(3AR,5R,6R,6AS)-6-ALLYL-5-[[TERT.-BUTYL-(DIPHENYL)-SILYL]-OXY]-4,5,6,6A-TETRAHYDROPENTALEN-1(3AH)-ONE
Compound with spectra: 1 NMR
![(3AR,5R,6R,6AS)-6-ALLYL-5-[[TERT.-BUTYL-(DIPHENYL)-SILYL]-OXY]-4,5,6,6A-TETRAHYDROPENTALEN-1(3AH)-ONE](/api/compound/8jsIQxaKSv.png?ph=true&h=300&w=458 "(3AR,5R,6R,6AS)-6-ALLYL-5-[[TERT.-BUTYL-(DIPHENYL)-SILYL]-OXY]-4,5,6,6A-TETRAHYDROPENTALEN-1(3AH)-ONE")
| SpectraBase Compound ID | 8jsIQxaKSv |
|---|---|
| InChI | InChI=1S/C27H32O2Si/c1-5-12-23-25(19-20-17-18-24(28)26(20)23)29-30(27(2,3)4,21-13-8-6-9-14-21)22-15-10-7-11-16-22/h5-11,13-18,20,23,25-26H,1,12,19H2,2-4H3/t20-,23-,25+,26-/m0/s1 |
| InChIKey | RIKPRATWKHJCNC-JWWGNVLFSA-N |
| Mol Weight | 416.6 g/mol |
| Molecular Formula | C27H32O2Si |
| Exact Mass | 416.217157 g/mol |
| Enantiomer InChIKey | RIKPRATWKHJCNC-AAVWJAMMSA-N |
| Copyright | Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved. |
|---|---|
| Solvent | CDCl3 |
(3AR,4R,5R,6AS)-4-ALLYL-5-[[TERT.-BUTYL-(DIPHENYL)-SILYL]-OXY]-4,5,6,6A-TETRAHYDROPENTALEN-1(3AH)-ONE
(3AS,4R,5R,6AS)-4-ALLYL-5-[[TERT.-BUTYL-(DIPHENYL)-SILYL]-OXY]-1,3A,4,5,6,6A-HEXAHYDROPENTALEN-1-OL
TERT.-BUTYL-(DIPHENYL)-[[(3AS',4'R,5'R,6A'R)-4',5,5-TRIMETHYLHEXAHYDRO-1'H-SPIRO-(1,3-DIOXANE-2,2'-PENTALEN)-5'-YL]-OXY]-SILANE
(1S,3R,4S,5R)-5-t-Butyldoihenylsilyloxy-3-mesyloxy-4-ethyl-1-(methoxycarbonyl)cyclohexane
(4S)-4-[(2R,4R,5R)-4-(tert-Butyldiphenylsilyloxy)-5-(5-trimethylsilylpent-2(E)-en-4-ynyl)tetrahydrofuran-2-yl]-2,2-dimethyl[[1,3]dioxolane
(2S,4S,5S,7E,9E,11E)-4-((tert-Butyldiphenylsilyl)oxy)-1,2-(isopropylidenedioxy)-5,7,11-trimethyl-12-(2'-methyloxazol-4'-yl)-7,9,11-dodecatrien-6-one
tert-Butyl-[(2R,3R,5R)-5-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]-2-(2-phenylmethoxyethyl)oxolan-3-yl]oxy-diphenyl-silane
Methyl (1S,3R)-3-[(t-butyldiphenylsilyl)oxy]-4-methylbicyclo[3.1.0]hexane-1-carboxylate
(1S,3R,4S,5S)-3-(tert-Butyl-diphenyl-silanyloxy)-4-methyl-bicyclo[3.1.0]hexane-1-carboxylic acid methyl ester
(4R,6R,7R)-6-tert-Butyldiphenylsilyloxy-7,8-cyclohexylidenedioxyoctan-4-yl 5'-hexenoate
| Title | Journal or Book | Year |
|---|---|---|
| Doing it Twice: Asymmetric Deprotonation/Alkylation of Weiss Diketone Derivatives as Key Steps in the Functionalization of Bicyclo[3.3.0]octanes | European Journal of Organic Chemistry | 2012 |