#18L;ANTI-(2S,3S)-1-[(2S,4R)-4-TERT.-BUTOXY-2-PHENOXYMETHYL-PYRROLIDIN-1-YL]-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-2-[(E)-2-(3-METHOXYPHENYL)-ETHYL]-4-METHYL
Compound with spectra: 1 NMR
![#18L;ANTI-(2S,3S)-1-[(2S,4R)-4-TERT.-BUTOXY-2-PHENOXYMETHYL-PYRROLIDIN-1-YL]-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-2-[(E)-2-(3-METHOXYPHENYL)-ETHYL]-4-METHYL](/api/compound/DwfQdgNXkqx.png?ph=true&h=300&w=458 "#18L;ANTI-(2S,3S)-1-[(2S,4R)-4-TERT.-BUTOXY-2-PHENOXYMETHYL-PYRROLIDIN-1-YL]-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-2-[(E)-2-(3-METHOXYPHENYL)-ETHYL]-4-METHYL")
| SpectraBase Compound ID | DwfQdgNXkqx |
|---|---|
| InChI | InChI=1S/C49H65NO5Si/c1-37(2)45(29-20-32-54-56(49(6,7)8,43-25-15-11-16-26-43)44-27-17-12-18-28-44)46(31-30-38-21-19-24-41(33-38)52-9)47(51)50-35-42(55-48(3,4)5)34-39(50)36-53-40-22-13-10-14-23-40/h10-19,21-28,33,39,42,45-46H,1,20,29-32,34-36H2,2-9H3/t39-,42+,45+,46-/m0/s1 |
| InChIKey | UVXHNJYERBAKHB-NMDNYBNQSA-N |
| Mol Weight | 776.1 g/mol |
| Molecular Formula | C49H65NO5Si |
| Exact Mass | 775.463201 g/mol |
| Enantiomer InChIKey | UVXHNJYERBAKHB-CKOYUXCLSA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
#17K;ANTI-(2R,3R)-1-[(2S,4R)-4-TERT.-BUTOXY-2-TERT.-BUTOXYMETHYL-PYRROLIDIN-1-YL]-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-2-[(E)-2-(3-METHOXYPHENYL)-ETHYL]-4-M
#8L;ANTI-(2R,3R)-1-[(2S,4R)-4-TERT.-BUTOXY-2-PHENOXYMETHYL-PYRROLIDIN-1-YL]-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-2-[(E)-2-(3-METHOXYPHENYL)-ETHENYL]-4-METHY
#8K;ANTI-(2R,3R)-1-[(2S,4R)-4-TERT.-BUTOXY-2-TERT.-BUTOXYMETHYL-PYRROLIDIN-1-YL]-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-2-[(E)-2-(3-METHOXYPHENYL)-ETHENYL]-4-
#9K;ANTI-(2S,3S)-1-[(2S,4R)-4-TERT.-BUTOXY-2-TERT.-BUTOXYMETHYL-PYRROLIDIN-1-YL]-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-2-[(E)-2-(3-METHOXYPHENYL)-ETHENYL]-4-
#8J;ANTI-(2R,3R)-1-[(2S,4R)-4-TERT.-BUTOXY-2-METHOXYMETHYL-PYRROLIDIN-1-YL]-3-(3-TERT.-BUTYLDIPHENYLSILYLOXYPROPYL)-2-[(E)-2-(3-METHOXYPHENYL)-ETHENYL]-4-METHY
tert-Butyl (2S)-2-[(1S,3Z,5S)-6-{[tert-Butyl(diphenyl)silyl]oxy}-1-hydroxy-1,5-dimethyl-3-(triphenylstannyl)-3-hexenyl]-1-pyrrolidinecarboxylate
4-{1'-[4"-(t-Butyldiphenylsilyl)oxy]butyl}-8,11,11-trimethyl-2-(phenymethoxy)bicyclo[5.3.1]undec-7-en-3-one
(5R,6R)-5-benzoxy-6-[(4S,5R)-5-[[tert-butyl(diphenyl)silyl]oxymethyl]-2,2-dimethyl-1,3-dioxolan-4-yl]-2-piperidone
(5R)-1-[(1R)-1-(TERT.-BUTYLDIPHENYLSILYLOXYMETHYL)-ALLYL]-5-[(2R)-5-OXO-3-VINYL-2,5-DIHYDRO-2-FURYL]-PYRROLIDIN-2-ONE
| Title | Journal or Book | Year |
|---|---|---|
| Zwitterionic Aza-Claisen Rearrangements Controlled by Pyrrolidine Auxiliaries - Useful Key Steps in Convergent Enantioselective Syntheses | European Journal of Organic Chemistry | 2012 |