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(-)-TRIETHYL-[(E)-(1R,2R)-2-ISOPROPYL-1-PHENYL-4-[(S)-N-METHYL-S-PHENYL-SULFONIMIDOYL]-PENT-3-ENYLOXY]-SILANE
SpectraBase Compound ID D2DL8VIX503
InChI InChI=1S/C27H41NO2SSi/c1-8-32(9-2,10-3)30-27(24-17-13-11-14-18-24)26(22(4)5)21-23(6)31(29,28-7)25-19-15-12-16-20-25/h11-22,26-27H,8-10H2,1-7H3/b23-21+/t26-,27-,31?/m0/s1
InChIKey WKRNHNJYCWAUQQ-KYCGFQNPSA-N
Mol Weight 471.8 g/mol
Molecular Formula C27H41NO2SSi
Exact Mass 471.262727 g/mol
Enantiomer InChIKey WKRNHNJYCWAUQQ-ZJIPVRQQSA-N
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
Title Journal or Book Year
Asymmetric Synthesis of anti-Homopropargylic Alcohols from Aldehydes and Chiral Sulfonimidoyl Substituted Bis(allyl)titanium Complexes through Generation and Elimination of Novel Chiral Alkylidenecarbene (Dimethylamino)sulfoxonium Ylides Journal of the American Chemical Society 2002
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