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1,3:4,6-DI-O-BENZYLIDENE-2-O-METHYL-3-O-[(R)-2,2'-O,O-(1,1'-BINAPHTHYL)-DIOXOPHOSPHITE]-D-MANNITOL

Compound with spectra: 4 NMR

1,3:4,6-DI-O-BENZYLIDENE-2-O-METHYL-3-O-[(R)-2,2'-O,O-(1,1'-BINAPHTHYL)-DIOXOPHOSPHITE]-D-MANNITOL
SpectraBase Compound ID FzGZZoA24sM
InChI InChI=1S/C41H35O8P/c1-42-34-24-43-40(28-14-4-2-5-15-28)45-38(34)39-35(25-44-41(46-39)29-16-6-3-7-17-29)49-50-47-32-22-20-26-12-8-10-18-30(26)36(32)37-31-19-11-9-13-27(31)21-23-33(37)48-50/h2-23,34-35,38-41H,24-25H2,1H3/t34-,35-,38-,39-,40?,41?/m1/s1
InChIKey PSWRRWFCDZTQBC-GMJIMUIXSA-N
Mol Weight 686.7 g/mol
Molecular Formula C41H35O8P
Exact Mass 686.206955 g/mol
Enantiomer InChIKey PSWRRWFCDZTQBC-NGYAFIQQSA-N

View Spectrum of 1,3:4,6-DI-O-BENZYLIDENE-2-O-METHYL-3-O-[(R)-2,2'-O,O-(1,1'-BINAPHTHYL)-DIOXOPHOSPHITE]-D-MANNITOL

31P NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent DMSO-D6

View Spectrum of 1,3:4,6-DI-O-BENZYLIDENE-2-O-METHYL-3-O-[(R)-2,2'-O,O-(1,1'-BINAPHTHYL)-DIOXOPHOSPHITE]-D-MANNITOL

31P NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent DMSO-D6

View Spectrum of 1,3:4,6-DI-O-BENZYLIDENE-2-O-METHYL-3-O-[(R)-2,2'-O,O-(1,1'-BINAPHTHYL)-DIOXOPHOSPHITE]-D-MANNITOL

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent DMSO-D6

View Spectrum of 1,3:4,6-DI-O-BENZYLIDENE-2-O-METHYL-3-O-[(R)-2,2'-O,O-(1,1'-BINAPHTHYL)-DIOXOPHOSPHITE]-D-MANNITOL

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent DMSO-D6
  • 1,3:4,6-DI-O-BENZYLIDENE-2-O-METHYL-3-O-[(S)-2,2'-O,O-(1,1'-BINAPHTHYL)-DIOXOPHOSPHITE]-D-MANNITOL
1,3:4,6-DI-O-BENZYLIDENE-2-O-PROPYL-3-O-[(R)-2,2'-O,O-(1,1'-BINAPHTHYL)-DIOXOPHOSPHITE]-D-MANNITOL
1,3:4,6-DI-O-BENZYLIDENE-2-O-ISOPROPYL-3-O-[(R)-2,2'-O,O-(1,1'-BINAPHTHYL)-DIOXOPHOSPHITE]-D-MANNITOL
JNLXVQSOECOXGP-UHFFFAOYSA-N
FPQCUYIJGYJOBA-UHFFFAOYSA-N
(S)-4-(2,4-Di-tert-butyl-6-diphenylphosphanyl-phenoxy)-3,5-dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalene
O,O'-[(R)-1,1'-Binaphthalene-2,2'-diyl] N-(1,1'-Biphenyl-2-yl)methyl]-N-[(R)-1-phenylethyl]phosphoramidite
FSAUMSKXRVZRAB-UHFFFAOYSA-N
NVSDRFOFAAVTSD-UHFFFAOYSA-N
HRJABHWZEQHPFS-UHFFFAOYSA-N
CZKOIYVABJQCQH-UHFFFAOYSA-N
Title Journal or Book Year
A Novel Class of P−O Monophosphite Ligands Derived from d-Mannitol:  Broad Applications in Highly Enantioselective Rh-Catalyzed Hydrogenations The Journal of Organic Chemistry 2004
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