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4-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-2-(4'-METHYLBENZENESULFONYL)-5-ENDO-NITRO-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE

Compound with spectra: 1 NMR, and 1 MS (GC)

4-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-2-(4'-METHYLBENZENESULFONYL)-5-ENDO-NITRO-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE
SpectraBase Compound ID Dh0DGprtY2H
InChI InChI=1S/C20H28N2O6SSi/c1-14-7-9-16(10-8-14)29(26,27)21-15-11-12-20(18(21)23,17(13-15)22(24)25)28-30(5,6)19(2,3)4/h7-12,15,17H,13H2,1-6H3/t15-,17-,20-/m0/s1
InChIKey SVMDWABIEMBIKF-KNBMTAEXSA-N
Mol Weight 452.6 g/mol
Molecular Formula C20H28N2O6SSi
Exact Mass 452.143734 g/mol
Enantiomer InChIKey SVMDWABIEMBIKF-WRWLIDTKSA-N

View Spectrum of 4-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-2-(4'-METHYLBENZENESULFONYL)-5-ENDO-NITRO-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE

MS (GC) Spectrum
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Source of Spectrum J-57-4093-2

View Spectrum of 4-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-2-(4'-METHYLBENZENESULFONYL)-5-ENDO-NITRO-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
  • 4-([tert-Butyldimethylsilyl)oxy]-2-(4'-Methylbenzenesulfonyl)-5-endo-nitro-3-oxo-2-azabicyclo[2.2.2]-7-octene
4-[(TERT.-BUTYLDIMETHYLSILYL)-OXY]-2-(4'-METHYLBENZENESULFONYL)-3-OXO-2-AZABICYCLO-[2.2.2]-OCT-7-ENE-5-ENDO-CARBOXALDEHYDE
4-([tert-Butyldimethylsilyl)oxy]-2-(4'-Methylbenzenesulfonyl)-3-oxo-2-azabicyclo[2.2.2]-7-octene-5-endo-carboxadehyde
Heptacyclo(8.5.1.0/2,9/.0/3,8/,.0/3,14/.0/8,12/.0/11,15/)hexadecane
(3-RS,4a-SR,4b-RS,10b-RS)-8-Formyl-5-methoxy-2,3-dihydro-1-H-3,4b-methanocyclopropa-[1,2:1,3]-dibenzene-4-(4a-H)-one
Pyrrolo[3,4-c]pyrrole-1,1(2H)-dicarboxylic acid, hexahydro-3-(4-nitrophenyl)-4,6-dioxo-5-phenyl-, diethyl ester, (3.alpha.,3a.beta.,6a.beta.)-
3H-Pentaleno[2,1-a]indene-3,4,7(3aH,4aH)-trione, 3b,8,8a,8b,9,9a-hexahydro-3a,4a-dimethyl-, (3a.alpha.,3b.beta.,4a.alpha.,8a.alpha.,8b.beta.,9a.alpha.)-
Annasterol sulfate
24(.xi.)-methylcholest-5-ene-1.alpha.,3.beta.,11.alpha.-triol
10b-n-Butyl-1,1-dimethyl-8,9-dimethoxy-1,5,6,10b-tetrahydrooxazolo[4,3-a]isoquinolin-3(2H)-one
Methyl 4-Methoxy-2-(4'-Methylbenzenesulfonyl)-3-oxo-2-azabicyclo[2.2.2]oct-7-ene-5-endo-carboxylate
Title Journal or Book Year
Diels-Alder cycloadditions using nucleophilic 2-pyridones. Regiocontrolled and stereocontrolled synthesis of unsaturated, bridged, bicyclic lactams The Journal of Organic Chemistry 1992
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