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#15A;[[(3AS,5R,6R,6AS)-6-ALLYL-5-[[TERT.-BUTYL-/DIMETHYL)-SILYL]-OXY]-1,3A,4,5,6,6A-HEXAHYDROPENTALEN-2-YL]-OXY]-(TRIETHYL)-SILANE;MINOR-DIASTEREOMER

Compound with spectra: 2 NMR

#15A;[[(3AS,5R,6R,6AS)-6-ALLYL-5-[[TERT.-BUTYL-/DIMETHYL)-SILYL]-OXY]-1,3A,4,5,6,6A-HEXAHYDROPENTALEN-2-YL]-OXY]-(TRIETHYL)-SILANE;MINOR-DIASTEREOMER
SpectraBase Compound ID Hxbe8XzETHT
InChI InChI=1S/C23H44O2Si2/c1-10-14-20-21-17-19(24-27(11-2,12-3)13-4)15-18(21)16-22(20)25-26(8,9)23(5,6)7/h10,15,18,20-22H,1,11-14,16-17H2,2-9H3/t18-,20+,21-,22+/m0/s1
InChIKey CWHSCBCOSFRJTN-WSWWRLHASA-N
Mol Weight 408.8 g/mol
Molecular Formula C23H44O2Si2
Exact Mass 408.287984 g/mol
Enantiomer InChIKey CWHSCBCOSFRJTN-ZDFPQIBNSA-N

View Spectrum of #15A;[[(3AS,5R,6R,6AS)-6-ALLYL-5-[[TERT.-BUTYL-/DIMETHYL)-SILYL]-OXY]-1,3A,4,5,6,6A-HEXAHYDROPENTALEN-2-YL]-OXY]-(TRIETHYL)-SILANE;MINOR-DIASTEREOMER

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3

View Spectrum of #15A;[[(3AS,5R,6R,6AS)-6-ALLYL-5-[[TERT.-BUTYL-/DIMETHYL)-SILYL]-OXY]-1,3A,4,5,6,6A-HEXAHYDROPENTALEN-2-YL]-OXY]-(TRIETHYL)-SILANE;MINOR-DIASTEREOMER

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
  • [[(3AS,5R,6R,6AS)-6-ALLYL-5-[[TERT.-BUTYL-/DIMETHYL)-SILYL]-OXY]-1,3A,4,5,6,6A-HEXAHYDROPENTALEN-2-YL]-OXY]-(TRIETHYL)-SILANE
1H-Inden-1-ol, 3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-2,3,3a,4,7,7a-hexahydro-, 4-nitrobenzoate, (1.alpha.,3.alpha.,3a.beta.,7a.beta.)-(.+-.)-
(3aR,4S,5R,6aS)-5-(tert-butyldimethylsilyloxy)-4-((tert-butyldimethylsilyloxy)methyl)hexahydro-2H-cyclopenta[b]furan -2-one
(3aRS,4SR,5RS,6aSR)-3,3a,4,5,6,6a-Hexahydro-5-[(t-butyl)dimethylsilyloxy)-4-(3'-oxooct-1'-en-1'-yl)-2H-cyclopenta[b]furan-2-one
(3a'S,4'R,5'R,6a'R)-5'-(tert-butyldimethylsilyloxy)-5,5-dimethylhexahydro-1'H-spiro[1,3]dioxane-2,2'-pentalene]-4'-carbaldehyde
.alpha.-7-(2-(3-(trimethylsiloxy)-octa-1(E)-enyl)-3,5-di(trimethylsiloxy)cyclopentyl)hepta-5(Z)-enoic acid methyl ester (1-18O)
.alpha.-7-(2-(3-(trimethylsiloxy)-octa-1(E),5(Z)-dienyl)-3,5-di(trimethylsiloxy)cyclopentyl)hepta-5(Z)-enoic acid methyl ester
(3a'S,4'S,5'R,6a'R)-5'-(tert-butyldimethylsilyloxy)-5,5-dimethylhexahydro-1'H-spiro[1,3]dioxane-2,2'-pentalene]-4'-yl]methanol
[[(2R,3R,3AS,6AR)-3-ALLYL-1,2,3,3A,4,6A-HEXAHYDROPENTALEN-2-YL]-OXY]-(TERT.-BUTYL)-DIPHENYLSILANE
[(1R*,2S,4aR,8S,8aS)-8-(tert-Butyldimethylsiloxy)-2-methyl-1,2,4a,5,6,7,8,8a-octahydronaphthalene-1-yl]methyl pivalate
4-[(tert-Butyldimethyl)siloxy]-1-[(2-methoxyethoxy)methoxy]-1.alpha.,2,3,3a.alpha.,4.alpha.,5,8.beta.,8a.alpha.-octahydroazulen-8-ol
Title Journal or Book Year
Doing it Twice: Asymmetric Deprotonation/Alkylation of Weiss Diketone Derivatives as Key Steps in the Functionalization of Bicyclo[3.3.0]octanes European Journal of Organic Chemistry 2012
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