(1R,3AS,4R,5R,6AS)-5-[[TERT.-BUTYL-(DIPHENYL)-SILYL]-OXY]-1,4-DIMETHYLHEXAHYDROPENTALEN-2(1H)-ONE
Compound with spectra: 1 NMR
![(1R,3AS,4R,5R,6AS)-5-[[TERT.-BUTYL-(DIPHENYL)-SILYL]-OXY]-1,4-DIMETHYLHEXAHYDROPENTALEN-2(1H)-ONE](/api/compound/F8YeKWueulL.png?ph=true&h=300&w=458 "(1R,3AS,4R,5R,6AS)-5-[[TERT.-BUTYL-(DIPHENYL)-SILYL]-OXY]-1,4-DIMETHYLHEXAHYDROPENTALEN-2(1H)-ONE")
| SpectraBase Compound ID | F8YeKWueulL |
|---|---|
| InChI | InChI=1S/C26H34O2Si/c1-18-23-17-25(19(2)22(23)16-24(18)27)28-29(26(3,4)5,20-12-8-6-9-13-20)21-14-10-7-11-15-21/h6-15,18-19,22-23,25H,16-17H2,1-5H3/t18-,19-,22-,23-,25-/m1/s1 |
| InChIKey | LSPPJWFKRJZSCR-PCXUCGPOSA-N |
| Mol Weight | 406.6 g/mol |
| Molecular Formula | C26H34O2Si |
| Exact Mass | 406.232807 g/mol |
| Enantiomer InChIKey | LSPPJWFKRJZSCR-DYJOPPPLSA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
(1S,3AR,5R,6R,6AS)-5-[[TERT.-BUTYL-(DIPHENYL)-SILYL]-OXY]-1,6-DIMETHYLHEXAHYDROPENTALEN-2(1H)-ONE
(3AS,4R,5R,6AR)-4-ALLYL-5-[(TERT.-BUTYL-(DIPHENYL)-SILYL]-OXY]-HEXAHYDROPENTALEN-2(1H)-ONE
[[(1R,2R,3AR,4S,6AS)-1-ALLYL-4-METHYL-1,2,3,3A,4,6A-HEXAHYDROPENTALEN-2-YL]-OXY]-(TERT.-BUTYL)-DIPHENYLSILANE
(SYN)-1-[(4S,5R)-5-[(S)-2-(TERT.-BUTYLDIPHENYLSILYLOXY)-3-METHYLBUTYL]-2-PHENYL-1,3,2-DIOXABOROLAN-4-YL]-ETHANONE;MAJOR-DIASTEREOMER
(ANTI)-1-[(4R,5S)-5-[(S)-2-(TERT.-BUTYLDIPHENYLSILYLOXY)-3-METHYLBUTYL]-2-PHENYL-1,3,2-DIOXABOROLAN-4-YL]-ETHANONE;MAJOR-DIASTEREOMER
(3AR,5R,6R,6AS)-6-ALLYL-5-[[TERT.-BUTYL-(DIPHENYL)-SILYL]-OXY]-1,3A,4,5,6,6A-HEXAHYDROPENTALEN-1-OL
[(1R,2S,3S)-3-TERT.-BUTYLDIPHENYLSILYLOXY-2-[(4S)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YL]:CYCLOBUTYL]-METHANOL
(5R)-5-[tert-butyl(diphenyl)silyl]oxy-5-[(1S,2R)-2-[(E)-2-[(4R,5S)-2,2-dimethyl-5-[(Z)-oct-2-enyl]-1,3-dioxolan-4-yl]ethenyl]cyclopropyl]pentanoic acid methyl ester
(1'E,6'Z)-(1S,2R,3'S,4'S,1''R)-1-(5'-tert-Butyldimethylsilyloxy-1'-tert-butyldiphenylsiloxypentyl)-2-(3',4'-dihydroxy-3',4'-O-isopropylideneundec-1',6'-dienyl)cyclopropane
(5R)-5-[tert-butyl(diphenyl)silyl]oxy-5-[(1S,2R)-2-[(E)-2-[(4R,5S)-2,2-dimethyl-5-[(Z)-oct-2-enyl]-1,3-dioxolan-4-yl]ethenyl]cyclopropyl]-1-pentanol
| Title | Journal or Book | Year |
|---|---|---|
| Doing it Twice: Asymmetric Deprotonation/Alkylation of Weiss Diketone Derivatives as Key Steps in the Functionalization of Bicyclo[3.3.0]octanes | European Journal of Organic Chemistry | 2012 |