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(3R,2'S,4'R,5'R)-2-BENZYL-3-(5'-TERT.-BUTYLDIMETHYLSILYLOXY-2'-METHYL-1',3'-DIOXAN-4'-YL)-4-[2-(TRIMETHYLSILYL)-ETHOXY]-3,6-DIHYDRO-2H-1,2-OXAZINE

Compound with spectra: 1 NMR, and 1 MS (GC)

(3R,2'S,4'R,5'R)-2-BENZYL-3-(5'-TERT.-BUTYLDIMETHYLSILYLOXY-2'-METHYL-1',3'-DIOXAN-4'-YL)-4-[2-(TRIMETHYLSILYL)-ETHOXY]-3,6-DIHYDRO-2H-1,2-OXAZINE
SpectraBase Compound ID Cgh7gSMwLVA
InChI InChI=1S/C27H47NO5Si2/c1-21-30-20-24(33-35(8,9)27(2,3)4)26(32-21)25-23(29-17-18-34(5,6)7)15-16-31-28(25)19-22-13-11-10-12-14-22/h10-15,21,24-26H,16-20H2,1-9H3/t21-,24+,25-,26-/m0/s1
InChIKey DAMJZOPHSLVMIQ-QUKDMSEQSA-N
Mol Weight 521.8 g/mol
Molecular Formula C27H47NO5Si2
Exact Mass 521.299277 g/mol
Enantiomer InChIKey DAMJZOPHSLVMIQ-GGLXGSTNSA-N

View Spectrum of (3R,2'S,4'R,5'R)-2-BENZYL-3-(5'-TERT.-BUTYLDIMETHYLSILYLOXY-2'-METHYL-1',3'-DIOXAN-4'-YL)-4-[2-(TRIMETHYLSILYL)-ETHOXY]-3,6-DIHYDRO-2H-1,2-OXAZINE

MS (GC) Spectrum
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Source of Spectrum H-2005-1016-0

View Spectrum of (3R,2'S,4'R,5'R)-2-BENZYL-3-(5'-TERT.-BUTYLDIMETHYLSILYLOXY-2'-METHYL-1',3'-DIOXAN-4'-YL)-4-[2-(TRIMETHYLSILYL)-ETHOXY]-3,6-DIHYDRO-2H-1,2-OXAZINE

13C NMR Spectrum
Copyright Copyright © 2016-2024 W. Robien, Inst. of Org. Chem., Univ. of Vienna. All Rights Reserved.
Solvent CDCl3
  • (3R)-2-Benzyl-4-[2"-(trimethylsilyl)ethoxy]-3-[5'-(t-butyldimethylsilyl)oxy-2'-methyl-1',3'-dioxan-4'-yl])-3,6-dihydro-2H-[1,2]-oxazine
(3S,2'S,4'R,5'R)-2-BENZYL-3-(5'-TERT.-BUTYLDIMETHYLSILYLOXY-2'-METHYL-1',3'-DIOXAN-4'-YL)-4-[2-(TRIMETHYLSILYL)-ETHOXY]-3,6-DIHYDRO-2H-1,2-OXAZINE
(CIS)-[(7S,8S)-8-[BENZYL-(TERT.-BUTYLDIMETHYLSILOXY)-AMINO]-5,5-DIMETHYL-2,3,4,5,7,8-HEXAHYDROPYRANO-[4,3-B]-PYRAN-7-YL]-METHANOL
N-[(1R,2S,3S)-4-(tert-Butyl-dimethyl-silanyloxy)-1-((Z)-2-{(4R,5R)-5-[(R)-(tert-butyl-dimethyl-silanyloxy)-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-methyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-vinyl)-2,3-isopropylidenedioxy
(CIS)-[(6S,7S)-8-[BENZYL-(TERT.-BUTYLDIMETHYLSILOXY)-AMINO]-4,4-DIMETHYL-3,4,6,7-TETRAHYDRO-2H-FURO-[3,2-C]-PYRAN-6-YL]-METHANOL
YWEQGOVZVDYXOE-JRGQVUDSSA-N
(3S,4R,5R,6S,7S)-3-Acetoxy-1,8-bis[(tert-butyldimethylsilyl)oxy]-4-(dibenzylamino)-6,7-(isopropylidenedioxy)-5-(methoxymethoxy)octane
BENZYL-BENZYL-[(S)-1-[(4S,5S)-2,2-DIMETHYL-5-[(R)-8,8,9,9-TETRAMETHYL-2,4,7-TRIOXA-8-SILADECAN-5-YL]-1,3-DIOXOLAN-4-YL]-BUT-3-ENYL]-CARBAMATE
7,9-Dichloro-4-(2-fluoro-phenyl)-2,2-bis-trifluoromethyl-2H-pyrido[1,2-a][1,3,5]triazine
N-((2R)-N'-p-Toluenesulphonylisopropyloxyglycine)-10-N,N-dicyclohexylsulphamoyl-(2R)-isoborneyl ester-
1H-Isoindol-1-one, 2,3-dihydro-3-hydroxy-3-(2-methoxy-1-phenylethyl)-2-methyl-, (R*,R*)-(.+-.)-
Title Journal or Book Year
Stereodivergent Syntheses of Highly Substituted Enantiopure 4-Alkoxy-3,6-dihydro-2H-1,2-oxazines by Addition of Lithiated Alkoxyallenes to Carbohydrate-Derived Aldonitrones European Journal of Organic Chemistry 2005
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