Spectra for:
Patrick Walleser, Reinhard Brückner
Compound 1 5A ETHYL-(4R,5R,E)-4,5-DIHYDROXYOCT-2-ENOATE
Compound 3 5A (R,E)-6-(BENZYLOXYMETHOXY)-NON-3-EN-2-ONE
Compound 12 B ETHYL-(2E,4E)-6-METHYLHEPTA-2,4-DIENOATE
Compound 12A ETHYL-(2E,4E)-OCTA-2,4-DIENOATE
Compound 13A (2E,4E)-N-METHOXY-N-METHYLOCTA-2,4-DIENAMIDE
Compound 13B (2E,4E)-N-METHOXY-N,6-DIMETHYLHEPTA-2,4-DIENAMIDE
Compound 14A (3E,5E)-NONA-3,5-DIEN-2-ONE
Compound 14B (3E,5E)-7-METHYLOCTA-3,5-DIEN-2-ONE
Compound 15B ETHYL-(4R,5R,E)-4,5-DIHYDROXY-6-METHYLHEPT-2-ENOATE
Compound 16A (4R,5R,E)-4,5-DIHYDROXY-N-METHOXY-N-METHYLOCT-2-ENAMIDE
Compound 16B (4R,5R,E)-4,5-DIHYDROXY-N-METHOXY-N,6-DIMETHYLHEPT-2-ENAMIDE
Compound 17A (5R,6R,E)-5,6-DIHYDROXYNON-3-EN-2-ONE
Compound 17B (5R,6R,E)-5,6-DIHYDROXY-7-METHYLOCT-3-EN-2-ONE
Compound 18 (E)-4-[(4R,5R)-2-PHENYL-5-PROPYL-1,3,2-DIOXABOROLAN-4-YL]-BUT-3-EN-2-ONE
![(E)-4-[(4R,5R)-2-PHENYL-5-PROPYL-1,3,2-DIOXABOROLAN-4-YL]-BUT-3-EN-2-ONE](/api/compound/85AJXCgH5Nk.png?h=300&w=458 "(E)-4-[(4R,5R)-2-PHENYL-5-PROPYL-1,3,2-DIOXABOROLAN-4-YL]-BUT-3-EN-2-ONE")
Compound 23A ETHYL-(E)-3-[(4R,5R)-2-OXO-5-PROPYL-1,3-DIOXOLAN-4-YL]-ACRYLATE
![ETHYL-(E)-3-[(4R,5R)-2-OXO-5-PROPYL-1,3-DIOXOLAN-4-YL]-ACRYLATE](/api/compound/HPEBXfMXIvq.png?h=300&w=458 "ETHYL-(E)-3-[(4R,5R)-2-OXO-5-PROPYL-1,3-DIOXOLAN-4-YL]-ACRYLATE")
Compound 23B ETHYL-(E)-3-[(4R,5R)-5-ISOPROPYL-2-OXO-1,3-DIOXOLAN-4-YL]-ACRYLATE
![ETHYL-(E)-3-[(4R,5R)-5-ISOPROPYL-2-OXO-1,3-DIOXOLAN-4-YL]-ACRYLATE](/api/compound/GwAhxIKTdWJ.png?h=300&w=458 "ETHYL-(E)-3-[(4R,5R)-5-ISOPROPYL-2-OXO-1,3-DIOXOLAN-4-YL]-ACRYLATE")
Compound 24A (E)-3-[(4R,5R)-2-OXO-5-PROPYL-1,3-DIOXOLAN-4-YL]-N-METHOXY-N-METHYL-ACRYLAMIDE
![(E)-3-[(4R,5R)-2-OXO-5-PROPYL-1,3-DIOXOLAN-4-YL]-N-METHOXY-N-METHYL-ACRYLAMIDE](/api/compound/HcAk3u2ui1.png?h=300&w=458 "(E)-3-[(4R,5R)-2-OXO-5-PROPYL-1,3-DIOXOLAN-4-YL]-N-METHOXY-N-METHYL-ACRYLAMIDE")
Compound 24B (E)-3-[(4R,5R)-5-ISOPROPYL-2-OXO-1,3-DIOXOLAN-4-YL]-N-METHOXY-N-METHYL-ACRYLAMIDE
![(E)-3-[(4R,5R)-5-ISOPROPYL-2-OXO-1,3-DIOXOLAN-4-YL]-N-METHOXY-N-METHYL-ACRYLAMIDE](/api/compound/5gfgDBp4zOs.png?h=300&w=458 "(E)-3-[(4R,5R)-5-ISOPROPYL-2-OXO-1,3-DIOXOLAN-4-YL]-N-METHOXY-N-METHYL-ACRYLAMIDE")
Compound 25A (4R,5R)-4-[(E)-3-OXOBUT-1-ENYL]-5-PROPYL-1,3-DIOXOLAN-2-ONE
![(4R,5R)-4-[(E)-3-OXOBUT-1-ENYL]-5-PROPYL-1,3-DIOXOLAN-2-ONE](/api/compound/Kt43xx2cQYE.png?h=300&w=458 "(4R,5R)-4-[(E)-3-OXOBUT-1-ENYL]-5-PROPYL-1,3-DIOXOLAN-2-ONE")
Compound 25B (4R,5R)-4-ISOPROPYL-5-[(E)-3-OXOBUT-1-ENYL]-1,3-DIOXOLAN-2-ONE
![(4R,5R)-4-ISOPROPYL-5-[(E)-3-OXOBUT-1-ENYL]-1,3-DIOXOLAN-2-ONE](/api/compound/KpgdiEAsOAm.png?h=300&w=458 "(4R,5R)-4-ISOPROPYL-5-[(E)-3-OXOBUT-1-ENYL]-1,3-DIOXOLAN-2-ONE")
Compound 26A ETHYL-(R,E)-5-HYDROXYOCT-2-ENOATE;MAJOR-ISOMER
Compound 26B ETHYL-(S,E)-5-HYDROXY-6-METHYLHEPT-2-ENOATE;MAJOR-ISOMER
Compound 27A (R,E)-5-HYDROXY-N-METHOXY-N-METHYLOCT-2-ENAMIDE;MAJOR-ISOMER
Compound 27B (S,E)-5-HYDROXY-N-METHOXY-N,6-DIMETHYLHEPT-2-ENAMIDE;MAJOR-ISOMER
Compound 28A (R,E)-6-HYDROXYNON-3-EN-2-ONE;MAJOR-ISOMER
Compound 28B (S,E)-6-HYDROXY-7-METHYLOCT-3-EN-2-ONE;MAJOR-ISOMER
Compound 29A ETHYL-(R,E)-5-(BENZYLOXYMETHOXY)-OCT-2-ENOATE
Compound 29B ETHYL-(S,E)-5-(BENZYLOXYMETHOXY)-6-METHYLHEPT-2-ENOATE
Compound 30A ETHYL-(R,E)-5-(4-METHOXYBENZYLOXY)-OCT-2-ENOATE
Compound 30B ETHYL-(S,E)-5-(4-METHOXYBENZYLOXY)-6-METHYLHEPT-2-ENOATE
Compound 31A ETHYL-(R,E)-5-(TERT.-BUTYLDIPHENYLSILYLOXY)-OCT-2-ENOATE
Compound 31B ETHYL-(R,E)-5-(TERT.-BUTYLDIPHENYLSILYLOXY)-6-METHYLHEPT-2-ENOATE
Compound 32A (R,E)-5-(BENZYLOXYMETHOXY)-N-METHOXY-N-METHYLOCT-2-ENAMIDE
Compound 32B (S,E)-5-(BENZYLOXYMETHOXY)-N-METHOXY-N,6-DIMETHYLHEPT-2-ENAMIDE
Compound 33A (R,E)-N-METHOXY-5-(4-METHOXYBENZYLOXY)-N-METHYLOCT-2-ENAMIDE
Compound 33B (R,E)-N-METHOXY-5-(4-METHOXYBENZYLOXY)-N,6-DIMETHYLHEPT-2-ENAMIDE
Compound 34A (R,E)-5-(TERT.-BUTYLDIPHENYLSILYLOXY)-N-METHOXY-N-METHYLOCT-2-ENAMIDE
Compound 34B (S,E)-5-(TERT.-BUTYLDIPHENYLSILYLOXY)-N-METHOXY-N,6-DIMETHYLHEPT-2-ENAMIDE
Compound 35B (S,E)-6-(BENZYLOXYMETHOXY)-7-METHYLOCT-3-EN-2-ONE
Compound 36A (R,E)-6-(4-METHOXYBENZYLOXY)-NON-3-EN-2-ONE
Compound 36B (S,E)-6-(4-METHOXYBENZYLOXY)-7-METHYLOCT-3-EN-2-ONE
Compound 37A (R,E)-6-(TERT.-BUTYLDIPHENYLSILYLOXY)-NON-3-EN-2-ONE
Compound 37B (R,E)-6-(TERT.-BUTYLDIPHENYLSILYLOXY)-7-METHYLOCT-3-EN-2-ONE
Compound 38A (ANTI)-1-[(4R,5S)-5-[(R)-2-(BENZYLOXYMETHOXY)-PENTYL]-2-PHENYL-1,3,2-DIOXABOROLAN-4-YL]-ETHANONE;MAJOR-DIASTEREOMER
![(ANTI)-1-[(4R,5S)-5-[(R)-2-(BENZYLOXYMETHOXY)-PENTYL]-2-PHENYL-1,3,2-DIOXABOROLAN-4-YL]-ETHANONE;MAJOR-DIASTEREOMER](/api/compound/23jP13Tshbv.png?h=300&w=458 "(ANTI)-1-[(4R,5S)-5-[(R)-2-(BENZYLOXYMETHOXY)-PENTYL]-2-PHENYL-1,3,2-DIOXABOROLAN-4-YL]-ETHANONE;MAJOR-DIASTEREOMER")
Compound 38A (SYN)-1-[(4S,5R)-5-[(R)-2-(BENZYLOXYMETHOXY)-PENTYL]-2-PHENYL-1,3,2-DIOXABOROLAN-4-YL]-ETHANONE;MAJOR-DIASTEREOMER
![(SYN)-1-[(4S,5R)-5-[(R)-2-(BENZYLOXYMETHOXY)-PENTYL]-2-PHENYL-1,3,2-DIOXABOROLAN-4-YL]-ETHANONE;MAJOR-DIASTEREOMER](/api/compound/BoiqLTJ0rVS.png?h=300&w=458 "(SYN)-1-[(4S,5R)-5-[(R)-2-(BENZYLOXYMETHOXY)-PENTYL]-2-PHENYL-1,3,2-DIOXABOROLAN-4-YL]-ETHANONE;MAJOR-DIASTEREOMER")
Compound 38B (ANTI)-1-[(4R,5S)-5-[(S)-2-(BENZYLOXYMETHOXY)-3-METHYLBUTYL]-2-PHENYL-1,3,2-DIOXABOROLAN-4-YL]-ETHANONE;MAJOR-DIASTEREOMER
![(ANTI)-1-[(4R,5S)-5-[(S)-2-(BENZYLOXYMETHOXY)-3-METHYLBUTYL]-2-PHENYL-1,3,2-DIOXABOROLAN-4-YL]-ETHANONE;MAJOR-DIASTEREOMER](/api/compound/IbrotJa26nX.png?h=300&w=458 "(ANTI)-1-[(4R,5S)-5-[(S)-2-(BENZYLOXYMETHOXY)-3-METHYLBUTYL]-2-PHENYL-1,3,2-DIOXABOROLAN-4-YL]-ETHANONE;MAJOR-DIASTEREOMER")
Compound 38B (SYN)-1-[(4S,5R)-5-[(S)-2-(BENZYLOXYMETHOXY)-3-METHYLBUTYL]-2-PHENYL-1,3,2-DIOXABOROLAN-4-YL]-ETHANONE;MAJOR-DIASTEREOMER
![(SYN)-1-[(4S,5R)-5-[(S)-2-(BENZYLOXYMETHOXY)-3-METHYLBUTYL]-2-PHENYL-1,3,2-DIOXABOROLAN-4-YL]-ETHANONE;MAJOR-DIASTEREOMER](/api/compound/BXjZZZlvVEw.png?h=300&w=458 "(SYN)-1-[(4S,5R)-5-[(S)-2-(BENZYLOXYMETHOXY)-3-METHYLBUTYL]-2-PHENYL-1,3,2-DIOXABOROLAN-4-YL]-ETHANONE;MAJOR-DIASTEREOMER")
Compound 39A (ANTI)-1-[(4R,5S)-5-[(R)-2-(4-METHOXYBENZYLOXY)-PENTYL]-2-PHENYL-1,3,2-DIOXABOROLAN-4-YL]-ETHANONE;MAJOR-DIASTEREOMER
![(ANTI)-1-[(4R,5S)-5-[(R)-2-(4-METHOXYBENZYLOXY)-PENTYL]-2-PHENYL-1,3,2-DIOXABOROLAN-4-YL]-ETHANONE;MAJOR-DIASTEREOMER](/api/compound/GQH8njCmrKX.png?h=300&w=458 "(ANTI)-1-[(4R,5S)-5-[(R)-2-(4-METHOXYBENZYLOXY)-PENTYL]-2-PHENYL-1,3,2-DIOXABOROLAN-4-YL]-ETHANONE;MAJOR-DIASTEREOMER")
Compound 39A (SYN)-1-[(4S,5R)-5-[(R)-2-(4-METHOXYBENZYLOXY)-PENTYL]-2-PHENYL-1,3,2-DIOXABOROLAN-4-YL]-ETHANONE;MAJOR-DIASTEREOMER
![(SYN)-1-[(4S,5R)-5-[(R)-2-(4-METHOXYBENZYLOXY)-PENTYL]-2-PHENYL-1,3,2-DIOXABOROLAN-4-YL]-ETHANONE;MAJOR-DIASTEREOMER](/api/compound/2q58bN5sa0a.png?h=300&w=458 "(SYN)-1-[(4S,5R)-5-[(R)-2-(4-METHOXYBENZYLOXY)-PENTYL]-2-PHENYL-1,3,2-DIOXABOROLAN-4-YL]-ETHANONE;MAJOR-DIASTEREOMER")
Compound 39B (ANTI)-1-[(4R,5S)-5-[(S)-2-(4-METHOXYBENZYLOXY)-3-METHYLBUTYL]-2-PHENYL-1,3,2-DIOXABOROLAN-4-YL]-ETHANONE;MAJOR-DIASTEREOMER
![(ANTI)-1-[(4R,5S)-5-[(S)-2-(4-METHOXYBENZYLOXY)-3-METHYLBUTYL]-2-PHENYL-1,3,2-DIOXABOROLAN-4-YL]-ETHANONE;MAJOR-DIASTEREOMER](/api/compound/JeKBfBSTSmQ.png?h=300&w=458 "(ANTI)-1-[(4R,5S)-5-[(S)-2-(4-METHOXYBENZYLOXY)-3-METHYLBUTYL]-2-PHENYL-1,3,2-DIOXABOROLAN-4-YL]-ETHANONE;MAJOR-DIASTEREOMER")
Compound 39B (SYN)-1-[(4S,5R)-5-[(S)-2-(4-METHOXYBENZYLOXY)-3-METHYLBUTYL]-2-PHENYL-1,3,2-DIOXABOROLAN-4-YL]-ETHANONE;MAJOR-DIASTEREOMER
![(SYN)-1-[(4S,5R)-5-[(S)-2-(4-METHOXYBENZYLOXY)-3-METHYLBUTYL]-2-PHENYL-1,3,2-DIOXABOROLAN-4-YL]-ETHANONE;MAJOR-DIASTEREOMER](/api/compound/FzmTaEN5a1H.png?h=300&w=458 "(SYN)-1-[(4S,5R)-5-[(S)-2-(4-METHOXYBENZYLOXY)-3-METHYLBUTYL]-2-PHENYL-1,3,2-DIOXABOROLAN-4-YL]-ETHANONE;MAJOR-DIASTEREOMER")
Compound 40B (SYN)-1-[(4S,5R)-5-[(S)-2-(TERT.-BUTYLDIPHENYLSILYLOXY)-3-METHYLBUTYL]-2-PHENYL-1,3,2-DIOXABOROLAN-4-YL]-ETHANONE;MAJOR-DIASTEREOMER
![(SYN)-1-[(4S,5R)-5-[(S)-2-(TERT.-BUTYLDIPHENYLSILYLOXY)-3-METHYLBUTYL]-2-PHENYL-1,3,2-DIOXABOROLAN-4-YL]-ETHANONE;MAJOR-DIASTEREOMER](/api/compound/6QzPMS8mAgn.png?h=300&w=458 "(SYN)-1-[(4S,5R)-5-[(S)-2-(TERT.-BUTYLDIPHENYLSILYLOXY)-3-METHYLBUTYL]-2-PHENYL-1,3,2-DIOXABOROLAN-4-YL]-ETHANONE;MAJOR-DIASTEREOMER")
Compound 40B (ANTI)-1-[(4R,5S)-5-[(S)-2-(TERT.-BUTYLDIPHENYLSILYLOXY)-3-METHYLBUTYL]-2-PHENYL-1,3,2-DIOXABOROLAN-4-YL]-ETHANONE;MAJOR-DIASTEREOMER
![(ANTI)-1-[(4R,5S)-5-[(S)-2-(TERT.-BUTYLDIPHENYLSILYLOXY)-3-METHYLBUTYL]-2-PHENYL-1,3,2-DIOXABOROLAN-4-YL]-ETHANONE;MAJOR-DIASTEREOMER](/api/compound/FWKW68UeEGj.png?h=300&w=458 "(ANTI)-1-[(4R,5S)-5-[(S)-2-(TERT.-BUTYLDIPHENYLSILYLOXY)-3-METHYLBUTYL]-2-PHENYL-1,3,2-DIOXABOROLAN-4-YL]-ETHANONE;MAJOR-DIASTEREOMER")
Compound 41 (SYN)-(4R,6R)-4-HYDROXY-6-(4-METHOXYBENZYLOXY)-NONAN-2-ONE;MAJOR-DIASTEREOMER
Compound 42 (ANTI)-(4S,6S)-6-(TERT.-BUTYLDIPHENYLSILYLOXY)-4-HYDROXY-7-METHYLOCTAN-2-ONE;MAJOR-DIASTEREOMER
Compound 43 (SYN,SYN)-(4S,6S)-2-ETHYL-4-[(R)-2-(4-METHOXYBENZYLOXY)-PENTYL]-6-METHYL-1,3,2-DIOXABORINANE;MAJOR-DIASTEREOMER
![(SYN,SYN)-(4S,6S)-2-ETHYL-4-[(R)-2-(4-METHOXYBENZYLOXY)-PENTYL]-6-METHYL-1,3,2-DIOXABORINANE;MAJOR-DIASTEREOMER](/api/compound/EZZnKrlTro9.png?h=300&w=458 "(SYN,SYN)-(4S,6S)-2-ETHYL-4-[(R)-2-(4-METHOXYBENZYLOXY)-PENTYL]-6-METHYL-1,3,2-DIOXABORINANE;MAJOR-DIASTEREOMER")
Compound 44 (SYN,ANTI)-TERT.-BUTYL-[(S)-1-(4R,6R)-2-ETHYL-6-METHYL-1,3,2-DIOXABORINAN-4-YL]-3-METHYLBUTAN-2-YL-OXY]-DIPHENYLSILANE;MAJOR-DIASTEREOMER
![(SYN,ANTI)-TERT.-BUTYL-[(S)-1-(4R,6R)-2-ETHYL-6-METHYL-1,3,2-DIOXABORINAN-4-YL]-3-METHYLBUTAN-2-YL-OXY]-DIPHENYLSILANE;MAJOR-DIASTEREOMER](/api/compound/5ocU9jjDERM.png?h=300&w=458 "(SYN,ANTI)-TERT.-BUTYL-[(S)-1-(4R,6R)-2-ETHYL-6-METHYL-1,3,2-DIOXABORINAN-4-YL]-3-METHYLBUTAN-2-YL-OXY]-DIPHENYLSILANE;MAJOR-DIASTEREOMER")
Compound 45 (ANTI,SYN)-(2R,4S,6R)-2-HYDROXY-6-(4-METHOXYBENZYLOXY)-NONAN-4-YL-ISOBUTYRATE;MAJOR-DIASTEREOMER
Compound 46 (ANTI,ANTI)-(2S,4R,6S)-6-(TERT.-BUTYLDIPHENYLSILYLOXY)-2-HYDROXY-7-METHYLOCTAN-4-YL-ISOBUTYRATE;MAJOR-DIASTEREOMER
Citation
| Citation | EUR.J.ORG.CHEM.,2010,4802(2010) |
|---|---|
| Journal | European Journal of Organic Chemistry |
| Issue | 25 |
| Volume | 2010 |
| Page(s) | 4802-4822 |
| Year | 2010 |
| Author(s) | Patrick Walleser, Reinhard Brückner |
| Publisher | Wiley |
| DOI | 10.1002/ejoc.201000280 |