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#44B;(S)-1-[(2S,3S,4R,6S)-4-[DIMETHYL-(1,1,2-TRIMETHYLPROPYL)-SILOXY]-6-ETHYNYL-2-METHOXY-3,4,5,6-TETRAHYDRO-2H-PYRAN-3-YL]-2-(4-METHOXY-BENZYLOXY)-ETHAN-1-OL

Compound with spectra: 2 NMR

#44B;(S)-1-[(2S,3S,4R,6S)-4-[DIMETHYL-(1,1,2-TRIMETHYLPROPYL)-SILOXY]-6-ETHYNYL-2-METHOXY-3,4,5,6-TETRAHYDRO-2H-PYRAN-3-YL]-2-(4-METHOXY-BENZYLOXY)-ETHAN-1-OL
SpectraBase Compound ID I00s9WGhKPQ
InChI InChI=1S/C26H42O6Si/c1-10-20-15-23(32-33(8,9)26(4,5)18(2)3)24(25(29-7)31-20)22(27)17-30-16-19-11-13-21(28-6)14-12-19/h1,11-14,18,20,22-25,27H,15-17H2,2-9H3/t20-,22-,23-,24+,25+/m1/s1
InChIKey SHHPALBSFILHHA-HFDWIEFGSA-N
Mol Weight 478.7 g/mol
Molecular Formula C26H42O6Si
Exact Mass 478.275066 g/mol
Enantiomer InChIKey SHHPALBSFILHHA-OXZBAMKGSA-N

View Spectrum of #44B;(S)-1-[(2S,3S,4R,6S)-4-[DIMETHYL-(1,1,2-TRIMETHYLPROPYL)-SILOXY]-6-ETHYNYL-2-METHOXY-3,4,5,6-TETRAHYDRO-2H-PYRAN-3-YL]-2-(4-METHOXY-BENZYLOXY)-ETHAN-1-OL

29Si NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3

View Spectrum of #44B;(S)-1-[(2S,3S,4R,6S)-4-[DIMETHYL-(1,1,2-TRIMETHYLPROPYL)-SILOXY]-6-ETHYNYL-2-METHOXY-3,4,5,6-TETRAHYDRO-2H-PYRAN-3-YL]-2-(4-METHOXY-BENZYLOXY)-ETHAN-1-OL

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
#42A;TERT.-BUTYL-[(2S,3R,4R,6S)-3-[(S)-(TERT.-BUTYLDIMETHYLSILOXY)-2-[(4-METHOXYBENZYLOXY)-ETHYL]-6-ETHYNYL-2-METHOXY-3,4,5,6-TETRAHYDRO-2H-4-YLOXY]-DIMETHYLSI
(2R,4R,6R,8R,10S)-10-(TERT.-BUTYLDIMETHYLSILANYLOXY)-2-(2'-ETHYLPROP-1'-EN-3'-YL)-8-(PARA-METHOXYBENZYLOXYMETHYL)-1,7-DIOXASPIRO-(5.5)-UNDECAN-4-OL;(AE)
(2R,4S,6R,8R,10S)-10-(TERT.-BUTYLDIMETHYLSILANYLOXY)-2-(2'-ETHYLPROP-1'-EN-3'-YL)-8-(PARA-METHOXYBENZYLOXYMETHYL)-1,7-DIOXASPIRO-(5.5)-UNDECAN-4-OL;(AE)
#20;(2R,4S,6R,8R,10S)-10-(TERT.-BUTYLDIMETHYLSILANYLOXY)-2-(2'-ETHYLPROP-1'-EN-3'-YL)-4-METHOXY-8-(PARA-METHOXYBENZYLOXYMETHYL)-1,7-DIOXASPIRO-(5.5)-UNDECANE
#2;(2'S,4'S,6'R,8'R,10'S)-1-(10'-(TERT.-BUTYLDIMETHYLSILANYLOXY)-4'-METHOXY-8'-(PARA-METHOXYBENZYLOXYMETHYL)-1',7'-DIOXADISPIRO-(5.5)-UNDEC-2'-YL)-BUTAN-2-ONE
[(2S,3R,4R,6S)-6-ETHYNYL-2-METHOXY-3-[(S)-OXIRAN-2-YL]-3,4,5,6-TETRAHYDRO-2H-PYRAN-4-YL]-DIMETHYL-PHENYLSILANE
.alpha.-D-Allofuranose, 3,5-dideoxy-5-(hydroxymethyl)-3-[[(4-methoxyphenyl)methoxy]methyl]-1,2-O-(1-methylethylidene)-6-O-(phenylmethyl)-
2.beta.-[(p-Methoxy)benzyloxy]-3.alpha.-[(triisopropylsilyl)oxy]-4.beta.-methyl-8-oxabicyclo[3.2.1]oct-6-ene
(2R,3S)-Acetic Acid 2-[(Benzyloxy)(2R,3S)-3-(tert-butyldimethylsiloxy)tetrahydropyran-2-yl]-(R)-methyl]tetrahydropyran-3-yl Ester
(1S,4S,5S,6R)-6-endo-Benzyloxy-5-exo-tert-butyldimethylsilyloxy-7-oxa-bicyclo(2.2.1)heptan-2-one
Title Journal or Book Year
Stereocontrolled Synthesis of a Cn–Cn+7 Building Block (“Eastern Moiety”) for the Unnatural Enantiomers of Important Polyol,Polyene Antibiotics Based on a Ring‐Closing Metathesis and an Aldol Addition of a Lactone Enolate European Journal of Organic Chemistry 2013
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