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(2S,3R,4R,6S)-3-[(S)-1-(2,3-DIMETHYLBUT-2-YL)-DIMETHYLSILOXY]-2-(4-METHOXYBENZYLOXY)-ETHYL]-6-ETHYNYL-2-METHOXY-3,4,5,6-TETRAHYDO-2H-PYRAN-4-OL

Compound with spectra: 2 NMR

(2S,3R,4R,6S)-3-[(S)-1-(2,3-DIMETHYLBUT-2-YL)-DIMETHYLSILOXY]-2-(4-METHOXYBENZYLOXY)-ETHYL]-6-ETHYNYL-2-METHOXY-3,4,5,6-TETRAHYDO-2H-PYRAN-4-OL
SpectraBase Compound ID EAsRuH0tR9Q
InChI InChI=1S/C26H42O6Si/c1-10-20-15-22(27)24(25(29-7)31-20)23(32-33(8,9)26(4,5)18(2)3)17-30-16-19-11-13-21(28-6)14-12-19/h1,11-14,18,20,22-25,27H,15-17H2,2-9H3/t20-,22-,23-,24-,25+/m1/s1
InChIKey ISROSJQYTHIWAY-MRPKTGBJSA-N
Mol Weight 478.7 g/mol
Molecular Formula C26H42O6Si
Exact Mass 478.275066 g/mol
Enantiomer InChIKey ISROSJQYTHIWAY-XFASLETNSA-N

View Spectrum of (2S,3R,4R,6S)-3-[(S)-1-(2,3-DIMETHYLBUT-2-YL)-DIMETHYLSILOXY]-2-(4-METHOXYBENZYLOXY)-ETHYL]-6-ETHYNYL-2-METHOXY-3,4,5,6-TETRAHYDO-2H-PYRAN-4-OL

29Si NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3

View Spectrum of (2S,3R,4R,6S)-3-[(S)-1-(2,3-DIMETHYLBUT-2-YL)-DIMETHYLSILOXY]-2-(4-METHOXYBENZYLOXY)-ETHYL]-6-ETHYNYL-2-METHOXY-3,4,5,6-TETRAHYDO-2H-PYRAN-4-OL

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
#44B;(S)-1-[(2S,3S,4R,6S)-4-[DIMETHYL-(1,1,2-TRIMETHYLPROPYL)-SILOXY]-6-ETHYNYL-2-METHOXY-3,4,5,6-TETRAHYDRO-2H-PYRAN-3-YL]-2-(4-METHOXY-BENZYLOXY)-ETHAN-1-OL
(2S,3R,4S,5R)-3,5-bis[[tert-butyl(dimethyl)silyl]oxy]-N-methoxy-N,2,4-trimethyl-6-phenylmethoxy-hexanamide
(S)-1-[(2S,3R,4R,6S)-4-(DIMETHYLPHENYLSILYL)-6-ETHYNYL-2-METHOXY-3,4,5,6-TETRAHYDRO-2H-PYRAN-3-YL]-ETHANE-1,2-DIOL
(1S,1'S,2R,3S,6S)-{[6-{2'-{[Dimethyl(1,1,2-trimethylpropyl)silyl]oxy}-1'-methylethyl}-2,3-epoxy-3-methylcyclohexyl]oxy}trimethylsilane
(1R,1'R,2R,3S,6S)-{[6-{2'-{[Dimethyl(1,1,2-trimethylpropyl)silyl]oxy}-1'-methylethyl}-2,3-epoxy-3-methylcyclohexyl]oxy}trimethylsilane
Methyl 2-O-benzyl-6-deoxy-5-C-methyl-3-O-tert-butyldimethylsilyl-A-L-arabino-hexofuranoside
3,4,6-Tri-O-benzyl-1-O-(3,4-dimethoxybenzylidene)-5-O-tert-butyldimethylsilyl-D-glucitol
(2R,3R,4S,5S,6S,6(2E))-3,5-Di-(tert-butyldimethylsiloxy)-6-(4-hydroxybutenyl)-2-methoxy-4-methyl-3,4,5,6-tetrahydro-2H-pyran
1-O-,2-C-,3-O-Trimethyl-4,6-O-benzylidene-2-deoxy-A-D-glucopyranoside
(2S,6R,8S,10S,3'R)-2-[4'-(TERT.-BUTYLDIMETHYLSILANYLOXY)-3'-METHYL-2'-METHYLENEBUTYL]-10-HYDROXY-8-[2''-(PARA-METHOXYBENZYLOXY)-ETHYL]-1,7-DIOXA-SPIRO-[5.5]-UND
Title Journal or Book Year
Stereocontrolled Synthesis of a Cn-Cn+7Building Block (“Eastern Moiety”) for the Unnatural Enantiomers of Important Polyol,Polyene Antibiotics Based on a Ring-Closing Metathesis and an Aldol Addition of a Lactone Enolate European Journal of Organic Chemistry 2013
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