENZYLIDENE-2-O-BENZYL-3-O-[2,2'-O,O-(3,3',5,5'-TETRA-TERT.-BUTYL-1,1'-BIPHENYL)-DIOXOPHOSPHITE]-D-MANNITOL
JNLXVQSOECOXGP-UHFFFAOYSA-N
FPQCUYIJGYJOBA-UHFFFAOYSA-N
Title Journal or Book Year
A Novel Class of P−O Monophosphite Ligands Derived from d-Mannitol:  Broad Applications in Highly Enantioselective Rh-Catalyzed Hydrogenations The Journal of Organic Chemistry 2004
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