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#5;(2S,5R,7S,1'S,2''R,4''S,5''R,1''''S)-(+)-2-[5''-BENZYLOXYMETHYL-4''-HYDROXY-2''-METHYLTETRAHYDROFUR-2''-YL)-HYDROXYMETHYL]-7-[2''''-(TERT.-BUTYLDIPHENYLSILYLOXY)-1''''-M

Compound with spectra: 1 NMR, and 1 MS (GC)

#5;(2S,5R,7S,1'S,2''R,4''S,5''R,1''''S)-(+)-2-[5''-BENZYLOXYMETHYL-4''-HYDROXY-2''-METHYLTETRAHYDROFUR-2''-YL)-HYDROXYMETHYL]-7-[2''''-(TERT.-BUTYLDIPHENYLSILYLOXY)-1''''-M
SpectraBase Compound ID 62QQ72S1jAj
InChI InChI=1S/C41H56O7Si/c1-30(27-45-49(39(2,3)4,32-18-11-7-12-19-32)33-20-13-8-14-21-33)35-22-15-24-41(47-35)25-23-36(48-41)38(43)40(5)26-34(42)37(46-40)29-44-28-31-16-9-6-10-17-31/h6-14,16-21,30,34-38,42-43H,15,22-29H2,1-5H3/t30-,34-,35-,36-,37+,38-,40+,41-/m0/s1
InChIKey VHPKSMOHXUWUMG-JEZKBJHTSA-N
Mol Weight 689.0 g/mol
Molecular Formula C41H56O7Si
Exact Mass 688.379531 g/mol
Enantiomer InChIKey VHPKSMOHXUWUMG-QLZBPEHBSA-N

View Spectrum of #5;(2S,5R,7S,1'S,2''R,4''S,5''R,1''''S)-(+)-2-[5''-BENZYLOXYMETHYL-4''-HYDROXY-2''-METHYLTETRAHYDROFUR-2''-YL)-HYDROXYMETHYL]-7-[2''''-(TERT.-BUTYLDIPHENYLSILYLOXY)-1''''-M

MS (GC) Spectrum
Copyright Copyright © 2020-2024 John Wiley & Sons, Inc. All Rights Reserved.
Source of Spectrum F5-4-1399-6

View Spectrum of #5;(2S,5R,7S,1'S,2''R,4''S,5''R,1''''S)-(+)-2-[5''-BENZYLOXYMETHYL-4''-HYDROXY-2''-METHYLTETRAHYDROFUR-2''-YL)-HYDROXYMETHYL]-7-[2''''-(TERT.-BUTYLDIPHENYLSILYLOXY)-1''''-M

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
  • (2S,5S,7S,1''S,2''R,4''S,5''R,1''''S)-2-[(5''-(Benzyloxymethyl)-4''-hydroxy-2''-methyltetrahydrofur-2''-yl)hydroxymethyl]-7-[2''-(t-butyldiphenylsilyloxy)-1''-methylethyl]-1,6-dioxaspiro[4.5]decane
(1''S,2S,2'S,6'R,8'S,9'S,11'R)-4-(8'-[1''-([(TERT.-BUTYLDIPHENYLSILYL)-OXY]-METHYL)-PROPYL]-9',11'-DIMETHYL-1',7'-DIOXASPIRO-[5.5]-UNDEC-4'-EN-2'-YL)-2-HYDROXY-2
(1''S,2S,2'R,6'R,8'S,9'S,11'R)-4-(8'-[1''-([(TERT.-BUTYLDIPHENYLSILYL)-OXY]-METHYL)-PROPYL]-9',11'-DIMETHYL-1',7'-DIOXASPIRO-[5.5]-UNDEC-4'-EN-2'-YL)-2-HYDROXY-2
SM-8-118
1,7-Dioxaspiro[5.5]undecane, 2-oxazolidinone deriv.
Benzyl exo-2,3-O-benzylidene-4-O-(2,3,4,6-tetra-O-benzyl.alpha.-D-galactopyranosyl).alpha.-L-rhamnopyranoside
[3aS-[3a.alpha.,4.alpha.,7a.alpha.,7.alpha.(3E,2S*)]]-tetrahydro-2,2-dimethyl-4-[2-[[(1,1-dimethylethyl)diphenylsilyl]oxy]ethyl]-.alpha.-(1-propenyl)-4H-1,3-dioxolo[4,5-c]pyran-7-ethanol [[(1,1-dimethylethyl)dimethylsilyl]oxy]acetate
2-AMINO-4-CHLORO-7-[2-DEOXY-5-O-[(1,1-DIMETHYLETHYL)-DIPHENYLSILYL]-BETA-D-THREO-PENTOFURANOSYL]-7H-PYRROLO-[2,3-D]-PYRIMIDINE
(1'R,2'S,3'S,5S)-3-BROMO-5-[4'-(TERT.-BUTYLDIPHENYLSILYLOXY)-1'-HYDROXY-2',3'-BIS-METHOXYMETHOXY]-BUTYL-4,4-DIMETHOXY-PYRROLIDIN-2-ONE
2-(TRIMETHYLSILYL)-ETHYL-2,4-DI-O-BENZOYL-3-O-BENZYL-6-O-(TERT.-BUTYLDIPHENYLSILYL)-BETA-D-GALACTOPYRANOSIDE
Tert-Butyl((3R,3aS,7aS)-7a-(chloromethyl)-5',5'-dimethylhexahydro-2H-spiro[benzofuran-5,2'-[1,3]dioxane]-3-yloxy)diphenylsilane
Title Journal or Book Year
Synthesis of the ABC Fragment of the Pectenotoxins Organic Letters 2005
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