(SYN)-1-[(4S,5R)-5-[(S)-2-(TERT.-BUTYLDIPHENYLSILYLOXY)-3-METHYLBUTYL]-2-PHENYL-1,3,2-DIOXABOROLAN-4-YL]-ETHANONE;MAJOR-DIASTEREOMER
Compound with spectra: 1 NMR
![(SYN)-1-[(4S,5R)-5-[(S)-2-(TERT.-BUTYLDIPHENYLSILYLOXY)-3-METHYLBUTYL]-2-PHENYL-1,3,2-DIOXABOROLAN-4-YL]-ETHANONE;MAJOR-DIASTEREOMER](/api/compound/6QzPMS8mAgn.png?ph=true&h=300&w=458 "(SYN)-1-[(4S,5R)-5-[(S)-2-(TERT.-BUTYLDIPHENYLSILYLOXY)-3-METHYLBUTYL]-2-PHENYL-1,3,2-DIOXABOROLAN-4-YL]-ETHANONE;MAJOR-DIASTEREOMER")
| SpectraBase Compound ID | 6QzPMS8mAgn |
|---|---|
| InChI | InChI=1S/C31H39BO4Si/c1-23(2)28(22-29-30(24(3)33)35-32(34-29)25-16-10-7-11-17-25)36-37(31(4,5)6,26-18-12-8-13-19-26)27-20-14-9-15-21-27/h7-21,23,28-30H,22H2,1-6H3/t28-,29+,30+/m0/s1 |
| InChIKey | HMVVBYZISLNQLT-FRXPANAUSA-N |
| Mol Weight | 514.5 g/mol |
| Molecular Formula | C31H39BO4Si |
| Exact Mass | 514.271066 g/mol |
| Enantiomer InChIKey | HMVVBYZISLNQLT-NGDRWEMDSA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
(1R,3AS,4R,5R,6AS)-5-[[TERT.-BUTYL-(DIPHENYL)-SILYL]-OXY]-1,4-DIMETHYLHEXAHYDROPENTALEN-2(1H)-ONE
(3AS,4R,5R,6AR)-4-ALLYL-5-[(TERT.-BUTYL-(DIPHENYL)-SILYL]-OXY]-HEXAHYDROPENTALEN-2(1H)-ONE
[[(1R,2R,3AR,4S,6AS)-1-ALLYL-4-METHYL-1,2,3,3A,4,6A-HEXAHYDROPENTALEN-2-YL]-OXY]-(TERT.-BUTYL)-DIPHENYLSILANE
5-[(t-Butyldiphenylsilyl)oxy]-1-ethynyl-2-[(triethylsilyl)oxy]-octahydropentalene
(1S,2R,4R,6S)-1-Allyl-2-(tert-butyldimethylsilyloxy)-4-(tert-butyldiphenylsilyloxy)-6-trimethylsilyloxycyclohexanol
(1S,2R,4R,6R)-1-Allyl-2-(tert-butyldimethylsilyloxy)-4-(tert-butyldiphenylsilyloxy)-6-trimethylsilyloxycyclohexanol
METHYL-4-O-BENZOYL-2-O-TERT.-BUTYLDIPHENYLSILYL-3,6-DIDEOXY-ALPHA-D-ARABINO-HEXOPYRANOSIDE
(5R)-5-[tert-butyl(diphenyl)silyl]oxy-5-[(1S,2R)-2-[(E)-2-[(4R,5S)-2,2-dimethyl-5-[(Z)-oct-2-enyl]-1,3-dioxolan-4-yl]ethenyl]cyclopropyl]pentanoic acid methyl ester
(1'E,6'Z)-(1S,2R,3'S,4'S,1''R)-1-(5'-tert-Butyldimethylsilyloxy-1'-tert-butyldiphenylsiloxypentyl)-2-(3',4'-dihydroxy-3',4'-O-isopropylideneundec-1',6'-dienyl)cyclopropane
| Title | Journal or Book | Year |
|---|---|---|
| Stereocontrolled Synthesis of 1,3,5‐Triols by an Iteration of Asymmetric Dihydroxylation and Deoxygenation | European Journal of Organic Chemistry | 2010 |