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#13H;ANTI-(2S,3S)-2-[(E)-2-(2-BROMO-5-METHOXYPHENYL)-ETHENYL]-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-1-[(2S,4R)-4-METHOXY-2-METHOXYMETHYL-PYRROLIDIN-1-YL]-4-M

Compound with spectra: 1 NMR

#13H;ANTI-(2S,3S)-2-[(E)-2-(2-BROMO-5-METHOXYPHENYL)-ETHENYL]-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-1-[(2S,4R)-4-METHOXY-2-METHOXYMETHYL-PYRROLIDIN-1-YL]-4-M
SpectraBase Compound ID LVEV3WYeL5L
InChI InChI=1S/2C41H54BrNO5Si/c2*1-30(2)37(20-15-25-48-49(41(3,4)5,35-16-11-9-12-17-35)36-18-13-10-14-19-36)38(23-21-31-26-33(46-7)22-24-39(31)42)40(44)43-28-34(47-8)27-32(43)29-45-6/h2*9-14,16-19,21-24,26,32,34,37-38H,1,15,20,25,27-29H2,2-8H3/b2*23-21+/t2*32-,34+,37+,38+/m00/s1
InChIKey BIDALXOYBXBTJY-DRBUMDQMSA-N
Mol Weight 1497.7 g/mol
Molecular Formula C82H108Br2N2O10Si2
Exact Mass 1494.590927 g/mol
Enantiomer InChIKey BIDALXOYBXBTJY-HYBPBVIASA-N

View Spectrum of #13H;ANTI-(2S,3S)-2-[(E)-2-(2-BROMO-5-METHOXYPHENYL)-ETHENYL]-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-1-[(2S,4R)-4-METHOXY-2-METHOXYMETHYL-PYRROLIDIN-1-YL]-4-M

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
#12H;ANTI-(2R,3R)-2-[(E)-2-(2-BROMO-5-METHOXYPHENYL)-ETHENYL]-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-1-[(2S,4R)-4-METHOXY-2-METHOXYMETHYL-PYRROLIDIN-1-YL]-4-M
#8J;ANTI-(2R,3R)-1-[(2S,4R)-4-TERT.-BUTOXY-2-METHOXYMETHYL-PYRROLIDIN-1-YL]-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-2-[(E)-2-(3-METHOXYPHENYL)-ETHENYL]-4-METHY
#9K;ANTI-(2S,3S)-1-[(2S,4R)-4-TERT.-BUTOXY-2-TERT.-BUTOXYMETHYL-PYRROLIDIN-1-YL]-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-2-[(E)-2-(3-METHOXYPHENYL)-ETHENYL]-4-
#8K;ANTI-(2R,3R)-1-[(2S,4R)-4-TERT.-BUTOXY-2-TERT.-BUTOXYMETHYL-PYRROLIDIN-1-YL]-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-2-[(E)-2-(3-METHOXYPHENYL)-ETHENYL]-4-
#8L;ANTI-(2R,3R)-1-[(2S,4R)-4-TERT.-BUTOXY-2-PHENOXYMETHYL-PYRROLIDIN-1-YL]-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-2-[(E)-2-(3-METHOXYPHENYL)-ETHENYL]-4-METHY
#17K;ANTI-(2R,3R)-1-[(2S,4R)-4-TERT.-BUTOXY-2-TERT.-BUTOXYMETHYL-PYRROLIDIN-1-YL]-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-2-[(E)-2-(3-METHOXYPHENYL)-ETHYL]-4-M
#17L;ANTI-(2R,3R)-1-[(2S,4R)-4-TERT.-BUTOXY-2-PHENOXYMETHYL-PYRROLIDIN-1-YL]-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-2-[(E)-2-(3-METHOXYPHENYL)-ETHYL]-4-METHYL
#18L;ANTI-(2S,3S)-1-[(2S,4R)-4-TERT.-BUTOXY-2-PHENOXYMETHYL-PYRROLIDIN-1-YL]-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-2-[(E)-2-(3-METHOXYPHENYL)-ETHYL]-4-METHYL
(4-R,5-R,1'-S,2'-S)-2-[2-[3-TERT.-BUTYL-(DIPHENYL)-SILOXYPROPYL]-CYCLOPROPYL]-4,5-BIS-[METHOXY-(DIPHENYL)-METHYL]-1,3,2-DIOXABOROLANE
4-{1'-[4"-(t-Butyldiphenylsilyl)oxy]butyl}-8,11,11-trimethyl-2-(phenymethoxy)bicyclo[5.3.1]undec-7-en-3-one
Title Journal or Book Year
Zwitterionic Aza-Claisen Rearrangements Controlled by Pyrrolidine Auxiliaries - Useful Key Steps in Convergent Enantioselective Syntheses European Journal of Organic Chemistry 2012
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