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(E)-(1SR,5SR,7RS,8SR)-3-(4ï-METHOXYCARBONYLBUTYLIDENE)-7-TERT.-BUTYLDIMETHYLSILYLOXY-8-CYANOBICYCLO-[3.3.0]-OCTAN-2-ONE

Compound with spectra: 1 NMR

(E)-(1SR,5SR,7RS,8SR)-3-(4ï-METHOXYCARBONYLBUTYLIDENE)-7-TERT.-BUTYLDIMETHYLSILYLOXY-8-CYANOBICYCLO-[3.3.0]-OCTAN-2-ONE
SpectraBase Compound ID GG8PjnL6Ek7
InChI InChI=1S/C21H33NO4Si/c1-21(2,3)27(5,6)26-17-12-15-11-14(9-7-8-10-18(23)25-4)20(24)19(15)16(17)13-22/h9,15-17,19H,7-8,10-12H2,1-6H3/b14-9+/t15-,16-,17+,19-/m0/s1
InChIKey IHZIZMKBYXHUEI-SQTQGFMSSA-N
Mol Weight 391.6 g/mol
Molecular Formula C21H33NO4Si
Exact Mass 391.217885 g/mol
Enantiomer InChIKey IHZIZMKBYXHUEI-LZKVWMSGSA-N

View Spectrum of (E)-(1SR,5SR,7RS,8SR)-3-(4ï-METHOXYCARBONYLBUTYLIDENE)-7-TERT.-BUTYLDIMETHYLSILYLOXY-8-CYANOBICYCLO-[3.3.0]-OCTAN-2-ONE

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
(E)-(1SR,5SR,7RS,8SR)-3-(4'-Methoxycarbonylbutylidene)-7-tert-Butyldimethylsilyloxy-8-cyanobicyclo[3.3.0]octan-2-one
5-[(1R,3aS,5R,6S,6aS)-5-(tert-Butyl-dimethyl-silanyloxy)-6-cyano-1-hydroxy-hexahydro-pentalen-(2E)-ylidene]-pentanoic acid methyl ester
(2aR,4aR,7aR,7bS)-3,7b-Dimethyl-2a,4a,5,6,7a,7b-hexahydro-1H-cyclobuta[e]indene-2,7-dione
(3AR,5R,6R,6AS)-6-ALLYL-5-[[TERT.-BUTYL-(DIPHENYL)-SILYL]-OXY]-4,5,6,6A-TETRAHYDROPENTALEN-1(3AH)-ONE
(1S,5S,6R,7R)-7-tert-Butyldimethylsilyloxy-6-[(E,S)-4-hydroxy-4-methyl-1-octenyl]-3-[2-(4-methoxycarbonylphenyl)ethyl]bicyclo[3.3.0]-2-octene
Methyl (1R*,2S*,4aR*,8R*,8aS*)-8-(tert-butyldimethylsiloxy)-2-methyl-4-oxodecahydronaphthalene-1-carboxylate
(3aS,4S,5R,6aR)-5-(tert-Butyl-dimethyl-silanyloxy)-4-{4-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-hexyl]-phenyl}-hexahydro-pentalen-2-one
(+)-(S,E)-2-{(3a'S,4'R,5'R,6a'R)-5'-(tert-butyldimethylsilyloxy)-5,5-dimethylhexahydro-1'H-spiro[1,3]dioxane-2,2'-pentalene]-4'-yl]-4-methyloct-1-en-6-yn-3-one
(5E,1R*,2R*,4R*,8S*)1-[(tert-Butyldimethylsilyl)oxy]-5(cyclohexylmethylene)-2-[(phenylsilyl)methyl]bicyclo[3.3.0]octane
(5E,1R*,2R*,4S*,8R*)-1-[(tert-Butyldimethylsilyl)oxy]-5-(cyclohexylmethylene)-2-[(phenylsilyl)methyl]bicyclo[3.3.0]octane
Title Journal or Book Year
Stereocontrol in organic synthesis using silicon-containing compounds. A synthesis of a (±)-carbacyclin analogue with the geometry of the exocyclic double bond controlled by the protodesilylation of an allylsilane Journal of the Chemical Society, Perkin Transactions 1 1998
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