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1,3:4,6-DI-O-BENZYLIDENE-2-O-BENZYL-3-O-[2,2'-O,O-(3,3',5,5'-TETRA-TERT.-BUTYL-1,1'-BIPHENYL)-DIOXOPHOSPHITE]-D-MANNITOL

Compound with spectra: 2 NMR

1,3:4,6-DI-O-BENZYLIDENE-2-O-BENZYL-3-O-[2,2'-O,O-(3,3',5,5'-TETRA-TERT.-BUTYL-1,1'-BIPHENYL)-DIOXOPHOSPHITE]-D-MANNITOL
SpectraBase Compound ID YvI8WefteN
InChI InChI=1S/C55H67O8P/c1-52(2,3)38-28-40-41-29-39(53(4,5)6)31-43(55(10,11)12)47(41)63-64(62-46(40)42(30-38)54(7,8)9)61-45-34-58-51(37-26-20-15-21-27-37)60-49(45)48-44(56-32-35-22-16-13-17-23-35)33-57-50(59-48)36-24-18-14-19-25-36/h13-31,44-45,48-51H,32-34H2,1-12H3/t44-,45-,48-,49-,50?,51?/m1/s1
InChIKey JBJBPTNFFKPZHO-RZSHCYCQSA-N
Mol Weight 887.1 g/mol
Molecular Formula C55H67O8P
Exact Mass 886.457356 g/mol
Enantiomer InChIKey JBJBPTNFFKPZHO-SUMFPQEZSA-N

View Spectrum of 1,3:4,6-DI-O-BENZYLIDENE-2-O-BENZYL-3-O-[2,2'-O,O-(3,3',5,5'-TETRA-TERT.-BUTYL-1,1'-BIPHENYL)-DIOXOPHOSPHITE]-D-MANNITOL

31P NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent DMSO-D6

View Spectrum of 1,3:4,6-DI-O-BENZYLIDENE-2-O-BENZYL-3-O-[2,2'-O,O-(3,3',5,5'-TETRA-TERT.-BUTYL-1,1'-BIPHENYL)-DIOXOPHOSPHITE]-D-MANNITOL

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent DMSO-D6
1,3:4,6-DI-O-BENZYLIDENE-2-O-BENZYL-3-O-[(R)-2,2'-O,O-(1,1'-BINAPHTHYL)-DIOXOPHOSPHITE]-D-MANNITOL
1,3:4,6-DI-O-BENZYLIDENE-2-O-BENZYL-3-O-[(S)-2,2'-O,O-(1,1'-BINAPHTHYL)-DIOXOPHOSPHITE]-D-MANNITOL
1,3:4,6-DI-O-BENZYLIDENE-2-O-ISOBUTYL-3-O-[(R)-2,2'-O,O-(1,1'-BINAPHTHYL)-DIOXOPHOSPHITE]-D-MANNITOL
1,3:4,6-DI-O-BENZYLIDENE-2-O-DIPHENYLMETHYL-3-O-[(R)-2,2'-O,O-(1,1'-BINAPHTHYL)-DIOXOPHOSPHITE]-D-MANNITOL
1,3:4,6-DI-O-BENZYLIDENE-2-O-PROPYL-3-O-[(R)-2,2'-O,O-(1,1'-BINAPHTHYL)-DIOXOPHOSPHITE]-D-MANNITOL
1,3:4,6-DI-O-BENZYLIDENE-2-O-ISOPROPYL-3-O-[(R)-2,2'-O,O-(1,1'-BINAPHTHYL)-DIOXOPHOSPHITE]-D-MANNITOL
METHYL-(2,4-DI-O-BENZOYL-3-O-CHLOROACETYL-ALPHA-L-RHAMNOPYRANOSYL)-(1->3)-(2,4-DI-O-BENZOYL-ALPHA-L-RHAMNOPYRANOSYL)-(1->2)-4,6-O-BENZYLIDE
#12;[4-O-BENZOYL-3-O-TERT.-BUTYLDIMETHYLSILYL-2,6-DIDEOXY-2-IODO-ALPHA-D-MANNO-HEXOPYRANOSYL]-(1->2)-METHYL-(3-O-BENZYL-4,6-O-BENZYLIDENE-BETA-D-GLUCOPYRANOSI
PGOLLLDFXYZNAM-MMAMNPGNSA-N
#8D;8-METHOXYCARBONYLOCTYL-ALPHA-D-GALACTOPYRANOSYL-(1->3)-BETA-D-GALACTOPYRANOSYL-(1->4)-2-DEOXY-2-(METHYL-BETA-L-GALACTOHEXOPYRANOSYLURONAMIDE)-BETA-D-GLUCOP
Title Journal or Book Year
A Novel Class of P−O Monophosphite Ligands Derived from d-Mannitol:  Broad Applications in Highly Enantioselective Rh-Catalyzed Hydrogenations The Journal of Organic Chemistry 2004
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