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(2S,8R,9S)-8-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-ETHYL-9-[(2Z)-5-(TRIISOPROPYLSILYL)-PENT-2-EN-4-YNYL]-1-OXA-3Z,5Z-CYCLONONADIENE

Compound with spectra: 1 NMR

(2S,8R,9S)-8-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-ETHYL-9-[(2Z)-5-(TRIISOPROPYLSILYL)-PENT-2-EN-4-YNYL]-1-OXA-3Z,5Z-CYCLONONADIENE
SpectraBase Compound ID L2GHrQx8X71
InChI InChI=1S/C30H54O2Si2/c1-13-27-20-16-14-17-22-29(32-33(11,12)30(8,9)10)28(31-27)21-18-15-19-23-34(24(2)3,25(4)5)26(6)7/h14-18,20,24-29H,13,21-22H2,1-12H3/b17-14-,18-15-,20-16-/t27-,28-,29+/m0/s1
InChIKey AGMAGTMPIWPPPE-FRTYHXQQSA-N
Mol Weight 502.9 g/mol
Molecular Formula C30H54O2Si2
Exact Mass 502.366234 g/mol
Enantiomer InChIKey AGMAGTMPIWPPPE-MIBGJXMGSA-N

View Spectrum of (2S,8R,9S)-8-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-ETHYL-9-[(2Z)-5-(TRIISOPROPYLSILYL)-PENT-2-EN-4-YNYL]-1-OXA-3Z,5Z-CYCLONONADIENE

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
(2S,8R,9S)-8-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-ETHYL-9-[(2Z)-5-(TRIISOPROPYLSILYL)-PENT-2-EN-4-YNYL]-1-OXA-3Z,5Z-CYCLONONADIENE
(5S,6S,9S,10S,13S,14S)5-tert-Butyldimethylsiloxy-14-hydroxy-6,9;10,13-diepoxy-1,18-octadecadiene
(5S,6S,9S,10S,13S,14S,17S)-5-tert-Butyldimethylsiloxy-18-hydroxy-6,9;10,13;14,17-triepoxy-1-octadecene
tert-Butyl-[(2S,3S,5R)-5-[[4-[[(2R,4S,5S)-4-[tert-butyl(dimethyl)silyl]oxy-5-pentyl-oxolan-2-yl]methoxy]phenoxy]methyl]-2-pentyl-oxolan-3-yl]oxy-dimethyl-silane
Methyl 8,11,12-tri(tert-butyldimethylsiloxy)eicosan-5(Z), 9(E),14(Z),17(Z)-tetraenoate
(1S)-1-[(2R,4S,5S)-4-[tert-butyl(dimethyl)silyl]oxy-5-pentyl-2-oxolanyl]-9-decen-1-ol
(3E,5R,6S,12R)-5,6-bis[[tert-butyl(dimethyl)silyl]oxy]-12-methyl-1-oxacyclododec-3-en-2-one
(R)-3-(4-Methoxybenzyl)-syn-5-[(R)-1-(tert-Butyldimethylsilyloxy)-3-butenyl]isoxazole
(1S,3S,4S,5Z,8R)-3-(tert-Butyldimethylsilyloxymethyl)-2,9-dioxabicyclo[6.4.0]dodec-5-en-4-ol
(2S,3R,E)-3-{[(t-Butyl)dimethylsilyl]oxy}-2-(prop-2'-enyl)-tetrahydro-4H-pyran-4-one - (O-methyloxime)
(2S,3R,Z)-3-{[(t-Butyl)dimethylsilyl]oxy}-2-(prop-2'-enyl)-tetrahydro-4H-pyran-4-one - (O-methyloxime)
Title Journal or Book Year
Intramolecular Silicon-Assisted Cross-Coupling:  Total Synthesis of (+)-Brasilenyne Journal of the American Chemical Society 2002
(2S,8R,9S)-8-(TERT.-BUTYLDIMETHYLSILYLOXY)-2-ETHYL-9-[(2Z)-5-(TRIISOPROPYLSILYL)-PENT-2-EN-4-YNYL]-1-OXA-3Z,5Z-CYCLONONADIENE
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