(2S,4R)-METHYL-4-TERT.-BUTYLDIPHENYLSILYLOXY-1-[(E)-6-TERT.-BUTYLDIPHENYLSILYLOXY-2-METHYLHEX-2-ENYL]-PYRROLIDINE-2-CARBOXYLATE
Compound with spectra: 1 NMR
![(2S,4R)-METHYL-4-TERT.-BUTYLDIPHENYLSILYLOXY-1-[(E)-6-TERT.-BUTYLDIPHENYLSILYLOXY-2-METHYLHEX-2-ENYL]-PYRROLIDINE-2-CARBOXYLATE](/api/compound/L7wAzF6SEey.png?ph=true&h=300&w=458 "(2S,4R)-METHYL-4-TERT.-BUTYLDIPHENYLSILYLOXY-1-[(E)-6-TERT.-BUTYLDIPHENYLSILYLOXY-2-METHYLHEX-2-ENYL]-PYRROLIDINE-2-CARBOXYLATE")
| SpectraBase Compound ID | L7wAzF6SEey |
|---|---|
| InChI | InChI=1S/C45H59NO4Si2/c1-36(23-21-22-32-49-51(44(2,3)4,38-24-13-9-14-25-38)39-26-15-10-16-27-39)34-46-35-37(33-42(46)43(47)48-8)50-52(45(5,6)7,40-28-17-11-18-29-40)41-30-19-12-20-31-41/h9-20,23-31,37,42H,21-22,32-35H2,1-8H3/b36-23+/t37-,42+/m1/s1 |
| InChIKey | SQOSYAWUKNDQSM-YPRLKAKBSA-N |
| Mol Weight | 734.1 g/mol |
| Molecular Formula | C45H59NO4Si2 |
| Exact Mass | 733.398262 g/mol |
| Enantiomer InChIKey | SQOSYAWUKNDQSM-RDPQSCHLSA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
Methyl (2S,3S)-1-benzyl-3-(tert-butyldiphenylsilyloxy)pyrrolidine-2-carboxylate
(6R,8R,11R,12R,E)-12-(2-(Benzyloxy)ethyl)-8-((tert-butyldiphenylsilyl)oxy)-14,14-diethyl-2,2,11-trimethyl-3,3-diphenyl-4,13-dioxa-3,14-disilahexadec-9-en-6-yl isobutyrate
[[(1R,2R,3AR,4S,6AS)-1-ALLYL-4-METHYL-1,2,3,3A,4,6A-HEXAHYDROPENTALEN-2-YL]-OXY]-(TERT.-BUTYL)-DIPHENYLSILANE
Dodecahydro-1-(2-[T-butyl-diphenyl-silyloxy]-ethyl)-6-(5-triisopropyl-silyl-2(Z)-penten-4-ynyl)-pyrrolo(1,2-A)quinoline
(+)-(3R,5R)-3-Acetyl-N-(benzyloxycarbonyl)-5-(-oxymethyl)-2-pyrrolidone
METHYL-4-O-BENZOYL-2-O-TERT.-BUTYLDIPHENYLSILYL-3,6-DIDEOXY-ALPHA-D-ARABINO-HEXOPYRANOSIDE
TERT.-BUTYL-(2R,5S)-2-(BENZYLOXYMETHYL)-5,6-DIHYDRO-5-(TERT.-BUTYLDIPHENYLSILYLOXY)-PIPERIDINE-1(2H)-CARBOXYLATE
(1R,3AS,4R,5R,6AS)-5-[[TERT.-BUTYL-(DIPHENYL)-SILYL]-OXY]-1,4-DIMETHYLHEXAHYDROPENTALEN-2(1H)-ONE
(1R,2R)-1-[[(2S,3R)-3-(tert-Butyldiphenylsiloxy)tetrahydropyran-2-yl]methyl]-2,3-dihydroxypropyl Benzoate
2,5-Piperazinedione, 3-[3-[[(1,1-dimethylethyl)diphenylsilyl]oxy]pro pyl]-1,4-bis(phenylmethyl)-, (.+-.)-
| Title | Journal or Book | Year |
|---|---|---|
| Zwitterionic Aza-Claisen Rearrangements Controlled by Pyrrolidine Auxiliaries - Useful Key Steps in Convergent Enantioselective Syntheses | European Journal of Organic Chemistry | 2012 |