Spectra for:
Gary H. Posner, Victoria Vinader, Kamyar Afarinkia
Compound EPI-2DG 4-(4''-METHYLBENZENESULFENYL)-2-(4'-METHYLBENZENESULFONYL)-5-EXO-NITRO-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE
![4-(4''-METHYLBENZENESULFENYL)-2-(4'-METHYLBENZENESULFONYL)-5-EXO-NITRO-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE](/api/compound/8rsAXoIAYhW.png?h=300&w=458 "4-(4''-METHYLBENZENESULFENYL)-2-(4'-METHYLBENZENESULFONYL)-5-EXO-NITRO-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE")
Compound 1A RHTONYXWNYMVLL-UHFFFAOYSA-N
Compound 2GD 4-(4''-METHYLBENZENESULFENYL)-2-(4'-METHYLBENZENESULFONYL)-5-ENDO-NITRO-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE
![4-(4''-METHYLBENZENESULFENYL)-2-(4'-METHYLBENZENESULFONYL)-5-ENDO-NITRO-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE](/api/compound/3CVtVVc4UTa.png?h=300&w=458 "4-(4''-METHYLBENZENESULFENYL)-2-(4'-METHYLBENZENESULFONYL)-5-ENDO-NITRO-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE")
1-(4'-METHYLBENZENESULFONYL)-3-(PHENYLMETHOXY)-2-PYRIDONE
1-(METHANESULFONYL)-3-(4'-METHYLBENZENESULFENYL)-2-PYRIDONE
3-(4''-METHYLBENZENESULFONYL)-1-(4'-METHYLBENZENESULFONYL)-2-PYRIDONE
3-[(tert-Butyldimethylsilyl)oxy]-1-(methanesulfonyl)-2-pyridone
![3-[(tert-Butyldimethylsilyl)oxy]-1-(methanesulfonyl)-2-pyridone](/api/compound/78whDYbr3Gi.png?h=300&w=458 "3-[(tert-Butyldimethylsilyl)oxy]-1-(methanesulfonyl)-2-pyridone")
3-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-1-(4'-METHYLBENZENESULFONYL)-2-PYRIDONE
![3-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-1-(4'-METHYLBENZENESULFONYL)-2-PYRIDONE](/api/compound/HMjzRGI3PK3.png?h=300&w=458 "3-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-1-(4'-METHYLBENZENESULFONYL)-2-PYRIDONE")
3-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-2-[(METHANESULFONYL)-OXY]-PYRIDINE
![3-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-2-[(METHANESULFONYL)-OXY]-PYRIDINE](/api/compound/9CFakTw8Vw2.png?h=300&w=458 "3-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-2-[(METHANESULFONYL)-OXY]-PYRIDINE")
4-(4''-METHYLBENZENESULFENYL)-2-(4'-METHYLBENZENESULFONYL)-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE-5-ENDO-CARBOXALDEHYDE
![4-(4''-METHYLBENZENESULFENYL)-2-(4'-METHYLBENZENESULFONYL)-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE-5-ENDO-CARBOXALDEHYDE](/api/compound/32evJb9GP92.png?h=300&w=458 "4-(4''-METHYLBENZENESULFENYL)-2-(4'-METHYLBENZENESULFONYL)-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE-5-ENDO-CARBOXALDEHYDE")
4-(BENZYLOXY)-2-(4'-METHYLBENZENESULFONYL)-5-ENDO-NITRO-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE
![4-(BENZYLOXY)-2-(4'-METHYLBENZENESULFONYL)-5-ENDO-NITRO-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE](/api/compound/Jx2V9x50caA.png?h=300&w=458 "4-(BENZYLOXY)-2-(4'-METHYLBENZENESULFONYL)-5-ENDO-NITRO-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE")
4-(Benzyloxy)-2-(4'-methylbenzenesulfonyl)-5-exo-nitro-3-oxo-2-azabicyclo[2.2.2]oct-7-ene
![4-(Benzyloxy)-2-(4'-methylbenzenesulfonyl)-5-exo-nitro-3-oxo-2-azabicyclo[2.2.2]oct-7-ene](/api/compound/Avcb38y9rr2.png?h=300&w=458 "4-(Benzyloxy)-2-(4'-methylbenzenesulfonyl)-5-exo-nitro-3-oxo-2-azabicyclo[2.2.2]oct-7-ene")
4-(BENZYLOXY)-5-ENDO-([(TERT.-BUTYLDIMETHYLSILYL)-OXY]-METHYL)-2-(4'-METHYLBENZENESULFONYL)-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE
![4-(BENZYLOXY)-5-ENDO-([(TERT.-BUTYLDIMETHYLSILYL)-OXY]-METHYL)-2-(4'-METHYLBENZENESULFONYL)-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE](/api/compound/9VdxsNhVTgb.png?h=300&w=458 "4-(BENZYLOXY)-5-ENDO-([(TERT.-BUTYLDIMETHYLSILYL)-OXY]-METHYL)-2-(4'-METHYLBENZENESULFONYL)-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE")
4-(BENZYLOXY)-5-ENDO-(HYDROXYMETHYL)-2-(4'-METHYLBENZENESULFONYL)-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE
![4-(BENZYLOXY)-5-ENDO-(HYDROXYMETHYL)-2-(4'-METHYLBENZENESULFONYL)-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE](/api/compound/AyvtBQZnCjQ.png?h=300&w=458 "4-(BENZYLOXY)-5-ENDO-(HYDROXYMETHYL)-2-(4'-METHYLBENZENESULFONYL)-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE")
4-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-2-(4'-METHYLBENZENESULFONYL)-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE-5-ENDO-CARBOXALDEHYDE
![4-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-2-(4'-METHYLBENZENESULFONYL)-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE-5-ENDO-CARBOXALDEHYDE](/api/compound/GlOeSawkegi.png?h=300&w=458 "4-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-2-(4'-METHYLBENZENESULFONYL)-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE-5-ENDO-CARBOXALDEHYDE")
4-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-2-(4'-METHYLBENZENESULFONYL)-5-ENDO-NITRO-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE
![4-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-2-(4'-METHYLBENZENESULFONYL)-5-ENDO-NITRO-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE](/api/compound/Dh0DGprtY2H.png?h=300&w=458 "4-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-2-(4'-METHYLBENZENESULFONYL)-5-ENDO-NITRO-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE")
4-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-5-ENDO-(HYDROXYMETHYL)-2-(4'-METHYLBENZENESULFONYL)-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE
![4-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-5-ENDO-(HYDROXYMETHYL)-2-(4'-METHYLBENZENESULFONYL)-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE](/api/compound/7HhrmiXOugn.png?h=300&w=458 "4-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-5-ENDO-(HYDROXYMETHYL)-2-(4'-METHYLBENZENESULFONYL)-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE")
4-HYDROXY-5-ENDO-([(TERT.-BUTYLDIMETHYLSILYL)-OXY]-METHYL)-2-(4'-METHYLBENZENESULFONYL)-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE
![4-HYDROXY-5-ENDO-([(TERT.-BUTYLDIMETHYLSILYL)-OXY]-METHYL)-2-(4'-METHYLBENZENESULFONYL)-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE](/api/compound/BpJpDSHCIyX.png?h=300&w=458 "4-HYDROXY-5-ENDO-([(TERT.-BUTYLDIMETHYLSILYL)-OXY]-METHYL)-2-(4'-METHYLBENZENESULFONYL)-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE")
4-Methoxy-2-(4'-Methylbenzenesulfonyl)-5-endo-nitro-3-oxo-2-azabicyclo[2.2.2]oct-7-ene
![4-Methoxy-2-(4'-Methylbenzenesulfonyl)-5-endo-nitro-3-oxo-2-azabicyclo[2.2.2]oct-7-ene](/api/compound/28fJpmjuzNt.png?h=300&w=458 "4-Methoxy-2-(4'-Methylbenzenesulfonyl)-5-endo-nitro-3-oxo-2-azabicyclo[2.2.2]oct-7-ene")
4-Methoxy-2-(4'-methylbenzenesulfonyl)-5-exo-nitro-3-oxo-2-azabicyclo[2.2.2]oct-7-ene
![4-Methoxy-2-(4'-methylbenzenesulfonyl)-5-exo-nitro-3-oxo-2-azabicyclo[2.2.2]oct-7-ene](/api/compound/D59J5SWFHRy.png?h=300&w=458 "4-Methoxy-2-(4'-methylbenzenesulfonyl)-5-exo-nitro-3-oxo-2-azabicyclo[2.2.2]oct-7-ene")
5-ENDO-([(TERT.-BUTYLDIMETHYLSILYL)-OXY]-METHYL)-2-(4'-METHYLBENZENESULFONYL)-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE
![5-ENDO-([(TERT.-BUTYLDIMETHYLSILYL)-OXY]-METHYL)-2-(4'-METHYLBENZENESULFONYL)-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE](/api/compound/EmaLEzDirWO.png?h=300&w=458 "5-ENDO-([(TERT.-BUTYLDIMETHYLSILYL)-OXY]-METHYL)-2-(4'-METHYLBENZENESULFONYL)-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE")
5-ENDO-([(TERT.-BUTYLDIMETHYLSILYL)-OXY]-METHYL)-4-(4''-METHYLBENZENESULFENYL)-2-(4'-METHYLBENZENESULFONYL)-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE
![5-ENDO-([(TERT.-BUTYLDIMETHYLSILYL)-OXY]-METHYL)-4-(4''-METHYLBENZENESULFENYL)-2-(4'-METHYLBENZENESULFONYL)-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE](/api/compound/FgVhgZLggZT.png?h=300&w=458 "5-ENDO-([(TERT.-BUTYLDIMETHYLSILYL)-OXY]-METHYL)-4-(4''-METHYLBENZENESULFENYL)-2-(4'-METHYLBENZENESULFONYL)-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE")
5-ENDO-([(TERT.-BUTYLDIMETHYLSILYL)-OXY]-METHYL)-4-METHOXY-2-(4'-METHYLBENZENESULFONYL)-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE
![5-ENDO-([(TERT.-BUTYLDIMETHYLSILYL)-OXY]-METHYL)-4-METHOXY-2-(4'-METHYLBENZENESULFONYL)-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE](/api/compound/KNsEjfZbZ5J.png?h=300&w=458 "5-ENDO-([(TERT.-BUTYLDIMETHYLSILYL)-OXY]-METHYL)-4-METHOXY-2-(4'-METHYLBENZENESULFONYL)-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE")
5-ENDO-(HYDROXYMETHYL)-4-(4''-METHYLBENZENESULFENYL)-2-(4'-METHYLBENZENESULFONYL)-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE
![5-ENDO-(HYDROXYMETHYL)-4-(4''-METHYLBENZENESULFENYL)-2-(4'-METHYLBENZENESULFONYL)-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE](/api/compound/BrMTvXrSowO.png?h=300&w=458 "5-ENDO-(HYDROXYMETHYL)-4-(4''-METHYLBENZENESULFENYL)-2-(4'-METHYLBENZENESULFONYL)-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE")
5-endo-Acetyl-4-Methoxy-2-(4'-Methylbenzenesulfonyl)-3-oxo-2-azabicyclo[2.2.2]oct-7-ene
![5-endo-Acetyl-4-Methoxy-2-(4'-Methylbenzenesulfonyl)-3-oxo-2-azabicyclo[2.2.2]oct-7-ene](/api/compound/4ys9etFskg9.png?h=300&w=458 "5-endo-Acetyl-4-Methoxy-2-(4'-Methylbenzenesulfonyl)-3-oxo-2-azabicyclo[2.2.2]oct-7-ene")
5-METHYL-4-(4''-METHYLBENZENESULFENYL)-2-(4'-METHYLBENZENESULFONYL)-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE-2-CARBOXALDEHYDE
![5-METHYL-4-(4''-METHYLBENZENESULFENYL)-2-(4'-METHYLBENZENESULFONYL)-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE-2-CARBOXALDEHYDE](/api/compound/8Bm0jBIaFuU.png?h=300&w=458 "5-METHYL-4-(4''-METHYLBENZENESULFENYL)-2-(4'-METHYLBENZENESULFONYL)-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE-2-CARBOXALDEHYDE")
DIMETHYL-1-BETA-METHOXY-4-ALPHA-[(4'-METHYLBENZENESULFONYL)-AMINO]-CYCLOHEX-5-ENE-1,2-DICARBOXYLATE
![DIMETHYL-1-BETA-METHOXY-4-ALPHA-[(4'-METHYLBENZENESULFONYL)-AMINO]-CYCLOHEX-5-ENE-1,2-DICARBOXYLATE](/api/compound/4aH6Ccba3wO.png?h=300&w=458 "DIMETHYL-1-BETA-METHOXY-4-ALPHA-[(4'-METHYLBENZENESULFONYL)-AMINO]-CYCLOHEX-5-ENE-1,2-DICARBOXYLATE")
IRNUMLRGFPUHJS-UHFFFAOYSA-N
JYJMIYIWRASWNJ-UHFFFAOYSA-N
METHYL-1-BETA-(BENZYLOXY)-6-BETA-([(TERT.-BUTYLDIMETHYLSILYL)-OXY]-METHYL)-4-ALPHA-(4'-METHYLBENZENESULFONYL)-CYCLOHEX-2-ENE-CARBOXYLATE
![METHYL-1-BETA-(BENZYLOXY)-6-BETA-([(TERT.-BUTYLDIMETHYLSILYL)-OXY]-METHYL)-4-ALPHA-(4'-METHYLBENZENESULFONYL)-CYCLOHEX-2-ENE-CARBOXYLATE](/api/compound/4W04KAU01UO.png?h=300&w=458 "METHYL-1-BETA-(BENZYLOXY)-6-BETA-([(TERT.-BUTYLDIMETHYLSILYL)-OXY]-METHYL)-4-ALPHA-(4'-METHYLBENZENESULFONYL)-CYCLOHEX-2-ENE-CARBOXYLATE")
METHYL-6-ALPHA-([(TERT.-BUTYLDIMETHYLSILYL)-OXY]-METHYL)-4-BETA-[(4'-METHYLBENZENESULFONYL)-AMINO]-CYCLOHEXENE-1-CARBOXYLATE
![METHYL-6-ALPHA-([(TERT.-BUTYLDIMETHYLSILYL)-OXY]-METHYL)-4-BETA-[(4'-METHYLBENZENESULFONYL)-AMINO]-CYCLOHEXENE-1-CARBOXYLATE](/api/compound/JNuR1cyw6WH.png?h=300&w=458 "METHYL-6-ALPHA-([(TERT.-BUTYLDIMETHYLSILYL)-OXY]-METHYL)-4-BETA-[(4'-METHYLBENZENESULFONYL)-AMINO]-CYCLOHEXENE-1-CARBOXYLATE")
METHYL-6-BETA-([(TERT.-BUTYLDIMETHYLSILYL)-OXY]-METHYL)-1-BETA-HYDROXY-4-ALPHA-(4'-METHYLBENZENESULFONYL)-CYCLOHEX-2-ENE-CARBOXYLATE
![METHYL-6-BETA-([(TERT.-BUTYLDIMETHYLSILYL)-OXY]-METHYL)-1-BETA-HYDROXY-4-ALPHA-(4'-METHYLBENZENESULFONYL)-CYCLOHEX-2-ENE-CARBOXYLATE](/api/compound/6T62cr3H8Fd.png?h=300&w=458 "METHYL-6-BETA-([(TERT.-BUTYLDIMETHYLSILYL)-OXY]-METHYL)-1-BETA-HYDROXY-4-ALPHA-(4'-METHYLBENZENESULFONYL)-CYCLOHEX-2-ENE-CARBOXYLATE")
METHYL-6-BETA-([(TERT.-BUTYLDIMETHYLSILYL)-OXY]-METHYL)-1-BETA-METHOXY-4-ALPHA-[(4'-METHYLBENZENESULFONYL)-AMINO]-CYCLOHEX-2-ENE-CARBOXYLATE
![METHYL-6-BETA-([(TERT.-BUTYLDIMETHYLSILYL)-OXY]-METHYL)-1-BETA-METHOXY-4-ALPHA-[(4'-METHYLBENZENESULFONYL)-AMINO]-CYCLOHEX-2-ENE-CARBOXYLATE](/api/compound/F4Joji4lyDg.png?h=300&w=458 "METHYL-6-BETA-([(TERT.-BUTYLDIMETHYLSILYL)-OXY]-METHYL)-1-BETA-METHOXY-4-ALPHA-[(4'-METHYLBENZENESULFONYL)-AMINO]-CYCLOHEX-2-ENE-CARBOXYLATE")
WFMWJALVUFSEAS-UHFFFAOYSA-N
Citation
| Citation | J.ORG.CHEM.,57,4088(1992) |
|---|---|
| Journal | The Journal of Organic Chemistry |
| Issue | 15 |
| Volume | 57 |
| Page(s) | 4088-4097 |
| Year | 1992 |
| Author(s) | Gary H. Posner, Victoria Vinader, Kamyar Afarinkia |
| Publisher | American Chemical Society (ACS) |
| DOI | 10.1021/jo00041a010 |