[[(3AS',4'R,5'R,6A'R)-4'-ALLYL-5,5-TRIMETHYLHEXAHYDRO-1'H-SPIRO-(1,3-DIOXANE-2,2'-PENTALEN)-5'-YL]-OXY]-(TERT.-BUTYL)-DIMETHYLSILANE
Compound with spectra: 1 NMR
![[[(3AS',4'R,5'R,6A'R)-4'-ALLYL-5,5-TRIMETHYLHEXAHYDRO-1'H-SPIRO-(1,3-DIOXANE-2,2'-PENTALEN)-5'-YL]-OXY]-(TERT.-BUTYL)-DIMETHYLSILANE](/api/compound/Jp0rNsgApJb.png?ph=true&h=300&w=458 "[[(3AS',4'R,5'R,6A'R)-4'-ALLYL-5,5-TRIMETHYLHEXAHYDRO-1'H-SPIRO-(1,3-DIOXANE-2,2'-PENTALEN)-5'-YL]-OXY]-(TERT.-BUTYL)-DIMETHYLSILANE")
| SpectraBase Compound ID | Jp0rNsgApJb |
|---|---|
| InChI | InChI=1S/C22H40O3Si/c1-9-10-17-18-13-22(23-14-21(5,6)15-24-22)12-16(18)11-19(17)25-26(7,8)20(2,3)4/h9,16-19H,1,10-15H2,2-8H3/t16-,17-,18+,19-/m1/s1 |
| InChIKey | QVFAERDLKKOJOF-AKHDSKFASA-N |
| Mol Weight | 380.6 g/mol |
| Molecular Formula | C22H40O3Si |
| Exact Mass | 380.274672 g/mol |
| Enantiomer InChIKey | QVFAERDLKKOJOF-OKYOBFRVSA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
(3a'S,4'R,5'R,6a'R)-5'-(tert-butyldimethylsilyloxy)-5,5-dimethylhexahydro-1'H-spiro[1,3]dioxane-2,2'-pentalene]-4'-carbaldehyde
5-(t-Butyldimethylsilyloxy)-{4'-ethynyl-octahydro-5,5-dimethyl)-spiro[1,3-dioxan-2,2(1'H)-pentalene]}
3ALPHA-TRIMETHYLSILYLOXY-2BETA-[3-OXO-1(E)-OCTENYL]-7,7-ETHYLENDIOXYBICYCLO[3.3.0]OCTANE
(1S*)-Tetrahydro-4'-(1"-hydroxy-2"-octenyl)-5,5-dimethylspiro[1,3-dioxane-2,2'-(1'H)-pentalen]-5'(3'H)-one
(1R*)-Tetrahydro-4'-(1"-hydroxy-2"-octenyl)-5,5-dimethylspiro[1,3-dioxane-2,2'-(1'H)-pentalen]-5'(3'H)-one
Prostaglandin F1.alpha. methyl ester t-butyldimethylsilyl ether
(3aRS,4SR,5RS,6aSR)-3,3a,4,5,6,6a-Hexahydro-5-[(t-butyl)dimethylsilyloxy)-4-(3'-oxooct-1'-en-1'-yl)-2H-cyclopenta[b]furan-2-one
[[(2R,3R,3AS,6AR)-3-ALLYL-1,2,3,3A,4,6A-HEXAHYDROPENTALEN-2-YL]-OXY]-(TERT.-BUTYL)-DIPHENYLSILANE
N-{(3'aS,4'R,6'aR)-(4'-Chloro-1',6'a',6',3'a-tetrahydro-5,5-dimethylspiro[1,3-dioxane-2,2'-(1'H)-pentalen])-5'-ylidene}-N'-(p-toluenesulfonyl)-hydrazine
4-[(tert-Butyldimethyl)siloxy]-1-[(2-methoxyethoxy)methoxy]-1.alpha.,2,3,3a.alpha.,4.alpha.,5,8.beta.,8a.alpha.-octahydroazulen-8-ol
| Title | Journal or Book | Year |
|---|---|---|
| Doing it Twice: Asymmetric Deprotonation/Alkylation of Weiss Diketone Derivatives as Key Steps in the Functionalization of Bicyclo[3.3.0]octanes | European Journal of Organic Chemistry | 2012 |