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(5R,6S)-ETHYL-6-ACETOXY-4-AZIDO-5-[DIMETHYL-(PHENYL)-SILYL]-6-[(R)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YL]-HEXANOATE;(SYN)-MAJOR-DIASTEREOMER

Compound with spectra: 1 NMR

(5R,6S)-ETHYL-6-ACETOXY-4-AZIDO-5-[DIMETHYL-(PHENYL)-SILYL]-6-[(R)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YL]-HEXANOATE;(SYN)-MAJOR-DIASTEREOMER
SpectraBase Compound ID DKf4QvxF3g4
InChI InChI=1S/C23H35N3O6Si/c1-7-29-20(28)14-13-18(25-26-24)22(33(5,6)17-11-9-8-10-12-17)21(31-16(2)27)19-15-30-23(3,4)32-19/h8-12,18-19,21-22H,7,13-15H2,1-6H3/t18?,19-,21+,22+/m1/s1
InChIKey FDHRRAHLFBSVQJ-YRAIZVJHSA-N
Mol Weight 477.6 g/mol
Molecular Formula C23H35N3O6Si
Exact Mass 477.229512 g/mol
Enantiomer InChIKey FDHRRAHLFBSVQJ-SPPJFZGQSA-N

View Spectrum of (5R,6S)-ETHYL-6-ACETOXY-4-AZIDO-5-[DIMETHYL-(PHENYL)-SILYL]-6-[(R)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YL]-HEXANOATE;(SYN)-MAJOR-DIASTEREOMER

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
6-ACETOXY-4-AZIDO-6-[2,2-DIMETHYL-[1,3]-DIOXOLAN-4-YL]-5-[DIMETHYL-(PHENYL)-SILYL]-HEXANOIC-ACID-ETHYLESTER;(SYN)-MAJOR-DIASTEREOMER
6-ACETOXY-4-AZIDO-6-[2,2-DIMETHYL-[1,3]-DIOXOLAN-4-YL]-5-[DIMETHYL-(PHENYL)-SILYL]-HEXANOIC-ACID-ETHYLESTER;(ANTI)-MINOR-DIASTEREOMER
METHYL{METHYL-3,4-DI-O-ACETYL-2-O-[METHYL(2,3,4-TRI-O-ACETYL-BETA-D-MANNOPYRANOSYL)URONATE]-ALPHA-D-MANNOPYRANOSIDE}URONATE
LIPEDOSIDE-B-VI;3-(6,7-DIHYDROXY-3,7-DIMETHYLOCT-1-ENYL)-(3-O-ALPHA-L-RHAMNOPYRANOSYL)-(4-O-TRANS-PARA-COUMAROYL)-BETA-D-GLUCOPYRANOSIDE
TURRILLIOSIDE-A;BETA-(3,4-DIHYDROXYPHENYL)-ETHYL-4-O-E-CAFFEOYL-O-[BETA-GLUCOPYRANOSYL-(1->4)-ALPHA-RHAMNOPYRANOSYL-(1->6)]-BETA-GLUCOPYRANOSIDE
3-cyclopropyl-6-methyl-1-phenyl-4-(trifluoromethyl)-1H-pyrazolo[3,4-b]pyridine
.beta.-D-Glucopyranoside, 2-[(acetyloxy)methyl]phenyl, 2,3,4-triacetate 6-[3-[4-(acetyloxy)phenyl]-2-propenoate]
(4aR,5aS,9R,10aS,11R,11aR,3'R)11-(p-Bromobenzoyloxy)-9-[(E)-3',4'-di(p-bromobenzoyloxy)-1'-butenyl]-4,4a,5a,6,9,10a,11,11a-decahydrooxepino[2',3':5,6]pyrano[3,2-d]-1.3-dioxin
(4aR,5aS,9R,10aS,11R,11aR,3'S)11-(p-Bromobenzoyloxy)-9-[(E)-3',4'-di(p-bromobenzoyloxy)-1'-butenyl]-4,4a,5a,6,9,10a,11,11a-decahydrooxepino[2',3':5,6]pyrano[3,2-d]-1.3-dioxin
METHYL{METHYL-2,4-DI-O-ACETYL-3-O-[METHYL(2,3,4-TRI-O-ACETYL-BETA-D-MANNOPYRANOSYL)URONATE]-ALPHA-D-MANNOPYRANOSIDE}URONATE
Title Journal or Book Year
Total Synthesis of Hyacinthacine A1 and 3-epi-Hyacinthacine A1 Organic Letters 2005
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