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[(2S,3R,4R,6S)-6-ETHYNYL-2-METHOXY-3-[(S)-OXIRAN-2-YL]-3,4,5,6-TETRAHYDRO-2H-PYRAN-4-YL]-DIMETHYL-PHENYLSILANE

Compound with spectra: 1 NMR

[(2S,3R,4R,6S)-6-ETHYNYL-2-METHOXY-3-[(S)-OXIRAN-2-YL]-3,4,5,6-TETRAHYDRO-2H-PYRAN-4-YL]-DIMETHYL-PHENYLSILANE
SpectraBase Compound ID 7CHLqe8d2nl
InChI InChI=1S/C18H24O3Si/c1-5-13-11-16(17(15-12-20-15)18(19-2)21-13)22(3,4)14-9-7-6-8-10-14/h1,6-10,13,15-18H,11-12H2,2-4H3/t13-,15-,16-,17+,18+/m1/s1
InChIKey IIZXLPIZHQBCJN-XABWRGDLSA-N
Mol Weight 316.47 g/mol
Molecular Formula C18H24O3Si
Exact Mass 316.149471 g/mol
Enantiomer InChIKey IIZXLPIZHQBCJN-OGCZYDBJSA-N

View Spectrum of [(2S,3R,4R,6S)-6-ETHYNYL-2-METHOXY-3-[(S)-OXIRAN-2-YL]-3,4,5,6-TETRAHYDRO-2H-PYRAN-4-YL]-DIMETHYL-PHENYLSILANE

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
#42A;TERT.-BUTYL-[(2S,3R,4R,6S)-3-[(S)-(TERT.-BUTYLDIMETHYLSILOXY)-2-[(4-METHOXYBENZYLOXY)-ETHYL]-6-ETHYNYL-2-METHOXY-3,4,5,6-TETRAHYDRO-2H-4-YLOXY]-DIMETHYLSI
(2S,3R,4R,6S)-3-[(S)-1-(2,3-DIMETHYLBUT-2-YL)-DIMETHYLSILOXY]-2-(4-METHOXYBENZYLOXY)-ETHYL]-6-ETHYNYL-2-METHOXY-3,4,5,6-TETRAHYDO-2H-PYRAN-4-OL
#44B;(S)-1-[(2S,3S,4R,6S)-4-[DIMETHYL-(1,1,2-TRIMETHYLPROPYL)-SILOXY]-6-ETHYNYL-2-METHOXY-3,4,5,6-TETRAHYDRO-2H-PYRAN-3-YL]-2-(4-METHOXY-BENZYLOXY)-ETHAN-1-OL
Methyl (2R,3R)-3-dimethyl(phenyl)silyl-2-[(S)-.alpha.-hydroxybenzyl]-3-phenylpropanoate
Methyl (2RS,3RS)-2-allyl-3-dimethyl(phenyl)silyl-2-methyl-3-phenylpropanoate
(1R,2S)-2-[DIMETHYL-(PHENYL)-SILYL]-1-[(R)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YL]-BUT-3-ENYL-ACETATE
(1S,2R)-2-[DIMETHYL-(PHENYL)-SILYL]-1-[(R)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YL]-BUT-3-ENYL-ACETATE
Methyl (2RS,3SR)-3-dimethyl(phenyl)silyl-2-isopropyl-2-methyl-3-phenylpropanoate
5-Acetoxy-4-[(dimethylphenylsilyl)methyl]hexahydro-2H-cyclopenta[b]furan-2-one
(5S)-1-[(3S)-3-[dimethyl(phenyl)silyl]-5-(1,3-dioxolan-2-yl)-1-oxopentyl]-5-[(triphenylmethyl)oxymethyl]-2-pyrrolidinone
Title Journal or Book Year
Stereocontrolled Synthesis of a Cn-Cn+7Building Block (“Eastern Moiety”) for the Unnatural Enantiomers of Important Polyol,Polyene Antibiotics Based on a Ring-Closing Metathesis and an Aldol Addition of a Lactone Enolate European Journal of Organic Chemistry 2013
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