(1''S,2S,2'S,6'R,8'S,9'S,11'R)-4-(8'-[1''-([(TERT.-BUTYLDIPHENYLSILYL)-OXY]-METHYL)-PROPYL]-9',11'-DIMETHYL-1',7'-DIOXASPIRO-[5.5]-UNDEC-4'-EN-2'-YL)-2-HYDROXY-2
Compound with spectra: 1 NMR
![(1''S,2S,2'S,6'R,8'S,9'S,11'R)-4-(8'-[1''-([(TERT.-BUTYLDIPHENYLSILYL)-OXY]-METHYL)-PROPYL]-9',11'-DIMETHYL-1',7'-DIOXASPIRO-[5.5]-UNDEC-4'-EN-2'-YL)-2-HYDROXY-2](/api/compound/Q8idf1eNf3.png?ph=true&h=300&w=458 "(1''S,2S,2'S,6'R,8'S,9'S,11'R)-4-(8'-[1''-([(TERT.-BUTYLDIPHENYLSILYL)-OXY]-METHYL)-PROPYL]-9',11'-DIMETHYL-1',7'-DIOXASPIRO-[5.5]-UNDEC-4'-EN-2'-YL)-2-HYDROXY-2")
| SpectraBase Compound ID | Q8idf1eNf3 |
|---|---|
| InChI | InChI=1S/C43H60O7SSi/c1-9-35(30-48-52(41(5,6)7,38-18-12-10-13-19-38)39-20-14-11-15-21-39)40-33(3)29-34(4)43(50-40)27-16-17-36(49-43)26-28-42(8,44)31-47-51(45,46)37-24-22-32(2)23-25-37/h10-16,18-25,27,33-36,40,44H,9,17,26,28-31H2,1-8H3/t33?,34?,35?,36-,40?,42-,43+/m1/s1 |
| InChIKey | LCZMNKQOAGPGHP-KPMABAJASA-N |
| Mol Weight | 749.1 g/mol |
| Molecular Formula | C43H60O7SSi |
| Exact Mass | 748.382902 g/mol |
| Enantiomer InChIKey | LCZMNKQOAGPGHP-JDJXRXGJSA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
#5;(2S,5R,7S,1'S,2''R,4''S,5''R,1''''S)-(+)-2-[5''-BENZYLOXYMETHYL-4''-HYDROXY-2''-METHYLTETRAHYDROFUR-2''-YL)-HYDROXYMETHYL]-7-[2''''-(TERT.-BUTYLDIPHENYLSILYLOXY)-1''''-M
(1'R,2'S,3'S,5S)-3-BROMO-5-[4'-(TERT.-BUTYLDIPHENYLSILYLOXY)-1'-HYDROXY-2',3'-BIS-METHOXYMETHOXY]-BUTYL-4,4-DIMETHOXY-PYRROLIDIN-2-ONE
RAC-5'-[(ACETYLTHIO)-METHYL]-N(6)-BENZOYL-3'-([(TERT.-BUTYL)-DIPHENYLSILYLOXY]-METHYL)-2',3',5'-TRIDEOXY-1'-A-CARBAADENOSINE;S-(-C-4-[6-
SM-8-118
4-C-(BENZOYLOXYMETHYL)-5-O-(TERT.-BUTYLDIPHENYLSILYL)-1,2-O-ISOPROPYLIDENE-ALPHA-D-XYLOFURANOSIDE
[9-(TERT.-BUTYLDIPHENYLSILYLOXYMETHYL)-2-METHYL-1,6,8-TRIOXASPIRO-[4.1.5.3]-PENTADEC-13-EN-2-YL]-METHYL-ACETATE
(2S)-2-[(2S,4Z)-4-[(2S)-3-[tert-butyl(diphenyl)silyl]oxy-2-methyl-propylidene]-5-keto-2-methyl-tetrahydrofuran-2-yl]pyrrolidine-1-carboxylic acid tert-butyl ester
Methyl 7-{1-[(1R,2R,4aR,6R,8S,8aS)-6-[(tert-butydiphenylsilyl)oxy]-8-[(2S)-methyl-1-oxobutyl)oxy]-1,2,4a,5,6,7,8,8a-octahydro-2-methylnaphthalenyl]}-3(R)-[(tert-butyldimethylsilyl)oxy]-5-oxohepten-6-oate
3-(3-AZIDO-5-O-TERT.-BUTYLDIPHENYLSILYL-2,3-DIDEOXY-ALPHA,BETA-D-ERYTHRO-PENTOFURANOSYL)-6-[(3,5-DIMETHYLPHENYL)-THIO]-URACIL
| Title | Journal or Book | Year |
|---|---|---|
| Synthesis of the bis-spiroacetal moiety of 17-epi-20-deoxysalinomycin | The Journal of Organic Chemistry | 1992 |