[[(2R,3R,3AS,6AR)-3-ALLYL-1,2,3,3A,4,6A-HEXAHYDROPENTALEN-2-YL]-OXY]-(TERT.-BUTYL)-DIPHENYLSILANE
Compound with spectra: 1 NMR
![[[(2R,3R,3AS,6AR)-3-ALLYL-1,2,3,3A,4,6A-HEXAHYDROPENTALEN-2-YL]-OXY]-(TERT.-BUTYL)-DIPHENYLSILANE](/api/compound/GQe1lfsQYOo.png?ph=true&h=300&w=458 "[[(2R,3R,3AS,6AR)-3-ALLYL-1,2,3,3A,4,6A-HEXAHYDROPENTALEN-2-YL]-OXY]-(TERT.-BUTYL)-DIPHENYLSILANE")
| SpectraBase Compound ID | GQe1lfsQYOo |
|---|---|
| InChI | InChI=1S/C27H34OSi/c1-5-13-25-24-19-12-14-21(24)20-26(25)28-29(27(2,3)4,22-15-8-6-9-16-22)23-17-10-7-11-18-23/h5-12,15-19,21,24-26H,1,13-14,20H2,2-4H3/t21-,24-,25+,26+/m0/s1 |
| InChIKey | XMMQJLWAJHLBHX-DTGGKOQTSA-N |
| Mol Weight | 402.7 g/mol |
| Molecular Formula | C27H34OSi |
| Exact Mass | 402.237892 g/mol |
| Enantiomer InChIKey | XMMQJLWAJHLBHX-AFQFEXIYSA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
(1R,3R,4S,5R)-3-[tert-butyl(diphenyl)silyl]oxy-4-ethyl-5-hydroxy-1-cyclohexanecarboxylic acid methyl ester
(1R,3R,4R,5R)-5-t-Butyldiphenylsilyloxy-3-hydroxy-4-ethyl-1-(methoxycarbonyl)cyclohexane
(1R,3R,4S,5S)-3-(tert-Butyl-diphenyl-silanyloxy)-4-ethyl-5-hydroxy-cyclohexanecarboxylic acid methyl ester
(1R,2S,3S,5S)-2-Methyl-3,5-di(1-methylethenyl)-1-(1,1-dimethylethyl)diphenylsiloxycyclohexane
(1S,2R,3aS,4aS)-2-t-Butyldiphenylsilyloxy-3a-formyl-1-ethylbicyclo[3.1.0]hexane
(1R,2R,3aS,4aS)-2-t-Butyldiphenylsilyloxy-3a-formyl-1-ethylbicyclo[3.1.0]hexane
(1S)-1-(3"-Hydroxy-1"-octenyl)-5-[(1',1'-dimethylethyl)diphenylsilyloxy]octahydro-2-pentalenol
(1R,2S,3S,5S)-3,5-Diacetyl-2-methyl-1-(1,1-dimethylethyl)diphenylsiloxycyclohexane
(1R,2R,3aR,5S,6aS)-5-[tert-butyl(diphenyl)silyl]oxy-1-[(E,1S)-1-hydroxyoct-2-enyl]-1,2,3,3a,4,5,6,6a-octahydropentalen-2-ol
(1S)-1-[(2R,4R,5R)-4-[tert-butyl(diphenyl)silyl]oxy-5-(2-phenylmethoxyethyl)-2-oxolanyl]ethane-1,2-diol
| Title | Journal or Book | Year |
|---|---|---|
| Doing it Twice: Asymmetric Deprotonation/Alkylation of Weiss Diketone Derivatives as Key Steps in the Functionalization of Bicyclo[3.3.0]octanes | European Journal of Organic Chemistry | 2012 |