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(1'S,2'S,8a'S)-1',2'-Di-tert-butoxy-7'-methylenehexahydrospiro[cyclopropane-1-8'(5'H)indolizine]

Compound with spectra: 1 NMR, and 1 MS (GC)

(1'S,2'S,8a'S)-1',2'-Di-tert-butoxy-7'-methylenehexahydrospiro[cyclopropane-1-8'(5'H)indolizine]
SpectraBase Compound ID ITvbv1WRylh
InChI InChI=1S/C19H33NO2/c1-13-8-11-20-12-14(21-17(2,3)4)15(22-18(5,6)7)16(20)19(13)9-10-19/h14-16H,1,8-12H2,2-7H3/t14-,15+,16+/m0/s1
InChIKey JCZNAJWWKMLKCA-ARFHVFGLSA-N
Mol Weight 307.5 g/mol
Molecular Formula C19H33NO2
Exact Mass 307.251129 g/mol
Enantiomer InChIKey JCZNAJWWKMLKCA-PMPSAXMXSA-N

View Spectrum of (1'S,2'S,8a'S)-1',2'-Di-tert-butoxy-7'-methylenehexahydrospiro[cyclopropane-1-8'(5'H)indolizine]

MS (GC) Spectrum
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Source of Spectrum BJO-7-SM6-15

View Spectrum of (1'S,2'S,8a'S)-1',2'-Di-tert-butoxy-7'-methylenehexahydrospiro[cyclopropane-1-8'(5'H)indolizine]

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
(ANTI)-(1'S,2'S,8A'S)-1',2'-DI-TERT.-BUTOXY-7'-OXOHEXAHYDROSPIRO-[CYCLOPROPANE-1-8'(5'H)-INDOLIZINE]
(SYN)-(1'S,2'S,8A*S)-1',2'-DI-TERT.-BUTOXY-7'-OXOHEXAHYDROSPIRO-[CYCLOPROPANE-1-8'(5'H)-INDOLIZINE]
1,3-Dioxolo[4,5-a]indolizine, carbonodithioic acid deriv.
(1R,2S,10aR)-1,2-(Isopropylidenedioxy)-1,2,3,5,10,10a-hexahydrobenzo[f]indolizine
[(1S,2S,8aS)-1-[tert-butyl(diphenyl)silyl]oxy-1,2,3,5,6,7,8,8a-octahydroindolizin-2-yl]oxy-tert-butyl-diphenyl-silane
(2R,3R,4S)-t-Butyl 2-Benzoylmethyl-3,4-isopropylidenedioxypyrrolidine-1-carboxylate
(2R,3S,4R)-N-Benzyl-2-[(1'S)-1,2-(isopropylidenedioxy)ethyl]-3,4-(isopropylidenedioxy)pyrrolidine
(2S,3aS,4S,5S)-2-(2-Bromophenyl)-4,5-di-tert-butoxyhexahydropyrrolo[1,2-b][1,2]oxazole
(2R,2'R,3AR,4R,5R,6R)-4,5-DIBENZYLOXY-6-(BENZYLOXYMETHYL)-2-(2-HYDROXYPROPYL)-HEXAHYDROPYRROLO-[1,2-B]-ISOXAZOLE
(CIS)-(3AS,4S,9AS,9BR)-4-ETHYL-2,2-DIMETHYLHEXAHYDRO-[1,3]-DIOXOLO-[4,5-G]-INDOLIZIN-7(3AH)-ONE
Title Journal or Book Year
Rh-Catalyzed rearrangement of vinylcyclopropane to 1,3-diene units attached to N-heterocycles Beilstein Journal of Organic Chemistry 2011
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