(-)-(S)-N,N-DIMETHYLAMINO-S-[(Z)-(3R,4R)-3-CYCLOHEXYL-4-(4-BROMOPHENYL)-4-[(TRIETHYLSILYL)-OXY]-BUT-ENYL]-PHENYL-SULFOXONIUM-TETRAFLUOROBORATE
Compound with spectra: 1 NMR
![(-)-(S)-N,N-DIMETHYLAMINO-S-[(Z)-(3R,4R)-3-CYCLOHEXYL-4-(4-BROMOPHENYL)-4-[(TRIETHYLSILYL)-OXY]-BUT-ENYL]-PHENYL-SULFOXONIUM-TETRAFLUOROBORATE](/api/compound/qYiI8qRbWG.png?ph=true&h=300&w=458 "(-)-(S)-N,N-DIMETHYLAMINO-S-[(Z)-(3R,4R)-3-CYCLOHEXYL-4-(4-BROMOPHENYL)-4-[(TRIETHYLSILYL)-OXY]-BUT-ENYL]-PHENYL-SULFOXONIUM-TETRAFLUOROBORATE")
| SpectraBase Compound ID | qYiI8qRbWG |
|---|---|
| InChI | InChI=1S/C30H45BrNO2SSi.BF4/c1-6-36(7-2,8-3)34-30(26-19-21-27(31)22-20-26)29(25-15-11-9-12-16-25)23-24-35(33,32(4)5)28-17-13-10-14-18-28;2-1(3,4)5/h10,13-14,17-25,29-30H,6-9,11-12,15-16H2,1-5H3;/q2*-1/b24-23-;/t29-,30-;/m0./s1 |
| InChIKey | GPVLCZZQLDJLKS-YHZATWBASA-N |
| Mol Weight | 678.5 g/mol |
| Molecular Formula | C30H45BBrF4NO2SSi |
| Exact Mass | 677.215283 g/mol |
| Parent InChIKey | ZVWVQDVQCFQXKZ-PFWOMTEYSA-N |
| Enantiomer InChIKey | GPVLCZZQLDJLKS-BAGDSWACSA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
(-)-TRIETHYL-[(Z)-(1R,2R)-2-CYCLOHEXYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-1-(4-BROMOPHENYL)-BUT-3-ENYLOXY]-SILANE
(-)-TRIETHYL-[(Z)-(1R,2R)-2-ISOPROPYL-3-METHYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-1-(4-BROMOPHENYL)-BUT-3-ENYLOXY]-SILANE
(-)-TRIETHYL-[(E)-(1R,2R)-2-ISOPROPYL-1-PHENYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-PENT-3-ENYLOXY]-SILANE
(4Z)-8,9,10-trimethoxy-2,2-dimethyl-3,6-dihydro-2H-1,2-benzoxasilocine
Triethyl ((R)-2-methyl-1-((S,E)-2-[(S)-N-methyl-S-phenyl-sulfonimidoyl)]-cyclo-hexyl-)propoxy)silane
2"-[Hydroxy(phenyl)methy)-2"-isopropyldispiro[1,3-dioxane-2,1'-cyclohexane-4',1"-oxirane]
(2S,3S)-2-(tert-butoxycarbonylamino)-3-[tert-butyl(dimethyl)silyl]oxy-3-phenyl-propanethioic acid S-(p-tolyl) ester
Ethyl 5-[3',5'-dimethoxy-4'-(oct-1''-en-4''-yl)phenyl]-4-methyl-5-[(triethylsilyl)oxy]pent-2-enoate
YAQYVAALGQEPBJ-OWCLPIDISA-N
(+)-(R)-Furan-2-yl[(Z,SS,R)-2-(N-methyl-S-phenylsulfonimidoylmethylene)cyclopentyl]-methanol
| Title | Journal or Book | Year |
|---|---|---|
| Asymmetric Synthesis of anti-Homopropargylic Alcohols from Aldehydes and Chiral Sulfonimidoyl Substituted Bis(allyl)titanium Complexes through Generation and Elimination of Novel Chiral Alkylidenecarbene (Dimethylamino)sulfoxonium Ylides | Journal of the American Chemical Society | 2002 |