Spectra for:
Laurent Chabaud, Yannick Landais, Philippe Renaud
Compound 1 0B (1R,2S)-2-[DIMETHYL-(PHENYL)-SILYL]-1-[(R)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YL]-BUT-3-ENYL-BENZOATE
![(1R,2S)-2-[DIMETHYL-(PHENYL)-SILYL]-1-[(R)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YL]-BUT-3-ENYL-BENZOATE](/api/compound/AN6Ub4GBCKJ.png?h=300&w=458 "(1R,2S)-2-[DIMETHYL-(PHENYL)-SILYL]-1-[(R)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YL]-BUT-3-ENYL-BENZOATE")
Compound 3 HYACINTHACINE-A1
Compound 10 A (1R,2S)-2-[DIMETHYL-(PHENYL)-SILYL]-1-[(R)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YL]-BUT-3-ENYL-ACETATE
![(1R,2S)-2-[DIMETHYL-(PHENYL)-SILYL]-1-[(R)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YL]-BUT-3-ENYL-ACETATE](/api/compound/D6TusfeC70R.png?h=300&w=458 "(1R,2S)-2-[DIMETHYL-(PHENYL)-SILYL]-1-[(R)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YL]-BUT-3-ENYL-ACETATE")
Compound 10C (1R,2S)-1-(METHOXYMETHOXY)-1-[(R)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YL]-BUT-3-EN-2-YL-DIMETHYL-(PHENYL)-SILANE
![(1R,2S)-1-(METHOXYMETHOXY)-1-[(R)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YL]-BUT-3-EN-2-YL-DIMETHYL-(PHENYL)-SILANE](/api/compound/8KXxy3DW8IW.png?h=300&w=458 "(1R,2S)-1-(METHOXYMETHOXY)-1-[(R)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YL]-BUT-3-EN-2-YL-DIMETHYL-(PHENYL)-SILANE")
Compound 11A 6-ACETOXY-4-AZIDO-6-[2,2-DIMETHYL-[1,3]-DIOXOLAN-4-YL]-5-[DIMETHYL-(PHENYL)-SILYL]-HEXANOIC-ACID-ETHYLESTER;(SYN)-MAJOR-DIASTEREOMER
![6-ACETOXY-4-AZIDO-6-[2,2-DIMETHYL-[1,3]-DIOXOLAN-4-YL]-5-[DIMETHYL-(PHENYL)-SILYL]-HEXANOIC-ACID-ETHYLESTER;(SYN)-MAJOR-DIASTEREOMER](/api/compound/5Vkkqa6CT3m.png?h=300&w=458 "6-ACETOXY-4-AZIDO-6-[2,2-DIMETHYL-[1,3]-DIOXOLAN-4-YL]-5-[DIMETHYL-(PHENYL)-SILYL]-HEXANOIC-ACID-ETHYLESTER;(SYN)-MAJOR-DIASTEREOMER")
Compound 11A 6-ACETOXY-4-AZIDO-6-[2,2-DIMETHYL-[1,3]-DIOXOLAN-4-YL]-5-[DIMETHYL-(PHENYL)-SILYL]-HEXANOIC-ACID-ETHYLESTER;(ANTI)-MINOR-DIASTEREOMER
![6-ACETOXY-4-AZIDO-6-[2,2-DIMETHYL-[1,3]-DIOXOLAN-4-YL]-5-[DIMETHYL-(PHENYL)-SILYL]-HEXANOIC-ACID-ETHYLESTER;(ANTI)-MINOR-DIASTEREOMER](/api/compound/EVP9sQTwEL5.png?h=300&w=458 "6-ACETOXY-4-AZIDO-6-[2,2-DIMETHYL-[1,3]-DIOXOLAN-4-YL]-5-[DIMETHYL-(PHENYL)-SILYL]-HEXANOIC-ACID-ETHYLESTER;(ANTI)-MINOR-DIASTEREOMER")
Compound 11B (1R,2S)-3-AZIDO-2-[DIMETHYL-(PHENYL)-SILYL]-1-(2,2-DIMETHYL-1,3-DIOXOLAN-4-YL)-6-ETHOXY-6-OXOHEXYL-BENZOATE;(SYN)-MAJOR-DIASTEREOMER
![(1R,2S)-3-AZIDO-2-[DIMETHYL-(PHENYL)-SILYL]-1-(2,2-DIMETHYL-1,3-DIOXOLAN-4-YL)-6-ETHOXY-6-OXOHEXYL-BENZOATE;(SYN)-MAJOR-DIASTEREOMER](/api/compound/CyKM4Q7oaXS.png?h=300&w=458 "(1R,2S)-3-AZIDO-2-[DIMETHYL-(PHENYL)-SILYL]-1-(2,2-DIMETHYL-1,3-DIOXOLAN-4-YL)-6-ETHOXY-6-OXOHEXYL-BENZOATE;(SYN)-MAJOR-DIASTEREOMER")
Compound 12 (1S,2R)-2-[DIMETHYL-(PHENYL)-SILYL]-1-[(R)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YL]-BUT-3-ENYL-ACETATE
![(1S,2R)-2-[DIMETHYL-(PHENYL)-SILYL]-1-[(R)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YL]-BUT-3-ENYL-ACETATE](/api/compound/28XIhe6PX8y.png?h=300&w=458 "(1S,2R)-2-[DIMETHYL-(PHENYL)-SILYL]-1-[(R)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YL]-BUT-3-ENYL-ACETATE")
Compound 13 (5R,6S)-ETHYL-6-ACETOXY-4-AZIDO-5-[DIMETHYL-(PHENYL)-SILYL]-6-[(R)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YL]-HEXANOATE;(SYN)-MAJOR-DIASTEREOMER
![(5R,6S)-ETHYL-6-ACETOXY-4-AZIDO-5-[DIMETHYL-(PHENYL)-SILYL]-6-[(R)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YL]-HEXANOATE;(SYN)-MAJOR-DIASTEREOMER](/api/compound/DKf4QvxF3g4.png?h=300&w=458 "(5R,6S)-ETHYL-6-ACETOXY-4-AZIDO-5-[DIMETHYL-(PHENYL)-SILYL]-6-[(R)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YL]-HEXANOATE;(SYN)-MAJOR-DIASTEREOMER")
Compound 14 (5R,6S)-ETHYL-6-ACETOXY-6-[(4S)-5-AZIDO-2,2-DIMETHYL-1,3-DIOXOLAN-4-YL]-5-[DIMETHYL-(PHENYL)-SILYL]-HEXANOATE
![(5R,6S)-ETHYL-6-ACETOXY-6-[(4S)-5-AZIDO-2,2-DIMETHYL-1,3-DIOXOLAN-4-YL]-5-[DIMETHYL-(PHENYL)-SILYL]-HEXANOATE](/api/compound/HxZHNe5KXhI.png?h=300&w=458 "(5R,6S)-ETHYL-6-ACETOXY-6-[(4S)-5-AZIDO-2,2-DIMETHYL-1,3-DIOXOLAN-4-YL]-5-[DIMETHYL-(PHENYL)-SILYL]-HEXANOATE")
Compound 16 (R)-METHYL-4-AZIDO-4-[[(4S,5R)-5-[(R)-1,2-DIHYDROXYETHYL]-2,2-DIMETHYL-1,3-DIOXOLAN-4-YL]-BUTANOATE
![(R)-METHYL-4-AZIDO-4-[[(4S,5R)-5-[(R)-1,2-DIHYDROXYETHYL]-2,2-DIMETHYL-1,3-DIOXOLAN-4-YL]-BUTANOATE](/api/compound/DpN0TNw3xo2.png?h=300&w=458 "(R)-METHYL-4-AZIDO-4-[[(4S,5R)-5-[(R)-1,2-DIHYDROXYETHYL]-2,2-DIMETHYL-1,3-DIOXOLAN-4-YL]-BUTANOATE")
Compound 17 METHYL-4-AZIDO-4-[5-[2-[[TERT.-BUTYL-(DIMETHYL)-SILYL]-OXY]-1-[(METHYLSULFONYL)-OXY]-ETHYL]-2,2-DIMETHYL-1,3-DIOXOLAN-4-YL]-BUTANOATE
![METHYL-4-AZIDO-4-[5-[2-[[TERT.-BUTYL-(DIMETHYL)-SILYL]-OXY]-1-[(METHYLSULFONYL)-OXY]-ETHYL]-2,2-DIMETHYL-1,3-DIOXOLAN-4-YL]-BUTANOATE](/api/compound/8N72IdcTeF8.png?h=300&w=458 "METHYL-4-AZIDO-4-[5-[2-[[TERT.-BUTYL-(DIMETHYL)-SILYL]-OXY]-1-[(METHYLSULFONYL)-OXY]-ETHYL]-2,2-DIMETHYL-1,3-DIOXOLAN-4-YL]-BUTANOATE")
Compound 18 METHYL-3-[(3AS,4R,6S,6AR)-6-[(TERT.-BUTYLDIMETHYLSILYLOXY)-METHYL]-2,2-DIMETHYL-TETRAHYDRO-3AH-[1,3]-DIOXOLO-[4,5-C]-PYRROL-4-YL]-PROPANOATE
![METHYL-3-[(3AS,4R,6S,6AR)-6-[(TERT.-BUTYLDIMETHYLSILYLOXY)-METHYL]-2,2-DIMETHYL-TETRAHYDRO-3AH-[1,3]-DIOXOLO-[4,5-C]-PYRROL-4-YL]-PROPANOATE](/api/compound/7eAkIsZZnLk.png?h=300&w=458 "METHYL-3-[(3AS,4R,6S,6AR)-6-[(TERT.-BUTYLDIMETHYLSILYLOXY)-METHYL]-2,2-DIMETHYL-TETRAHYDRO-3AH-[1,3]-DIOXOLO-[4,5-C]-PYRROL-4-YL]-PROPANOATE")
Compound 19 KYYUIXQVYASRTH-LJISPDSOSA-N
Compound 20 (3AR,4S,8AR,8BS)-4-[(TERT.-BUTYLDIMETHYLSILYLOXY)-METHYL]-2,2-DIMETHYL-HEXAHYDRO-3AH-[1,3]-DIOXOLO-[4,5-A]-PYRROLIZINE
![(3AR,4S,8AR,8BS)-4-[(TERT.-BUTYLDIMETHYLSILYLOXY)-METHYL]-2,2-DIMETHYL-HEXAHYDRO-3AH-[1,3]-DIOXOLO-[4,5-A]-PYRROLIZINE](/api/compound/AzkvKBQ6ule.png?h=300&w=458 "(3AR,4S,8AR,8BS)-4-[(TERT.-BUTYLDIMETHYLSILYLOXY)-METHYL]-2,2-DIMETHYL-HEXAHYDRO-3AH-[1,3]-DIOXOLO-[4,5-A]-PYRROLIZINE")
Compound 21 3-EPI-HYACINTHACINE-A1
Compound 22 (R)-METHYL-4-AZIDO-4-[(4S,5S)-2,2-DIMETHYL-5-[(S)-OXIRAN-2-YL]-1,3-DIOXOLAN-4-YL]-BUTANOATE
![(R)-METHYL-4-AZIDO-4-[(4S,5S)-2,2-DIMETHYL-5-[(S)-OXIRAN-2-YL]-1,3-DIOXOLAN-4-YL]-BUTANOATE](/api/compound/Hm0zxQUcx95.png?h=300&w=458 "(R)-METHYL-4-AZIDO-4-[(4S,5S)-2,2-DIMETHYL-5-[(S)-OXIRAN-2-YL]-1,3-DIOXOLAN-4-YL]-BUTANOATE")
Compound 23 (3AR,4R,8AR,8BS)-4-(HYDROXYMETHYL)-2,2-DIMETHYL-TETRAHYDRO-7H-[1,3]-DIOXOLO-[4,5-A]-PYRROLIZIN-6(8BH)-ONE
![(3AR,4R,8AR,8BS)-4-(HYDROXYMETHYL)-2,2-DIMETHYL-TETRAHYDRO-7H-[1,3]-DIOXOLO-[4,5-A]-PYRROLIZIN-6(8BH)-ONE](/api/compound/A6TBDzGjLqf.png?h=300&w=458 "(3AR,4R,8AR,8BS)-4-(HYDROXYMETHYL)-2,2-DIMETHYL-TETRAHYDRO-7H-[1,3]-DIOXOLO-[4,5-A]-PYRROLIZIN-6(8BH)-ONE")
#11C;(4S,5R,6S)-ETHYL-4-AZIDO-6-(METHOXYMETHOXY)-5-[DIMETHYL-(PHENYL)-SILYL]-6-[(R)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YL)-HEXANOATE;(SYN)-MAJOR+(ANTI)-MINOR
![#11C;(4S,5R,6S)-ETHYL-4-AZIDO-6-(METHOXYMETHOXY)-5-[DIMETHYL-(PHENYL)-SILYL]-6-[(R)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YL)-HEXANOATE;(SYN)-MAJOR+(ANTI)-MINOR](/api/compound/4BCYVUzi5zs.png?h=300&w=458 "#11C;(4S,5R,6S)-ETHYL-4-AZIDO-6-(METHOXYMETHOXY)-5-[DIMETHYL-(PHENYL)-SILYL]-6-[(R)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YL)-HEXANOATE;(SYN)-MAJOR+(ANTI)-MINOR")
(4R,5S,6S)-ETHYL-4-AZIDO-5,6-DIACETOXY-6-[(R)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YL]-HEXANOATE
![(4R,5S,6S)-ETHYL-4-AZIDO-5,6-DIACETOXY-6-[(R)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YL]-HEXANOATE](/api/compound/INgVG55CnBx.png?h=300&w=458 "(4R,5S,6S)-ETHYL-4-AZIDO-5,6-DIACETOXY-6-[(R)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YL]-HEXANOATE")
NO-NAME
Citation
| Citation | ORG.LETTERS,7,2587(2005) |
|---|---|
| Journal | Organic Letters |
| Issue | 13 |
| Volume | 7 |
| Page(s) | 2587-2590 |
| Year | 2005 |
| Author(s) | Laurent Chabaud, Yannick Landais, Philippe Renaud |
| Publisher | American Chemical Society (ACS) |
| DOI | 10.1021/ol050713s |