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(SYN)-(1'S,2'S,8A*S)-1',2'-DI-TERT.-BUTOXY-7'-OXOHEXAHYDROSPIRO-[CYCLOPROPANE-1-8'(5'H)-INDOLIZINE]

Compound with spectra: 1 NMR, and 1 MS (GC)

(SYN)-(1'S,2'S,8A*S)-1',2'-DI-TERT.-BUTOXY-7'-OXOHEXAHYDROSPIRO-[CYCLOPROPANE-1-8'(5'H)-INDOLIZINE]
SpectraBase Compound ID 9EDCAg44AB9
InChI InChI=1S/C18H31NO3/c1-16(2,3)21-12-11-19-10-7-13(20)18(8-9-18)15(19)14(12)22-17(4,5)6/h12,14-15H,7-11H2,1-6H3/t12-,14+,15-/m0/s1
InChIKey CQVKVHYKQHOYDX-CFVMTHIKSA-N
Mol Weight 309.45 g/mol
Molecular Formula C18H31NO3
Exact Mass 309.230394 g/mol
Enantiomer InChIKey CQVKVHYKQHOYDX-VHDGCEQUSA-N

View Spectrum of (SYN)-(1'S,2'S,8A*S)-1',2'-DI-TERT.-BUTOXY-7'-OXOHEXAHYDROSPIRO-[CYCLOPROPANE-1-8'(5'H)-INDOLIZINE]

MS (GC) Spectrum
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Source of Spectrum BJO-7-SM4-syn-12

View Spectrum of (SYN)-(1'S,2'S,8A*S)-1',2'-DI-TERT.-BUTOXY-7'-OXOHEXAHYDROSPIRO-[CYCLOPROPANE-1-8'(5'H)-INDOLIZINE]

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
  • (1'S,2'S,8a'R)-1',2'-di-tert-butoxy-7'-oxohexahydrospiro[cyclopropane-1-8'(5'H)indolizine]
(1'R,2'R,8'aR)-1',2'-ditert-butoxyspiro[cyclopropane-1,8'-indolizidine]-7'-one
(ANTI)-(1'S,2'S,8A'S)-1',2'-DI-TERT.-BUTOXY-7'-OXOHEXAHYDROSPIRO-[CYCLOPROPANE-1-8'(5'H)-INDOLIZINE]
(1'S,2'S,8a'S)-1',2'-Di-tert-butoxy-7'-methylenehexahydrospiro[cyclopropane-1-8'(5'H)indolizine]
Methyl 4,5,6,7,8,8a-hexahydro-2-hydroxy-6-oxo-2-(trifluoromethyl)-4,8-epi-imino-3aH-cyclohepta[d]-(1,3)-dioxole-9-carboxylate
(3aR,9aS,9bS)-2,2,8-Trimethyl-9-vinyl-3a,4,6,7,9a,9b-hexahydro[1,3]dioxolo[4,5-a]indolizine
(2R,3R,4S)-t-Butyl 2-Benzoylmethyl-3,4-isopropylidenedioxypyrrolidine-1-carboxylate
(CIS)-(3AS,4S,9AS,9BR)-4-ETHYL-2,2-DIMETHYLHEXAHYDRO-[1,3]-DIOXOLO-[4,5-G]-INDOLIZIN-7(3AH)-ONE
PFFVMCHLSQPEAN-AXXKPAGNSA-N
3-(Benzyloxy)-1-{5'-[(t-butyldimethylsilyloxy)methyl]-2',2'-dimethyl-1',3'-dioxolan-4'-yl}methyl-[(fluoren-9'-yl)methoxycarbonyl)amino}-propan-2-ol
(1S,2R,10aR)-1,2-(Isopropylidenedioxy)-1,2,3,5,10,10a-hexahydrobenzo[f]indolizine
Title Journal or Book Year
Rh-Catalyzed rearrangement of vinylcyclopropane to 1,3-diene units attached to N-heterocycles Beilstein Journal of Organic Chemistry 2011
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